• 제목/요약/키워드: carbon deposit

검색결과 127건 처리시간 0.026초

디젤기관의 대체연료로서의 식물유 (Vegetable oils for diesel fuel substitutes)

  • 오영택
    • 오토저널
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    • 제18권2호
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    • pp.72-92
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    • 1996
  • 식물유, 어유 및 축산 폐기물을 포함한 동식물성 기름은 어느 연료든지 기관의 연료로서 사용 가능하지만, 이들 연료는 점도가 높고, 저휘발성이어서 착화지연기간동안에 가연성혼합기 생성이 어려워 저 NOx이며, 정숙한 운전이 사능할 뿐 아니라 경유정도의 열소비율 및 배기 매연농도로 디젤기관의 대체 연료로서의 충분한 가능성이 있는 연료임을 확인하였다. 그러나, 고점도에 의한 분무 특성의 악화에 기인한 분무입자의 증대로 미연소분에 의한 carbon deposit 및 piston ring stick 등이 문제점으로 지적되었다. 그러나, 이같은 문제점의 해결책으로 경질유와의 혼합, 에스테르 변환 및 연료의 가열등 여러 해결책을 제시하였고, 배기가스분석결과도 양호함을 확인하였다. 이같은 biomass 연료 일종인 식물유가 아무런 변화없이 이용되기 위해서는 고과급화, 단열 및 연소실의 적절한 설계가 필요할 것으로 생각된다. 따라서, 현재의 실황을 생각한다면 기존기관을 특별하게 개조함이 없이 사용을 전제로 할 때 식물유의 이용은 local 에너지로서, 생산, 전환 또는 이용기술의 개발과 동시에 화석에너지의 보충적인 에너지로 고려하는 것이 유효할 것으로 생각된다.

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분사주조 성형체의 기공형성에 대한 기판재료의 영향 (Effects of Substrate Materials on the Porosity Formation of Spary Cast Deposit)

  • 김동규
    • 한국주조공학회지
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    • 제13권5호
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    • pp.476-483
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    • 1993
  • The influence of substrate materials on the degree of basal porosity during spray casting process has been investigated. Different conditions of droplet spreading on the substrate were induced by varying the substrate material. Flat sections of cast iron and aluminum have been spray deposited via spray casting process onto an aluminum substrate, a low carbon steel substrate, and an alumina based refractory substrate. Results for cast iron and aluminum sprayed onto the aluminum substrate showed significant improvements in the surface condition and degree of basal porosity with evidence of substrate deformation that round pits ranging from $5{\mu}m$ to $20{\mu}m$ in diameter are distributed on the surface of aluminum substrate. The lowest level of porosity was developed in alumina based refractory material. Several mechanisms for porosity formation were discussed with droplet impact pressure and droplet spreading. Adopting a spray cutting mechanism for removing the periphery of spray cone, porosity level was remarkably decreased.

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중간층이 DLC 코팅에 미치는 영향 (The Effects of Interlayer on the DLC Coating)

  • 송진수;남태운
    • Corrosion Science and Technology
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    • 제10권2호
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    • pp.65-70
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    • 2011
  • DLC is considered as the candidate material for application of moving parts in automotive components relatively in high pressure and temperature operating conditions for its high hardness with self lubrication and chemical inertness. The properties of interlayer between the substrate and the DLC film were studied. Arc ion plating method have been employed to deposit onto substrate and sputtering method was used for synthesizing DLC onto interlayer. Among these six types of interlayer, deposited DLC film onto TiCN showed excellent value for characteristics. From the results of analysis for physical properties of DLC films, it seems that the adhesion forces were more important factors than intrinsic mechanical properties such as hardness, roughness and wear resistance of DLC films. AFM(Atomic Force Microscope) was used for understanding roughness of DLC films. Hardnesses of the coating layers were identified by nano-indentation method and adhesions were checked by scratch method.

