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Modeling of Cementite Precipitation Kinetics on Solute Carbon Content in Extra and Ultra Low Carbon Steels (극저탄소강의 고용 탄소 함량에 미치는 시멘타이트 석출 속도 모델링)

  • Choi, Jong Min;Park, Bong June;Kim, Sung Il;Lee, Kyung Sub;Lee, Kyung Jong
    • Korean Journal of Metals and Materials
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    • v.48 no.3
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    • pp.187-193
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    • 2010
  • The solute carbon content in ferrite is one of the important factors to obtain good formability in low carbon steels. Although most of the carbons are consumed by the formation of grain boundary cementite during coiling after hot-rolling, the carbon content after coiling is normally observed much more than that of equilibrium. In this study, a classical nucleation and growth model is used to simulate the precipitation kinetics of the grain boundary cementite from coiling temperature (CT) to room temperature (RT). The predicted precipitation behaviors depending on the initial carbon content and the cooling rate are compared with the reported. As a result, the lateral growth of thickening of cementite is a major factor for the sluggish reaction of grain boundary cementite. The reduction of solute carbon content after coiling is divided into three regions: a) increase due to no cementite precipitation, b) decrease due to the fast length-wise growth of cementite, c) increase due to the slow thickness-wise growth of cementite.

Experimental Study on the Flue Gas Phenomena in Infrared Mobile Heaters (이동식 적외선 가스히터의 배기가스현상에 대한 실험적 연구)

  • 김영규;류근준
    • Journal of the Korean Society of Safety
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    • v.11 no.3
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    • pp.119-125
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    • 1996
  • The experimental work is performed to obtain content levels and characteristics of flue gas in infrared mobile heaters for butane gas with varying the chamber size and its room temperature. The results showed that the oxygen depletion sensor device is operated at 18.3% of oxygen content. And the relation of oxygen content and carbon dioxide content in an enclosed space show linear aspect, but the content rate of carbon monoxide occurs at random without the level of oxygen content and carbon dioxide content.

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A Study on Stabilization and Mechanical Properties of Polyacrylonitrile-based Fiber with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴계 전구체섬유의 열안정화 및 그 물성에 관한 연구)

  • 신익기;이신희;박수민
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.76-85
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    • 2003
  • In this study, a continuous stabilization process is used to make high-performance carbon fiber from polyacrylonitrile(PAM)-based fibers. The effect of oxygen content of PAN-based fiber on the stabilization process and the properties of the resultant carbon fibers is investigated. In order to research the progress of stabilization reaction FT-IR, elemental analysis, density, DSC, etc are used. Stabilization is carried out in air atmosphere from the 200 to $300^\circ{C}$ temperature range. An increase of PAN-based fibers diameter reduces the oxygen content during the continuous stabilization process. A higher oxygen content increase the density, tensile strength and modulus in the resultant carbon fibers. The most appropriate oxygen content in the stabilized fiber should be about 12%. Fibers having more than 2% oxygen content yield carbon fibers with inferior properties. Those carbon fibers also have sufficient commercial availability.

Development of a soil total carbon prediction model using a multiple regression analysis method

  • Jun-Hyuk, Yoo;Jwa-Kyoung, Sung;Deogratius, Luyima;Taek-Keun, Oh;Jaesung, Cho
    • Korean Journal of Agricultural Science
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    • v.48 no.4
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    • pp.891-897
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    • 2021
  • There is a need for a technology that can quickly and accurately analyze soil carbon contents. Existing soil carbon analysis methods are cumbersome in terms of professional manpower requirements, time, and cost. It is against this background that the present study leverages the soil physical properties of color and water content levels to develop a model capable of predicting the carbon content of soil sample. To predict the total carbon content of soil, the RGB values, water content of the soil, and lux levels were analyzed and used as statistical data. However, when R, G, and B with high correlations were all included in a multiple regression analysis as independent variables, a high level of multicollinearity was noted and G was thus excluded from the model. The estimates showed that the estimation coefficients for all independent variables were statistically significant at a significance level of 1%. The elastic values of R and B for the soil carbon content, which are of major interest in this study, were -2.90 and 1.47, respectively, showing that a 1% increase in the R value was correlated with a 2.90% decrease in the carbon content, whereas a 1% increase in the B value tallied with a 1.47% increase in the carbon content. Coefficient of determination (R2), root mean square error (RMSE), and mean absolute percentage error (MAPE) methods were used for regression verification, and calibration samples showed higher accuracy than the validation samples in terms of R2 and MAPE.

