• Proceedings of the Korean Society For Composite Materials Conference
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• 2002.10a
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• pp.48-51
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• 2002

This paper predicted the thermal conductivity of spun carbon/phenolic composites by the thermal resistance method. This method uses the analogy between the diffusion of heat and electrical charge. To verify the theoretical predictions, the thermal conductivity of spun carbon/phenolic composites was examined experimentally. The reported thermal conductivities of graphite/epoxy composite of a eight harness satin laminate was used of the comparison with the prediction values of the model and it was noticed that a good agreement has been found.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.198-203
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• 1999

2D carbon/carbon composites have been prepared with and without addition of 1, 3 and 5wt% of oxidation inhibitor boron and then heat teated up to 1700, 2000, 2300, 2600 each. This paper presents the effects of boron on the mechanical properties of 2D C/C composites in terms of the acceleration of graphitization and also discussed about the retardation of air oxidation.

• Carbon letters
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• v.6 no.2
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• pp.106-110
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• 2005

In this work, the effects of atmospheric oxygen plasma treatment of carbon fibers on mechanical interfacial properties of carbon fibers-reinforced epoxy matrix composites was studied. The surface properties of the carbon fibers were determined by acid/base values, Fourier-transform infrared spectrometer (FT-IR), and X-ray photoelectron spectroscopy (XPS) analyses. Also, the crack resistance properties of the composites were investigated in critical stress intensity factor ($K_{IC}$), and critical strain energy release rate mode II ($G_{IIC}$) measurements. As experimental results, FT-IR of the carbon fibers showed that the carboxyl/ester groups (C=O) at 1632 $cm^{-1}$ and hydroxyl group (O-H) at 3450 $cm^{-1}$ were observed for the plasma treated carbon fibers, and the treated carbon fibers had the higher O-H peak intensity than that of the untreated ones. The XPS results also indicated that the $O_{1S}/C_{1S}$ ratio of the carbon fiber surfaces treated by the oxygen plasma led to development of oxygen-containing functional groups. The mechanical interfacial properties of the composites, including $K_{IC}$ (critical stress intensity factor) and $G_{IIC}$ (critical strain energy release rate mode II), were also improved for the oxygen plasma-treated carbon fibersreinforced composites. These results could be explained that the oxygen plasma treatment played an important role to increase interfacial adhesions between carbon fibers and epoxy matrix resins in our composite system.

• Composites Research
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• v.31 no.6
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• pp.299-303
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• 2018

In order to improve the interfacial bonding force and reaction polymerization degree of the carbon fiber reinforced nylon 6 composite material, the surface of the existing epoxy-sizing carbon fiber was desized to remove the epoxy and treated with urethane, nylon and phenoxy sizing agent, was observed. The interfacial bond strength of the resized carbon fiber was confirmed by IFSS (Interfacial Shear Strength) and the fracture surface was observed by scanning electron microscope. The results showed that the interfacial bonding strength of the carbon fiber treated with nylon and phenoxy sizing agents was higher than that of urethane - based sizing. It has been found that the urethane - type resizing carbon fiber has lower interfacial bonding strength than the conventional epoxy - sizing carbon fiber. This result shows that the interfacial bonding between carbon fiber and nylon 6 is improved by removing low activity and smoothness of existing carbon fiber.

• Composites Research
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• v.37 no.3
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• pp.197-203
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• 2024

Mechanical, electrical and thermal properties of polymer composites can be improved simultaneously by incorporating carbon fibers (CFs), which are beneficial for improving the mechanical properties, and multi-walled carbon nanotubes (MWCNTs), which are advantageous for improving the conductive properties. In this study, MWCNTs were incorporated into carbon long fiber thermoplastic (CLFT), which has excellent mass production processability and excellent mechanical properties, to control electrical and thermal properties. The mechanical and electrical properties of the prepared composites were most significantly influenced by the amount of filler incorporated. On the other hand, the thermal properties were improved due to the formation of a filler network interconnected by the incorporation of MWCNTs. By adjusting the filler amount, filler composition, and filler network structure of MWCNT-incorporated CLFT, the mechanical, electrical, and thermal properties could be controlled.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07b
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• pp.1091-1091
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• 2005

• Macromolecular Research
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• v.13 no.3
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• pp.194-205
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• 2005

The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08a
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• pp.772-774
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• 2007

The improvement in the field emission parameters, luminescent uniformity, degradation rate and half life has been observed for the thin-multi wall carbon nanotube (t-MWCNT) composite, after incorporating the Zn nanoparticles. The Zn nanoparticles $(diameter\;{\sim}\;100\;{\pm}15\;nm)$ has been incorporated to synthesize the Zn-t-MWCNT composite.

• Elastomers and Composites
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• v.56 no.3
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• pp.113-116
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• 2021

In this study, we report a facile fabrication of multi-walled carbon nanotubes (MWCNTs)-CuO composites synthesized by a microwave method using MWCNTs and copper oxide (CuO). The number of copper hydrate precursors affect the size and number of CuO domains formed along the MWCNTs in the composites. The domain size is controllable from 239 nm to 348 nm. The composites are characterized by transmission electron microscopy, energy dispersive spectrometry, X-ray diffraction (XRD), Raman spectroscopy, and UV-Vis spectroscopy. The CuO produced in the composites is confirmed to be tenorite with a monoclinic crystal structure through the XRD patterns of (-111), (111) and (-202).

• Korean Journal of Materials Research
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• v.30 no.10
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• pp.522-532
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• 2020

Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/㎤, which is 0.017 g/㎤ less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.