해저 퇴적토 내 유기성 메탄 회수를 위한 가스하이드레이트 치환기법 연구 (A Study on Gas Hydrate Replacement Method for Organic Methane Recovery in Ocean Sediment)

  • 신동현;박대원
    • 유기물자원화
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    • 제26권4호
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    • pp.5-10
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    • 2018
  • 본 연구에서는 압력, 전해질, 유기물 등 가스하이드레이트 부존 지역의 물리화학적 인자가 치환반응에 미치는 영향을 실험적으로 규명하였다. 가스 주입 시 초기 압력이 높을수록 초반 반응속도는 향상되었으나 시간이 지남에 따라 치환효율이 일정한 값으로 수렴하였다. 전해질과 유기물 등의 경우 가스하이드레이트 해리 후 재생성 과정에서 일부 영향을 미치는 것으로 밝혀졌다. 향후 실제 유기성 메탄 하이드레이트가 부존된 퇴적토를 활용한 추가 연구를 통해 국내 해저 지질특성에 적용 가능한 기술 개발이 가능할 것으로 기대된다. 궁극적으로 향후 동해 울릉 분지의 가스하이드레이트 매장 지역 현장 적용을 통해서 유기성 자원인 메탄을 회수하고 활용할 수 있을 것으로 예상된다.

다중벽 탄소나노튜브와 다양한 나노입자 복합체의 In-situ 합성법개발 및 구조제어연구 (Study about the In-situ Synthesis and Structure Control of Multi-walled Carbon Nanotubes and their Nanocomposites)

  • 박호석
    • Korean Chemical Engineering Research
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    • 제50권4호
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    • pp.729-732
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    • 2012
  • 본 논문에서 이온성액체를 이용한 초음파화학을 통해서 칼코젠 나노입자를 in-situ로 합성하여서 다중벽 탄소나노튜브(MWCNT) 위에 도포하였다. 1-Butyl-3-methylimidazolium tetrafluoroborate ($BMimBF_4$) 이온성액체를 이용해서 MWCNT의 표면을 기능화하였다. 합성된 MWCNT/$BMimBF_4$/CdTe, MWCNT/$BMimBF_4$/ZnTe, MWCNT/$BMimBF_4$/ZnSe 나노복합체를 TEM과 EDS를 이용해서 분석하였다. 특히, MWCNT/$BMimBF_4$/CdTe, MWCNT/$BMimBF_4$/ZnTe, and MWCNT/$BMimBF_4$/ZnSe 나노복합체는 각각 요철과 같거나, 거칠거나 부드러운 코어-쉘 형태와 같은 특이한 구조를 보여주었다. 본 연구는 반응속도가 다른 전구체로부터 얻어진 이성분 반도체 나노입자를 합성과 동시에 탄소나노튜브에 도포할 수 있는 새로운 합성법을 제시한다.

Ni/γ-Al2O3 촉매상에서 이산화탄소에 의한 프로판의 개질 (Reforming of Propane by Carbon Dioxide using Ni/γ-A12O3 Catalysts)

  • 김경훈;김종화;장성진;박대원
    • 공업화학
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    • 제8권3호
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    • pp.382-388
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    • 1997
  • 본 연구는 펄스 반응기 및 고정층 연속반응기를 사용하여 ${\gamma}$-알루미나에 담지된 니켈촉매상에서 이산화탄소에 의한 프로판의 개질반응 특성을 고찰한 것이다 Ni/${\gamma}$-$A1_2O_3$촉매가 NiO/${\gamma}$-$A1_2O_3$촉매보다 $CO_2$의 해리능력과 프로판의 개질 능력이 우수한 것으로 나타났다. 프로판과 $CO_2$의 혼합물에 산소를 추가한 결과 프로판의 전환율이 증가하였고 표면의 탄소침적도 감소함을 알 수 있었다. Ni/${\gamma}$-$A1_2O_3$$Ga_2O_3$의 기계적 혼합 촉매는 Ni/${\gamma}$-$A1_2O_3$자체보다 촉매의 활성이 오래 유지되었고 두 상의 협동에 의한 상승효과(synergistic effect)가 관찰되었다.

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갈륨이 첨가된 산화아연막의 코팅에 따른 미세팁 구조 탄소나노튜브의 전계방출 특성 및 장시간 안정성 (Field-emission Properties and Long-term Stability of Tip-type Carbon Nanotubes Coated with Gallium-incorporated Zinc Oxide Films)

