• Title/Summary/Keyword: carbon composites

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Monitoring Failure Behaviour of Pultruded CFRP Composites by Electrical Resistance Measurement

  • Mao, Yaqin;Yu, Yunhua;Wu, Dezhen;Yang, Xiaoping
    • Carbon letters
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    • v.5 no.1
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    • pp.18-22
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    • 2004
  • The failure behaviours of unidirectional pultruded carbon fiber reinforced polymer (CFRP) composites were monitored by the electrical resistance measurement during tensile loading, three-point-bending, interlaminar shear loading. The tensile failure behaviour of carbon fiber tows was also investigated by the electrical resistance measurement. Infrared thermography non-destructive evaluation was performed in real time during tensile test of CFRP composites to validate the change of microdamage in the materials. Experiment results demonstrated that the CFRP composites and carbon fiber tows were damaged by different damage mechinsms during tensile loading, for the CFRP composites, mainly being in the forms of matrix damage and the debonding between matrix and fibers, while for the carbon fiber tows, mainly being in the forms of fiber fracture. The correlation between the infrared thermographs and the change in the electrical resistance could be regarded as an evidence of the damage mechanisms of the CFRP composites. During three-point-bending loading, the main damage forms were the simultaneity fracture of matrix and fibers firstly, then matrix cracking and the debonding between matrix and fiber were carried out. This results can be shown in Fig. 9(a) and (b). During interlaminar shear loading, the change in the electrical resistance was related to the damage degree of interlaminar structure. Electrical resistance measurement was more sensitive to the damage behaviour of the CFRP composites than the stress/time curve.

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Preparation and Characteristic of Carbon/Carbon Composites with Coal-tar and Petroleum Binder Pitches (석탄계 및 석유계 피치가 함침된 탄소/탄소 복합재료 제조 및 특성)

  • Yang, Jae-Yeon;Park, Sang-Hee;Park, Soo-Jin;Seo, Min-Kang
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.406-412
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    • 2015
  • Unidirectional carbon/carbon (C/C) composites were manufactured using phenolic resins as a precursor of the carbonized matrix throughout a one-step manufacturing process. Also, molybdenum oxide ($MoO_3$) and binder pitches were impregnated with phenolic resins to improve the bulk density and mechanical property of the C/C composites. In this study, the influence of $MoO_3$ and binder pitches on mechanical properties of the C/C composites were investigated by measuring flexural strength (${\sigma}_f$) and interlaminar shear strength (ILSS). The results show that the enhancement of interfacial adhesions between the fibers and matrix resins of the C/C composites with $MoO_3$ and binder pitches which led to the improvement of mechanical properties of the C/C composites. This indicates that the presence of $MoO_3$ and binder pitches in C/C composites can develop the graphite structure and increase the bulk density.

Effects of maleic anhydride content on mechanical properties of carbon fibers-reinforced maleic anhydride-grafted-poly-propylene matrix composites

  • Kim, Hyun-Il;Han, Woong;Choi, Woong-Ki;Park, Soo-Jin;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • v.20
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    • pp.39-46
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    • 2016
  • In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (KIC). From the KIC test results, the KIC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

A Review of Carbon-Reinforced Carbon Nanotube Fibers Composites (탄소강화 탄소나노튜브 섬유 복합소재 연구 동향)

  • Lee, Dongju;Ryu, Seongwoo;Ku, Bon-Cheol
    • Composites Research
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    • v.32 no.3
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    • pp.127-133
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    • 2019
  • Although carbon nanotubes(CNTs) have outstanding theoretical mechanical and electrical properties, CNT fibers(CNTFs) have not yet reached that level. Particularly, tensile strength is only about 10% or less, so studies for making up for it are being actively conducted. As a way for improving mechanical strength, methods such as synthesizing long CNT, orientation, chemical cross-linking, hydrogen bonding and polymer infiltration are being studied. In this review paper, we report preparation methods for highly conductive and strong CNTF/Carbon composites through coating and infiltration followed by carbonization of carbon precursor polymers such as polyacrylonitrile (PAN) and polydopamine (PDA) on CNTFs.

