• 제목/요약/키워드: calcite

검색결과 626건 처리시간 0.027초

Tribological enhancement of $CaCO_3$dissolution during scanning force microscopy

  • Kjm, Jong-Min;Hwang, Do-Jin;Lee, Joo-sun;Kim, Myoung-Won
    • Journal of Korean Vacuum Science & Technology
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    • 제4권4호
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    • pp.102-106
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    • 2000
  • We report scanning force microscope (SFM) observations of enhanced calcite dissolution in aqueous solution due to mechanical stimulation induced by the SFM tip. Images and mechanical treatment were performed in saturated ($\geq$ 60 ${\mu}{\textrm}{m}$) CaCO$_3$ solution adjusted to pH~9. Small area scans of monolayer steps significantly increased the step velocity in the scanned area (in the direction corresponding to dissolution) when the applied contact force is above about 160 nN fer the tips employed. The step velocity could be increased at least an order of magnitude by scanning at even higher contact forces (e.g.,270nN). This enhancement is a function of step orientation relative to the calcite lattice. Indentations near preexisting steps also locally enhance the step velocity. We present evidence that the higher dissolution rates are caused by stress-induced increases in the rate of double-kink nucleation.

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연속식 탄산칼슘 결정화기에서 교반속도와 온도가 입도분포에 미치는 영향 (Effect of RPM and Temperature on the CSD in the CMSMPR Calcium Carbonate Crystallizer)

  • 한현각;정옥희;임미희;김진아
    • Korean Chemical Engineering Research
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    • 제44권3호
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    • pp.289-293
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    • 2006
  • 탄산칼슘을 제조하는 연속식 결정화 공정에서 결정의 입도분포에 대한 온도와 교반속도 영향을 연구하였다. 연속식조업에서 용액의 산도 변화는 적었다. 교반속도가 300 RPM 이하, 용액의 온도가 낮으면 탄산칼슘 결정의 부피 평균크기는 안정하였고, 전자현미경 사진 관찰에서 calcite와 aragonite가 만들어졌음을 알 수 있었다

Evolution of reaction zones in reactive barriers consisting of calcite and glass beads

  • Jeong Gon, Kim;Gwang Man, Lee;Ik Hwan, Go
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.19-22
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    • 2004
  • Two-dimensional modeling studies using TOUGHREACT were conducted to investigate the coupling between flow and transport developed as a consequence of differences in density, dissolution/ precipitation, and medium heterogeneity. The model includes equilibrium reactions for aqueous species, kinetic reactions between tile solid phases and aqueous constituents, and full coupling of porosity and permeability changes resulting from precipitation and dissolution reactions in porous media. Generally, the evolutions in the concentrations of the aqueous phase are intimately related to the reaction-front dynamics. Plugging of the medium contributed to significant transients in patterns of flow and mass transport.

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석고(石膏)의 본초고증(本草考證) 및 좌용석고(左用石膏)의 품질(品質) (Study for the quality and the herbalogical Gypsum)

  • 이장천
    • 대한한의학방제학회지
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    • 제11권2호
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    • pp.61-82
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    • 2003
  • Objectives: This study has been done to make sure the Gypsum's standardization in medical use. Gypsum has a quality for removing pathogenic heat from the stomach meridian function and headache. Methods: I studied the herbalogical Gypsum and compared its' compositions and character before and after high temperature burning. Results: Gypsum and Lishi(理石) are the sulfate which is made of $CaSO_4{\cdot}2H_2O$, Feldspar is a Calcite, Hanshuishi(寒水石) and Ningshuishi(凝水石) are not a Gypsum but a Magnesium Sulfate($MgSO_4$) and Kalium Sulfate($K_2SO_4$). Conclusion: Real Gypsum is supposed to be Yiong cheng${\setminus}$(應城) Gypsum. Chemical edible Gypsum isn't appropriated to be used in medicine.

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용골(龍骨)(부용치)(附龍齒)의 품질표준(品質標準) 및 포제전후의 성분비교(成分比較) (Study for the standardization of Os Draconis and comparison composition before and after using processed method on Os Draconis)

  • 이장천
    • 대한한의학방제학회지
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    • 제11권1호
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    • pp.171-195
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    • 2003
  • Objectives: This experimental study has been done to compare the Os Draconis composition before and after using processing method. Os Draconis has a quality for calming the liver meridian function and relaxation the mind. Methods: I studied the Os Draconis and processed Os Draconis by vinegar to compare the compositions and its' character. Results: Os Draconis is not a dinosaur's bone fossil but a mammal's bone fossil which has a Calcite mineral, an Apatite mineral, $SiO_2\;Al_2$ O, etc. Os Draconis contains a main ingredients CaO>50.00%. Processed Os Draconis which is heated and soaked in vinegar changes to weak condition Conclusion: Os Draconis is supposed to be a mammal's bone fossil. Some Os Draconis has a radioactive substance like a U, Th so we pay heed to deal with it in a medical clinic.