  • 김종필;노영록;조경철;이상렬;박진석
    • 반도체디스플레이기술학회지
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    • 제8권4호
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    • pp.65-69
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    • 2009
  • Carbon nanotubes (CNTs) were coated with undoped zinc oxide (ZnO) or 5 wt% gallium-incorporated ZnO (GZO) using various deposition conditions. The CNTs were directly grown on conical-type tungsten substrates at $700^{\circ}C$ using inductively coupled plasma-chemical vapor deposition. The pulsed laser deposition technique was used to deposit the ZnO and GZO thin films with very low stress. Field-emission scanning electron microscopy and high-resolution transmission electron microscopy were used to monitor the variations in the morphology and microstructure of CNTs prior to and after ZnO or GZO coating. The formation of ZnO and GZO films on CNTs was confirmed using energy-dispersive x-ray spectroscopy. In comparison to the as-grown (uncoated) CNT emitter, the CNT emitter that was coated with a thin (10 nm) GZO film showed remarkably improved field emission characteristics, such as the emission current of $325\;{\mu}A$ at 1 kV and the threshold field of $1.96\;V/{\mu}m$ at $0.1\;{\mu}A$, and it also exhibited the highly stable operation of emission current up to 40 h.

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Cu-ferrite에 의한 메탄의 부분산화 (Methane Partial Oxidation Using Cu-ferrite)

  • 우성웅;강경수;김창희;박주식
    • 한국수소및신에너지학회논문집
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    • 제18권2호
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    • pp.124-131
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    • 2007
  • Methane is partially oxidized to produce the syngas by the lattice oxygen of metal oxides in the absence of gaseous oxygen. The present work deals with ferrite including copper component, which does not chemisorb methane, to investigate the suppression of the carbon deposition during the reduction of metal oxides by methane. Iron-based oxides of $Cu_xFe_{3-x}O_4$(X=0.25, 0.5, 1.0) was synthesized by the co-precipitation method. Thermogravimetric Analysis(TGA) was used to observe the isothermal reduction behavior of $Cu_xFe_{3-x}O_4$ and $Fe_3O_4$ at $600-900^{\circ}C$ under methane atmosphere. The crystal structures of reduced specimens were characterized by X-rays powder diffraction(XRD) technique. From the analyses of TGA, it is concluded that the reduction kinetics of $CuFe_2O_4$ was the fastest among $Fe_3O_4$ and $Cu_xFe_{3-x}O_4$(X=0.25, 0.5, 1.0). The X-ray diffraction analyses indicated that $Cu_xFe_{3-x}O_4$ was decomposed to Cu and $Fe_3O_4$ phase at $600^{\circ}C$ and was reduced to Cu and Fe phase at $800^{\circ}C$. $Fe_3O_4$, which was reduced at $900^{\circ}C$, showed Fe, graphite and $Fe_3C$ phases. On the contrary, $Cu_xFe_{3-x}O_4$ does not show the graphite or $Fe_3C$ phases. This results infer that Cu component suppress the carbon deposition on Cu-ferrite.

탄소계 경질 박막의 연구 및 산업 적용 동향 (Trend in Research and Application of Hard Carbon-based Thin Films)