Characteristics Correlations Between Fiber-Reinforced and Interfacial Adhesion in Carbon fiber reinforced Cement composite Prepared by Slurry Method. (슬러리법에 의한 탄소섬유보강 시멘트복합체의 제조에서 보강섬유와 계면결착제와의 상관특성)

  • Choi, Eung-Kyoo
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.3
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    • pp.131-138
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    • 2002
  • The objective of the study is to examine the characteristic correlations between reinforcing carbon fiber and interfacial adhesion agent since the interfacial adhesion strength between reinforcing carbon fiber and matrices is believed to be an essential element influencing the physical properties in carbon fiber reinforced cement composite using slurry method. The integrity of interfacial adhesion between reinforcing fiber and cement not only affects the quality of fiber reinforced cement composite but also influences to a large degree the physical properties of the cement composite when producing carbon fiber reinforced cement composite using slurry method. Having analyzed the physical properties 1.e., water content, tensile strength, flexural strength and flexural toughness of carbon fiber reinforced cement composite specimens, C-PAM(cation polyacrylamide) was determined to be an optimum interfacial adhesion agent. The study has also demonstrated that interfacial adhesion strength varies largely on the content and type of the reinforcing fiber. Judging from magnified view of the tensile shear cross-section using VMS(video microscope system), interfacial adhesion strength between reinforcing fiber and matrices is affected by the type of interfacial adhesion agent. According to the result of the experiments, C-PAM was determined to be an ideal interfacial adhesion agent when using carbon fiber in producing carbon fiber reinforced cement composite with the optimum content of carbon fiber being established.

Investigation of field emission mechanism of undoped polycrystalline diamond films (도핑되지 않은 다결정 다이아몬드 박막의 전계방출기구 조사)

  • 심재엽;지응준;송기문;백홍구
    • Journal of the Korean Vacuum Society
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    • v.8 no.4A
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    • pp.417-424
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    • 1999
  • In order to investigate field emission mechanism of undoped polycrystalline diamond films, diamond films with different structural properties were deposited by varying positive substrate bias and/or $CH_4$ concentration. When increasing $CH_4$ concentration and positive substrate bias voltage, nondiamond carbon content in diamond films increased. Increase of nondiamond carbon content with increasing substrate voltage is ascribed to increase of substrate and excess generation of $CH_n$ radicals. Field emission properties of undoped polycrystalline diamond films ere significantly enhanced with increasing nondiamond carbon content. For diamond films with a small amount of nondiamond carbon, electrons are emitted through diamond surface while for the films with a large amount of nondiamond carbon, electron emission occurs through diamond bulk as well as surface. From this study, depending on nondiamond carbon content two field emission mechanisms were suggested.

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Effects of Carbon Content on the Weldability of B-Containing $620^{\circ}C$ Grade High Cr Ferritic Cast Steel for Turbine Casing (B 첨가 $620^{\circ}C$급 터빈 케이싱용 고Cr 페라이트계 주강의 용접성에 미치는 탄소함량의 영향)

  • Seo, Won-Chan;Bang, Kook-Soo;Chi, Byung-Ha
    • Journal of Ocean Engineering and Technology
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    • v.22 no.6
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    • pp.41-45
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    • 2008
  • Effectsof carbon content on the weldability of B-containing 620 grade high Cr ferritic cast steels were investigated. Cast steel with lower carbon content of 0.07% showed lower HAZ hardness because of the formation of lower carbon martensite in HAZ. It also showed less solidification cracking susceptibility in weld metal because of the formation of delta ferrite. However, hot ductility showed no difference between cast steels with lower and higher carbon contents. Cast steel with lower carbon content showed greater HAZ softening after PWHT in the region heated between AC1 and AC3 because of its higher base metal hardness.

