• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.3
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• pp.314-321
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• 2024

Due to the depletion of natural aggregate resources, the use of recycled aggregates became an urgent issue. Microcracks generated during production of recycled aggregate and cement paste attached to the surface of aggregate have been the biggest obstacles to promote the use of recycled aggregate. To alleviate such problem, this study attempted the spray and immersion treatment of recycled fine aggregate using mono-ammonium phosphate solution, which is known to be effective for reducing the pH of recycled aggregate. The changes in physical properties before and after treatment were observed, and the compressive strength of mortar specimen was evaluated. According to the experimental results, the absorption capacity of the recycled fine aggregate increased with reduction in pH after mono-ammunium phosphate treatment. Calcium hydroxide and ettringite was removed, and skeletal density of recycled fine aggregate increased due to the formation of hydroxyapatite. Despite the increase in absorption capacity, the compressive strength of the mortar increased and it seems to be associated with the increase in adhesion strength at the interface between cement paste and recycled fine aggregate. When the concentration of ammonium monophosphate aqueous solution was excessive (immersion: 15% and 20%, spraying 20%), the compressive strength of the mortar decreased, which seemed to be related to the increase in the absorption capacity caused by the the excessive dissolution of the hydration products such as portlandite and ettringite.

• Clean Technology
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• v.3 no.2
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• pp.87-93
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• 1997

A new process has been developed for nitrate and other salts removals from polluted waters. Alumina cement and calcium oxide served as precipitating agents to remove nitrate with stirring at basic pH. Low content of alumina in the commercialized alumina cements resulted in a increasing in nitrate removal yield. It is found that the compositions of aluminium and calcium are the most important factors in successful nitrate insolubilization. In order to remove high concentration of nitrate in polluted water, multi-stage precipitation was found to be very effective. Sulfate, chloride, and phosphate ions as well as nitrate were also removed by the precipitated reaction. After precipitation, post-treatments including Na2CO3 addition and neutralization with acid alleviated the level of aluminium and calcium in the treated water.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.463-469
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• 2016

In this paper, compressive strength and water permeability performance for two types of crack self-healing materials such as SH-PO-0 composed of mineral admixtures(expansive agent, swelling material and crystal growth agent) and SH-PO-(5, 15, 30) blended with SH-PO-0 and phosphate additive(PO) dissolving easily calcium ion, were evaluated. The test results show that the water flow of SH-PO-0 decreased steeply at the early age although compressive strength decreased about 9% at 28 days compared with OPC. The higher PO replacement ratio is, the lower compressive strength and more improved water permeability performance is, and thus, based on such results, adequate PO replacement ratio is 15%. It is also found that the self-healing performance of SH-PO-15 was quite improved at the early ages and however, the performance of SH-PO-15 is similar to one of SH-PO-0 at long-term ages, and 28 days compressive strength of SH-PO-15 decreased about 8% compared with SH-PO-0. In addition, it is confirmed from the analysis of SEM-EDS that calcium ions of SH-PO-15 were crystallized more than those of SH-PO-0.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.152-160
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• 2021

Converter steel slag(BOF slag) is a vast amount of solid waste generated in the steelmaking process which has very low utilization rate in Korea. Due to the presence of free CaO which can derive bad volume stability in BOF slag, it usually land filled. For recycling BOF and identify its applicability as fine aggregate, this study investigates the fundamental characteristics of mortar with cement replaced ferronickel slag(FNS), which has the potential to be used as a binder. The results suggest that the mineral phases of BOF slag mainly include larnite(CaSiO₄), mayenite(Ca₁₂Al₁₄O₃₃) and wuestite(FeO) while olivine crystallines are shown in FNS. The results of flow and setting time reveals that the flowability and process of hardening increased when the amount of FNS and BOF slag incorporated was increased. The length change shows that the amount of change in the length of the mortar was almost constant regardless of mix proportion while compressive strength was reduced. Micro structure test results revealed that FNS or/and BOF slag mix took a long time to react in the cement matrix to form a complete hydration products. To achieve the efficient utilization of B OF slag as construction materials, proper replacement rate is necessary.