• Archives of Metallurgy and Materials
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• v.65 no.3
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• pp.1001-1004
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• 2020

We investigated the austenite stability and mechanical properties in FeMnNiC alloy fabricated by spark plasma sintering. The addition of Mn, Ni, and C, which are known austenite stabilizing elements, increases its stability to a stable phase existing above 910℃ in pure iron; as a result, austenitic microstructure can be observed at room temperature, depending on the amounts of Mn, Ni, and C added. Depending on austenite stability and the volume fraction of austenite at a given temperature, strain-induced martensite transformation during plastic deformation may occur. Both stability and the volume fraction of austenite can be controlled by several factors, including chemical composition, grain size, dislocation density, and so on. The present study investigated the effect of carbon addition on austenite stability in FeMnNi alloys containing different Mn and Ni contents. Microstructural features and mechanical properties were analyzed with regard to austenite stability.

• Journal of Energy Engineering
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• v.23 no.3
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• pp.157-162
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• 2014

In this research, we investigate electrical performance and electrochemical properties of carbon supported Pt (Pt/C) that is synthesized by polyol method. With the Polyol_Pt/C that is adopted for oxygen reduction reaction (ORR) as cathode of proton exchange membrane fuel cells (PEMFCs), their catalytic activity and ORR performance and electrical performance are estimated and compared with commercial Pt/C(Johnson Mattey) catalyst. Their electrochemically active surface (EAS) area are measured by cyclic voltammetry (CV), respectively. On the other hand, regarding ORR activity and electrical performance of the catalysts, (i) linear sweeping voltammetry by rotating disk electrode and (ii) PEMFC single cell tests are used. The CV measurement demonstrate EAS of Polyol_Pt/C is compared with commercial JM_Pt/C. In case of Polyol_Pt/C, its half-wave potential, kinetic current density are excellent. Based on data obtained by half-cell test, when PEMFC single cell tests are carried out, current density measured at 0.6V and maximum power density of the PEMFC single cell employing Polyol_Pt/C are better than those employing commercial Pt/C. Conclusively, Polyol_Pt/C synthesized by modified polyol process shows better ORR catalytic activity and PEMFC performance than other catalysts.

• Journal of Environmental Science International
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• v.12 no.4
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• pp.461-467
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• 2003

This study was conducted to provide the basic information to know reasonable method f3r the removal and treatment of municipal solid wastes(MSWs). MSWs four different sources(apartment residence, commerce, office/industry) in Daegu city were collected, and bulk density, physical composition, moisture, combustible, ash, elements and heating values were investigated. The values of bulk density were at range of 0.30∼0.41ton/m$^3$. The percentages of foods, papers, vinyls/plastics, textiles, rubbers/leathers, metals and glasses/ceramics of wet muncipal solid wastes from three sources except office/industry were at range of 27.3∼46.4%, 21.2∼38.4%, 10.3∼11.9%, 3.8∼5.2%, 0.5∼1.7%, 6.9∼8.7% and 1.9∼2.6% respectively. The percentages of papers, foods, vinyls/plastics, textiles, rubbers/leathers, metals and glasses/ceramics of dry muncipal solid wastes from three sources except office/industry were at range of 21.1∼40.4%, 14.2∼30.1%, 15.2∼17.8%, 4.0∼6.0%, 0.9∼2.8%, 12.2∼14.1% and 3.1∼3.7％ respectively. The moisture contents of foods, woods, textiles and papers in wastes were at range of 65.7∼76.2%, 34.6∼50.0%, 22.2∼44.8 and 30.6∼44.4% respectively. The carbon contents of vinyls/plastics, rubbers/leathers, textiles, woods, papers and foods in wastes were at range of 75.88∼79.87%, 58.24∼70.74%, 45.23∼51.63%, 42.29∼45.58%, 40.19∼48.4% and 25.86∼36.25% respectively. The low heating values of foods, papers, woods, textiles, rubbers/leathers and vinyls/plastics by Dulong's law were at range of 178∼1,353kcal/kg, 770∼1,660kcal/kg, 995∼1,629kcal/kg, 2,133∼2,432kca1/kg, 4,200∼7,275 kcal/kg and 6,384∼8,722kcal/kg respectively, and the high heating values of them were at range of 782∼2,056 kcal/kg, 2,459∼3,314kca1/kg, 3,056∼3,592kcal/kg, 4,381∼5,087kca1/kg, 5,005∼8,066kca1/kg and 10,032∼10,739 kcal/kg respectively.