  • 이경황;박종원;양지훈;정재인
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2009년도 춘계학술대회 논문집
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    • pp.111-112
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    • 2009
  • Diamond-like carbon (DLC) is a convenient term to indicate the compositions of the various forms of amorphous carbon (a-C), tetrahedral amorphous carbon (ta-C), hydrogenated amorphous carbon and tetrahedral amorphous carbon (a-C:H and ta-C:H). The a-C film with disordered graphitic ordering, such as soot, chars, glassy carbon, and evaporated a-C, is shown in the lower left hand corner. If the fraction of sp3 bonding reaches a high degree, such an a-C is denoted as tetrahedral amorphous carbon (ta-C), in order to distinguish it from sp2 a-C [2]. Two hydrocarbon polymers, that is, polyethylene (CH2)n and polyacetylene (CH)n, define the limits of the triangle in the right hand corner beyond which interconnecting C-C networks do not form, and only strait-chain molecules are formed. The DLC films, i.e. a-C, ta-C, a-C:H and ta-C:H, have some extreme properties similar to diamond, such as hardness, elastic modulus and chemical inertness. These films are great advantages for many applications. One of the most important applications of the carbon-based films is the coating for magnetic hard disk recording. The second successful application is wear protective and antireflective films for IR windows. The third application is wear protection of bearings and sliding friction parts. The fourth is precision gages for the automotive industry. Recently, exciting ongoing study [1] tries to deposit a carbon-based protective film on engine parts (e.g. engine cylinders and pistons) taking into account not only low friction and wear, but also self lubricating properties. Reduction of the oil consumption is expected. Currently, for an additional application field, the carbon-based films are extensively studied as excellent candidates for biocompatible films on biomedical implants. The carbon-based films consist of carbon, hydrogen and nitrogen, which are biologically harmless as well as the main elements of human body. Some in vitro and limited in vivo studies on the biological effects of carbon-based films have been studied [$2{\sim}5$].The carbon-based films have great potentials in many fields. However, a few technological issues for carbon-based film are still needed to be studied to improve the applicability. Aisenberg and Chabot [3] firstly prepared an amorphous carbon film on substrates remained at room temperature using a beam of carbon ions produced using argon plasma. Spencer et al. [4] had subsequently developed this field. Many deposition techniques for DLC films have been developed to increase the fraction of sp3 bonding in the films. The a-C films have been prepared by a variety of deposition methods such as ion plating, DC or RF sputtering, RF or DC plasma enhanced chemical vapor deposition (PECVD), electron cyclotron resonance chemical vapor deposition (ECR-CVD), ion implantation, ablation, pulsed laser deposition and cathodic arc deposition, from a variety of carbon target or gaseous sources materials [5]. Sputtering is the most common deposition method for a-C film. Deposited films by these plasma methods, such as plasma enhanced chemical vapor deposition (PECVD) [6], are ranged into the interior of the triangle. Application fields of DLC films investigated from papers. Many papers purposed to apply for tribology due to the carbon-based films of low friction and wear resistance. Figure 1 shows the percentage of DLC research interest for application field. The biggest portion is tribology field. It is occupied 57%. Second, biomedical field hold 14%. Nowadays, biomedical field is took notice in many countries and significantly increased the research papers. DLC films actually applied to many industries in 2005 as shown figure 2. The most applied fields are mold and machinery industries. It took over 50%. The automobile industry is more and more increase application parts. In the near future, automobile industry is expected a big market for DLC coating. Figure 1 Research interests of carbon-based filmsFigure 2 Demand ratio of DLC coating for industry in 2005. In this presentation, I will introduce a trend of carbon-based coating research and applications.

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홍천 철-희토류광상 모암의 암석화학 (Petrochemistry of the Hongcheon Fe-REE ore deposit in the Hongcheon area, Korea)

  • 박중권;이한영
    • 암석학회지
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    • 제12권3호
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    • pp.135-153
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    • 2003
  • 선캠브리아기 변성퇴적암류를 관입하고 있는 탄산염암에 배태하는 홍천 철-희토류 광상은 자철석, 안케라이트, 능철석, 마그네사이트, 스트론티아나이트 등의 다양한 탄산염광물과 모나자이트, 아지린휘석, Na가 섬석 및 황화광물들이 산출되어 이들 암석의 지화학적특성과 성인을 규명하고자 주 원소, 미량원소, 희토류원소 및 산소-탄소의 안정동위원소의 광물 및 암석화학연구가 이루어졌다. 각 원소(주원소, 미량원소, 희토류원소)들을 본 연구지역의 탄산염암과 유사한 철질 카보나타이트(ferro-carbonatite)와 비교하면 주 원소에서는 농집된 FeO와 결핍된 CaO가 관찰되며, $SiO_2$가 증가하면서 $TiO_2$$A1_2O_3$증가, CaO, FeO, MgO 및 $P_2O_{5}$의 약한 감소가 인지되나 분산되어 뚜렷한 경향은 아니다. 미량원소는 Nb, Zr 및 Zn이 철질 카보나타이트보다 결핍되어 나타나며, $SiO_2$의 증가에 따른 V 및 Ni의 증가, U 및 Rb의 미약한 증가가 확인되나 타 원소들은 분산되어 뚜렷한 경향을 나타내지 않는다. 희토류원소는 전희토류(TREE)함량이 매우 높고 La, Ce, Pr, Nd 및 Sm 같은 경희토류의 농집, 그리고 결핍된 중희토류로 인하여 높은 La/Lu 값을 보이고 있다. 안케라이트, 스트론티아나이트 및 전암의 산소 및 탄소 안정동위원소 결과는 본 암이 화성기원의 카보나타이트용융체에서 유래된 것으로 나타난다. 홍천 철-희토류 광상 탄산염암의 암석화학적 특성은 일반적인 철질 카보나타이트와는 차이가 있으며 러시아 Kovdor 및 핀랜드 Sokli 지역에서 산출되는 카보나타이트의 일종인 포스코라이트(phoscorite)의 암석화학성분과 매우 유사하다.