Carbon Storage in Aboveground, Root, and Soil of Pinus densiflora Stand in Six Different Sites, Korea

  • Park, Gwan-Soo;Choi, Jaeyong;Lee, Kyung-Hak;Son, Young-Mo;Kim, Rae-Hyun;Lee, Hang-Goo;Lee, Sang-Jin
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.2
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    • pp.1-9
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    • 2009
  • Due to the increase of carbon dioxide in the atmosphere and global warming, the importance of forest ecosystems, as a place of carbon accumulation and emission, has received a great amount of recognition lately. This study was performed to help understand and provide the current status of carbon cycle in the pinus densiflora stand, Korea. The samples were collected from average 35-years-old Pinus densifiora rands in Gongju, Youngdong, Chungsan, Muju, Mupung, and Jangsu regions. Total thirty aboveground sample trees were cut, and ten roots were sampled, and soil samples were collected. Average carbon concentrations in foliage, branch, stem bark, stem wood, and root were 55.7%, 56.0%, 56.0%, 57.3%, and 56.5%, respectively. Carbon content was estimated by the model $Wt=aD^b$ where Wt is oven-dry weight in kg and D is DBH in cm. Total carbon content (aboveground and root) was 42.39tonC/ha in the Pinus densiflora stand. The proportion of each tree component to total carbon content was high in order of stemwood, root, branch, stem bark, and foliage. Total net primary production (aboveground and root) was estimated at 6.51tonC/ha/yr in Pinus densiflora stand. The proportion of each tree component to total net primary carbon content was high in order of sternwood, root, branch, foliage and stembark. Soil carbon contents in the study sites was 43.51tonC/ha at 0-50cm soil depth.

Effects of maleic anhydride content on mechanical properties of carbon fibers-reinforced maleic anhydride-grafted-poly-propylene matrix composites

  • Kim, Hyun-Il;Han, Woong;Choi, Woong-Ki;Park, Soo-Jin;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • v.20
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    • pp.39-46
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    • 2016
  • In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (KIC). From the KIC test results, the KIC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

Quality Comparison of Activated Carbon Produced From Oil Palm Fronds by Chemical Activation Using Sodium Carbonate versus Sodium Chloride

  • MAULINA, Seri;HANDIKA, Gewa;Irvan, Irvan;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.4
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    • pp.503-512
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    • 2020
  • Using Na2CO3 versus NaCl as chemical activator, we compared the quality of activated carbon produced from oil palm fronds as raw material. These activators were selected for comparison because both are readily available and are environmentally friendly. In the manufacturing, we used Indonesian National Standard (SNI 06-3730-1995) parameters. For the quality comparison, we determined activated-carbon yield, moisture, ash, volatiles, and fixed-carbon contents; and adsorption capacity of iodine. The best characteristics, assessed by morphological surface analysis and Fourier transform infrared (FTIR) spectral analysis, were observed in the carbon activated by Na2CO3 at an activator concentration of 10% and carbonization temperature of 400 ℃. The results were as follows: activated-carbon yield, 84%; water content, 8.80%; ash content, 2.20%; volatiles content, 14.80%; fixed-carbon content, 68.60%; and adsorption capacity of iodine, 888.51 mg/g. Identification using the FTIR spectrophotometer showed the presence of the functional groups O-H, C=O, C=C, C-C, and C-H in the Na2CO3-activated carbon.