• Journal of Korean Society of Forest Science
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• v.102 no.4
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• pp.543-549
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• 2013

This study was conducted to evaluate age-specific and generalized allometric equations and biomass expansion factors (BEFs) for each tree component across three age-sequence stands (35-year-old, 51-year-old, 62-year-old) of black pine (Pinus thunbergii Parl.) in Jinju, located in the western part of Gyeongnam province, Korea. Biomass in each tree component, i.e. foliage, branch, and stem, was quantified by destructive tree harvesting. Allometric regression equations were significant (P<0.05) with diameter at breast height (DBH) or combination of DBH and height ($DBH^2H$) accounting for 55-98% of the variation (as indicated by coefficients of determination, $R^2$) in aboveground biomass except for foliage biomass of the 62-year-old stand. Generalized allometric equations can be used to estimate the biomass of black pine stands because the slopes of age-specific equations over 35-year-old stands were not significantly different by the age-sequence. The stem density and biomass expansion factor (BEFs) were not significantly different (P>0.05) from different stand ages and ranged from 0.45 to $0.51gcm^{-3}$, and from 1.32 to 1.38, respectively. The results indicate that allometric equations, stem density and aboveground BEFs in the matured black pine over 35-year-old are little influenced by different stand ages.

• Journal of Radiation Protection and Research
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• v.27 no.2
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• pp.95-100
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• 2002

Conventional and modified electrolytic decontamination experiment were performed in the 1.7 M solution of sodium sulfate and sodium nitrate tot decontamination of carbon steel as the simulated metal wastes which have been produced in large amounts from nuclear power plants. Anode ant cathode were used as inconel and titanium respective. The reaction time and temperature were 1 hr and $25^{\circ}C$ The analyses were performed of the characteristics such as weight loss arid thickness change of metal waste. suspended solid in electrolyte and SEM observation. In modified electrolyte decontamination system with increased current density ranged from 0.1 to $0.6A/cm^2$, the metal waste showed thickness changes of $0.48{\pm}0.005$ to $67.7{\pm}0.02{\mu}m$ in 1.7 M sodium sulfate and those of $0.06{\pm}0.005$ to $17.7{\pm}0.05{\mu}m$ in sodium nitrate. Metal waste in modified electrolyte decontamination system showed the thickness change of $9.8{\pm}0.01{\mu}m$ while it reacted up to $3.7{\pm}0.03{\mu}m$ in conventional system with $0.3 A/cm^2$ of current density and 1.7 M sodium sulfate. Decontamination efficiencies of modified electrolytic process ate much hither than that of conventional electrolytic process when both are applied to metal waste.

• Journal of Korean Society of Forest Science
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• v.101 no.2
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• pp.244-250
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• 2012

The objective of this study was to analyze the above-ground biomass and crown fuel characteristics of Pinus densiflora stands in Yangyang, Gangwon province. A total of thirteen representative trees were destructively sampled in Yangyang region. The results showed that the stem density ($g{\cdot}cm^{-3}$) was 0.347~0.409, whereas the above-ground biomass expansion factors ranged from 1.251~1.419. In terms of crown fuel biomass, the above-ground biomass was $161.6Mg{\cdot}ha^{-1}$ while the stem biomass, branch biomass and needle biomass were $126.4Mg{\cdot}ha^{-1}$, $29.3Mg{\cdot}ha^{-1}$ and $5.9Mg{\cdot}ha^{-1}$, respectively. Needles and twigs with less than 1 cm diameter accounted 45.2% of the total crown fuel load. The available crown bulk density, which was calculated by dividing the crown fuel load to the crown volume, was $0.178kg{\cdot}m^{-3}$. The results of this study on the biomass and carbon stocks estimation of the Pinus densiflora together with the crown fire hazard assessment based on crown fuel loads are very significant information for the forest managers.