Wear Characterization of $Al/Al_2O_3$ Composites Reinforced with Hybrid of Carbon Fibers and SiC Whiskers (탄소섬유와 SiC 휘스커를 혼합한 $Al/Al_2O_3$ 복합재료의 마멸특성)

  • 봉하동;송정일;한경섭
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.7
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    • pp.1619-1629
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    • 1995
  • The Al/Al$_{2}$O$_{3}$ SiC and Al/Al$_{2}$O$_{3}$/C hybrid metal matrix composites (MMCs) were fabricated by squeeze infiltration method. Uniform distribution of reinforcements were found in the microstructure of metal matrix composites. Mechanical tests were carried out under various test conditions to clearly identify mechanical behavior of MMCs, and the wear mechanism of Al/Al$_{2}$O$_{3}$/(SiC or C) hybrid metal matrix composites were investigated. The tensile strength and hardness of hybrid composites was resulted in increasing compared with those of the unreinforced matrix alloy. Wear resistance was strongly dependent upon kinds of fiber, volume fraction and sliding speed. The wear resistance of metal matrix composites was remarkably improved by the addition of reinforcements. Especially, the wear resistance of the hybrid composites of carbon fibers was more effective than in the composites reinforced with alumina and SiC whiskers of reinforcements. This was due to the effect of carbon fiber on the solid lubrication. Wear mechanisms of hybrid composites were suggested from wear surface analyses. The major wear mechanism of hybrid composites was the abrasive wear at low to intermediate sliding speed, and the melting wear at intermediate to high sliding speed.

Effects of Electrochemical Oxidation of Carbon Fibers on Mechanical Interfacial Properties of Carbon Fibers-reinforced Polarized-Polypropylene Matrix Composites (전기화학적 산화처리가 탄소섬유/극성화된 폴리프로필렌 복합재의 기계적 계면 특성에 미치는 영향)

  • Kim, Hyun-Il;Choi, Woong-Ki;Oh, Sang-Yub;An, Kay-Hyeok;Kim, Byung-Joo
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.476-482
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    • 2013
  • In this work, the effects of electrochemical oxidation of carbon fiber surfaces on mechanical interfacial properties of carbon fibers-reinforced polarized-polypropylene matrix composites were studied with various current densities during the treatments. Surface properties of the fibers before and after treatments were observed by SEM, AFM, XPS, and contact angle measurements. Mechanical interfacial properties of the composites were measured in terms of critical stress intensity factor ($K_{IC}$). From the results it was found that $O_{1s}$ peaks of the fiber surfaces were strengthened after electrochemical oxidation which led to the enhancement of surface free energy of the fiber, resulting in good mechanical performance of the composites. It can be concluded that electrochemical oxidation of the carbon fiber surfaces can control the interfacial adhesion between the carbon fibers and polarized-polypropylene in this composites system.

CNT and CNF reinforced carbon fiber hybrid composites by electrophoresis deposition (전기영동법에 의한 탄소나노튜브 및 탄소나노섬유 강화 탄소섬유 하이브리드 복합재료)

  • Choi, O-Young;Lee, Won-Oh;Lee, Sang-Bok;Yi, Jin-Woo;Kim, Jin-Bong;Choe, Hyeon-Seong;Byun, Joon-Hyung
    • Composites Research
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    • v.23 no.3
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    • pp.7-12
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    • 2010
  • In order to increase the electrical conductivity and the mechanical properties of carbon fabric composites, multi-walled carbon nanotubes (MWCNTs) and carbon nanofibers (CNFs) were deposited on carbon fabrics by anodic and cathodic electrophoretic deposition (EPD) processes. In the cathodic EPD, carbon nano-particles and nano-sized Cu particles were simultaneously deposited on the carbon fabric, which gave a synergetic effect on the enhancement of properties as well as the degree of deposition. The hybridization of carbon nano-particles and micron-sized carbon fiber significantly improved the through-the-thickness electrical conductivity. In addition, both MWCNTs and CNFs were deposited onto the carbon fabric for multi-scale hybrid composites. Multi-scale deposition improved the through-the-thickness electrical conductivity, compared to the deposition of either MWCNTs or CNFs.