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스트론튬 격리화를 위한 요소 분해 박테리아의 분리 및 특성 연구 (Isolation and Characterization of Ureolytic Bacteria for Biosequestration of Strontium)

  • 최재호;강창호;한상현;곽대영;오수지;소재성
    • KSBB Journal
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    • 제28권3호
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    • pp.165-169
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    • 2013
  • In this study, 52 ureolytic bacterial strains were newly isolated from various environments. From these, 2 strains (TB-15 and TB-22) were selected based on their high urease activity. XRD spectra clearly showed presence of various sequestration products such as calcite and strontianite in samples. TB-22 showed 20~30% higher survivability upon Sr concentration (20 mM) than Sporosarcina pasteurii KCTC 3558. TB-15 and TB-22 showed 80~90% higher survivability at pH 6 than S. pasteurii. The results demonstrated that the 2 isolates colud be good candidates for the bioremediation of Sr contaminated sites.

경남고성지역(慶南固城地域) 동광상(銅鑛床)의 성인(成人)에 관한 연구(硏究) (Genesis of the Copper Deposits in Goseong District, Gyeongnam Area)

  • 박희인;최석원;장호완;이민성
    • 자원환경지질
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    • 제16권3호
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    • pp.135-147
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    • 1983
  • The copper deposits in Goseong district, Gyeongnam area are fissure filled copper veins emplaced on Cretaceous Goseong formation and andesitic rocks. Occurrence of ore veins and mineral paragenesis suggest a division of the hydrothermal mineralization into three stages: stage 1, deposition of arsenopyrite, pyrite, quartz, chlorite and epidote; stageII, deposition of pyrite, chalcopyrite, galena, sphalerite, electrum, pyrargyrite, tetrahedrite, silver sulfosalt minerals, quartz, chlorite, sericite and miner amount of calcite; stage III, formation of barren calcite veins. Filling temperature of fluid inclusions in quartz of stage II, range from 260 to 360 C and salinities from 6.2 to 13.6 weight percent NaCi equivalent.

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원전콘크리트의 탄산화에 의한 미세구조 변화에 관한 연구 (A Study on the Microstrucutre Changes by carbonation in NPP Concrete)

  • 이장화;김도겸;김기범;이호재
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2011년도 정기 학술대회
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    • pp.400-403
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    • 2011
  • 본 논문에서는 시차열중량분석법과 X-선 회절분석법을 이용한 원전콘크리트의 탄산화에 의한 열화도 평가를 진행하였으며 두 가지 정성적 분석방법을 이용한 반정량적 평가 방법을 개발하였다. 원자력발전소 건설에 사용된 동일한 콘크리트 배합을 사용한 시편을 촉진 탄산화 시험장치에 28, 56, 91, 180, 365일 기간에 걸쳐 노출시켜 탄산화를 진행하였으며 노출된 시편은 시차열중량분석법, X-선 회절분석법을 이용하여 탄산화에 따라 발생된 열화생성물의 양을 정성적으로 분석하였다. 그 결과, 탄산화로 인해 발생되는 Calcite의 양이 노출기간에 따라 점차적으로 증가되는 것이 확인되었으며, Calcite의 생성을 위해 이산화탄소와 반응하는 Portlandite의 양이 점차적으로 감소되는 것이 확인되었다. 본 논문에서는 위의 언급된 두 방법의 관계성을 통해 열화도 평가를 진행하였다.

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Effect of microorganism on engineering properties of cohesive soils

  • Yasodian, Sheela Evangeline;Dutta, Rakesh Kumar;Mathew, Lea;Anima, T.M.;Seena, S.B.
    • Geomechanics and Engineering
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    • 제4권2호
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    • pp.135-150
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    • 2012
  • This paper presents the study of the effect of microorganism Bacillus pasteurii on the properties such as Atterbergs' limit and unconfined compressive strength of cohesive soils. The results of this study reveal that the liquid limit and plasticity index for all clay soils decreased and the unconfined compressive strength increased. Decrease in plasticity index is very high for Kuttanad clay followed by bentonite and laterite. The unconfined compressive strength increased for all the soils. The increase was high for Kuttanad soil and low for laterite soil. After 24 h of treatment the improvement in the soil properties is comparatively less. Besides the specific bacteria selected Bacillus pasteurii, other microorganisms may also be taking part in calcite precipitation thereby causing soil cementation. But the naturally present microorganisms alone cannot work on the calcite precipitation.