• Microbiology and Biotechnology Letters
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• v.41 no.1
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• pp.105-111
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• 2013

Biofilm formation of multifunctional plant growth promoting rhizobacterium (PGPR), Pseudomonas fluorescens 2112 is necessary for P. fluorescens 2112 to have a positive impact on the rhizosphere of red-pepper. This study investigated whether signal molecules of the quorum sensing AHLs are produced in order to confirm biofilm formative ability. Through the use of Petri dish bioassays a blue circle formed evidence of AHLs. It was confirmed that P. fluorescens 2112 produced six-carbon-chain-long AHLs by TLC bioassay. The bacterial density of P. fluorescens 2112 on the top and bottom of pepper plant roots was estimated as $3{\times}10^5$ and $8{\times}10^3$ CFU/g root, respectively. P. fluorescens 2112 exist more with high-density of $3.5{\times}10^6$ CFU/g soil at a depth of 1 cm but at a low-density of $1.1{\times}10$ CFU/g soil at a depth of 5 cm, from the surface of rhizosphere soil. In addition, biofilm formation of P. fluorescens 2112 on the epidermises and the tips of the red-pepper roots were confirmed visually by SEM. Thus, the production of AHLs by P. fluorescens 2112 brings about quorum sensing signaling and the formation of biofilm on the roots which has a positive effect on economically important crops such as red-pepper by additionally producing a variety of antifungal substances and auxin.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.1
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• pp.1-6
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• 2014

The composite anodes of exfoliated graphite (EG) and multiwall carbon nanotube (MWCNT) were fabricated by using the binders with different content of epoxy in Nafion solution. The influence of the epoxy content in the anode binder on the performance of microbial fuel cell (MFC) was examined in a batch reactor. With the increase in the epoxy content in the anode binder, increase in physical binding force was observed, but at the same time an increase in the internal resistance of MFC was also observed. This was due to the increase in activation and ohmic resistance. For the anode binder without epoxy, the maximum power density was $1,892mW/m^2$, but a decrease in maximum power density was observed with the increase in the epoxy content in the anode binder. With the epoxy content of 50% in the anode binder, a decrease in the maximum power density to $1,425mW/m^2$ was observed, which about 75.3% of the anode binder without epoxy is. However, the material consisting of the same amount of epoxy and Nafion solution is a good alternative for anode binder in terms of durability and economics of MFC.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.385-389
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• 2012

In this study, torrefaction of mixed softwood chips under anoxic condition was performed to improve energy density and maintain consistent quality of biomass. Characteristics of torrefied biomass depending on reaction time (30 min) and temperature (240, 260,$280^{\circ}C$) were investigated. Torrefaction of mixed softwood chips significantly improved the heating value compared to that of untreated biomass. As the torrefaction temperature was increased, the carbon content of torrefied biomass increased from 46.55 to 55.73%, while its hydrogen and oxygen contents decreased from 6.00 to 5.87% and from 30.55 to 27.21%, respectively. Most of hemicelluloses and volatile compounds were removed during torrefaction. The highest heating value was 5132 kcal/kg when torrefaction was performed at$280^{\circ}C$ for 30 min. It implied that the heating value increased by 13% compared to that of original biomass. However, the condition of effective torrefaction was at $240^{\circ}C$ for 30 min when weight loss and energy yield was considered.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.6
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• pp.305-311
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• 2012

In order to recycle the coal bottom ashes (denoted as BA) produced from a thermal power plant, the artificial aggregates (denoted as AAs) containing BA and red clay were manufactured, and the physical properties of AAs were studied as a function of particle size of BA and batch compositions. As-received BA had 38 wt% coarse particles of above 2 mm and many unburned carbon mass and porous slag particles were co-existed. So the two particle sizes of BA, the fine (< 100 ${\mu}m$) and coarse (< 2 mm), were prepared by milling and screening process. The AAs containing fine BA sintered at $1100{\sim}1200^{\circ}C$ had the higher bulk density and lower water absorption compared to the specimen made of coarse BA. The inside core of AAs manufactured by using coarse BA showed nonuniform and porous microstructure, while the AAs made of fine BA had a uniform and dense microstructure. In this research, the AAs containing BA and red clay with various bulk density (1.2~1.7) and water absorption (13~21 %) could be manufactured by controlling the particle size of BA and batch compositions, so the AAs of various physical properties could be applied to the wide fields such as construction/building materials in near future.