Effect of Fabricating Temperature on the Mechanical Properties of Spread Carbon Fiber Fabric Composites (스프레드 탄소섬유 직물 복합재료의 성형온도에 따른 기계적 특성에 관한 연구)

  • Eun, Jong Hyun;Gwak, Jae Won;Kim, Ki Jung;Kim, Min Seong;Sung, Sun Min;Choi, Bo Kyoung;Kim, Dong Hyun;Lee, Joon Seok
    • Composites Research
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    • v.33 no.3
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    • pp.161-168
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    • 2020
  • In this paper, we have studied the mechanical properties of thermoplastic carbon fiber fabric composites with spread technology and compression molding temperature were investigated. Carbon fiber reinforcement composites were fabricated using commercial carbon fiber fabrics and spread carbon fiber fabrics. Mechanical properties of the commercial carbon fiber composites (CCFC) and spread carbon fiber composites (SCFC) according to compression molding temperatures were investigated. Thermal properties of the polypropylene film were examined by rheometer, differential scanning calorimetry, thermal gravimetric analysis. Tensile, flexural and Inter-laminar shear test. Commercial carbon fiber reinforcement composites and spread carbon fiber composites were fabricated at 200~240℃ above the melting temperature of the polypropylene film. Impregnation properties according to compression molding temperature of the polypropylene film were investigated by scanning electron microscopy. As a result, as the compression molding temperature was increased, the viscosity of the polypropylene film was decreased. The mechanical properties of the compression molding temperature of 230℃ spread carbon fiber composite was superior.

Effect of Plasma Treatment on Mechanical Properties of Carbon Fibers-reinforced Composites (플라즈마 처리가 탄소섬유강화 복합재료의 기계적특성에 미치는 영향)

  • Oh, Jin-Seok;Lee, Jae-Rock;Park, Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.80-83
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    • 2005
  • In this work, effects of oxygen plasma on surface characteristics of carbon fibers were investigated in mechanical properties interfacial of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by acid/base values, FT-IR, and X-ray photoelectron spectroscopy (XPS). Also, the mechanical properties of the composites were studied in and critical stress intensity factor ($K_{IC}$) and critical strain energy release rate mode II ($G_{IIC}$) measurements. As experimental results, the $O_{lS}/C_{lS}$ ratio of the carbon fiber surfaces treated by oxygen plasma was increased compared to that of untreated ones, possibly due to development of oxygen-containing functional groups. The mechanical properties of the composites, including $K_{IC}$ and $G_{IIC}$ had been improved in the oxygen plasma on fibers. These results could be explained that the oxygen plasma was resulted in the increase of the adhesion of between fibers and matrix in a composite system.

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Influence of Oxygen Plasma Treatment on Impact Behaviors of Carbon Fibers-reinforced Composites (산소 플라즈마 처리가 탄소섬유강화 복합재료의 충격특성에 미치는 영향)

  • Oh, Jin-Seok;Lee, Jae-Rock;Park, Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.23-26
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    • 2005
  • In this work, effects of oxygen plasma on surfc1ce characteristics of carbon fibers were investigated in impact strength of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by acid/base values, FT-IR, and X-ray photoelectron spectroscopy (XPS). Also, the mechanical properties of the composites were studied by impact strength measurements. As experimental results, the $O_{IS}/C_{IS}$ ratio of the carbon fiber surfaces treated by oxygen plasma was increased compared to that of untreated ones, possibly due to development of oxygen-containing functional groups. The mechanical properties of the composites, including impact strength had been improved by the oxygen plasma on fibers. These results could be explained that the oxygen plasma resulted in the increase of the adhesion of between fibers and matrix in a composite system.

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