• Journal of the Microelectronics and Packaging Society
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• v.18 no.4
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• pp.27-32
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• 2011

Tin nanoparticles were synthesized at room temperature by a compulsive reduction reaction using tin(II) acetate and tin(II) chloride precursors. When an identical amount (0.015 g) of polyvinyl pyrrolidone (PVP) was added, it was concluded that the probability of abnormally big particles forming increased with an increase in PVP molecular weight, resulting in the wide distribution of Sn nanoparticles. Differential scanning calorimetry measurements were carried out using diethylene glycol solution containing synthesized tin nanoparticles. When the population of specific particles with sizes below 35 nm was adequate, the melting point depression peaks of tin nanoparticles corresponding to the specific size were observed besides an evaporation endothermic peak of DEG during the first heating. Because DEG was evaporated and tin nanoparticles in contact became molten and coarsened during the first heating, a melting peak of bulk tin was only observed at $232^{\circ}C$ during the second heating.

• Journal of the Korea Concrete Institute
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• v.14 no.2
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• pp.207-215
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• 2002

This study is focusing on mixing the foamed concrete incorporated by waste expanded polystyrene(W-EPS), investigating the physical properties and offering a proper quality control method to the field engineers. Two types of W-EPS (type A and type B) were studied. Type A (B) had globular (crushed) shape and diameter of 3-5 (1-2) mm. The results show that the flow was suddenly reduced with increasing mixing quantity of two types, but it satisfies KS F 4039 until 60 ％ of mixing rate. In general, the absorption rate was suddenly reduced with increased mixing quantity of two types especially, in type A. Apparent specific gravity was 0.36∼0.53 and reduced with increasing mixing quantify of type A. But it increased in case of type B. Compressive strength and heat conduction rate increased with mixing with W-EPS than non-mixing W-EPS but reduced with mixing too much W-EPS. Based ong the results, it is believed that mixing with W-EPS can improve the recycle of industrial wastes and produce the high quality foamed concrete.

• Journal of the Korean Chemical Society
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• v.24 no.4
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• pp.288-294
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• 1980

Methanolysis rate constants were determined for $CH_3O(CO)Cl,\;CH_3S(CO)Cl\;and\;CH_3S(CS)Cl\;in\;CH_3OH-CH_3CN$ mixtures. Results show that the rates are not predominantly influenced by the bulk solvent properties but are partly influenced by specific electrophilic solvation.Polarity of the solvent is not a dominant factor but it nevertheless plays a role in charge stabilization of the $S_N1$ like transition state. The methanolysis proceeds through $S_N1$ mechanism for $CH_3S(CS)Cl$ for which both specific solvation of leaving group by methanol and charge stabilization by a high dielectric medium are important, while for $CH_3O(CO)Cl\;methanolysis occurs\;via\;S_N2$ mechanism in which both of the solvent effects are unimportant.

• Journal of the Korean Ceramic Society
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• v.13 no.1
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• pp.35-44
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• 1976

The effect of quartz which exists in clays, especially in kaolin used for the production of chamotte sagger, on the strength of refractory was examined. In this study, a mixture of chamotte 50%, kaolin 25%, plastic clay 25% in ternary component system was selected as a batch composition. To this mixture 1%, 3% and 5% of feldspar and sericite were added respectively. The plastic clay used here was separated under 170 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. In order to change the particle size and the content of quartz, the kaolin was separated under 60, 115, 170 and 325 mesh by wet process, substituted quartz for coarse parts of it. Chamotte was classified into three grades, coarse (5-10mesh): medium (10-20mesh): fine(20-115mesh) and the ratio was 1:1:1. Samples were formed in 0.8xIx10cm size with 12.5% water at 160kg/$\textrm{cm}^2$ pressure, and fired at 130$0^{\circ}C$ for 1 hr. The fired samples were ivnestigated by means of x-ray diffraction analysis and microscopic observation, and the physical properties of them were also examined, such as firing shrinkage, apparent specific gravity and bulk specific gravity, apparent porosity, water absorption and modulus of rupture. The obtained results are as follows: 1. When screened kaolin with low content of quartz was added to fixed chamotte-plastic clay system, the sample lowered modulus of rupture and increased apparent porosity as the size of kaolin became finer. 2. When kaolin under 325 mesh with 7.2-15.81% quartz between 60-325 mesh was added to fixed chamotte-plastic clay system, the sample had higher apparent porosity and lower modulus of ruputure as the size and the amount of quartz became larger. 3. The addition of feldspar and sericite to chamotte-plastic clay system improved apparent porosity and modulus of rupture. The effect of feldspar was better when quartz content was low, although that of sericite was better than quartz content was high.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.2
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• pp.166-171
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• 2014

This experimental study considers manufacturing method of the non-portland cement matrix for the light-weight building materials using blast furnace slag, paper ash, fly ash and polysilicon sludge the industrial by-product. For the experiment, we used paper ash by means of the foaming agent and alkali activator to make non-portland cement light-weight matrix. Various specimens were prepared with different types and addition ratios of the alkali activator. Then, the properties of these specimens were investigated by compressive strength test, bulk specific gravity. As a results, it was judged that experiment results of non-portland cement matrix with specific waste resources and alkali activators were useful as basic data for mixtures design and evaluation properties of lightweight non-portland cement building material.

• Proceedings of the KSRS Conference
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• 2007.10a
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• pp.306-309
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• 2007

Japanese Ocean Flux Data Sets with Use of Remote Sensing Observations (J-OFURO) includes global ocean surface heat flux data derived from satellite data and are used in many studies related to air-sea interaction. Recently latent heat flux data version 2 was constructed in J-OFURO. In version 2 many points are improved compared with version 1. A bulk algorithm used for estimation of latent heat flux is changed from Kondo (1975) to COASRE 3.0(Fairall et al., 2005). In version 1 we used NCEP reanalysis data (Reynolds and Smith, 1994) as SST data. However, the temporal resolution of the data is weekly and considerably low. Recently there are many kinds of global SST data because we can obtain SST data using a microwave radiometer sensor such as TRMM/MI and Aqua/AMSR-E. Therefore, we compared many SST products and determined to use Merged satellite and in situ data Global Daily (MGD) SST provided by Japan Meteorological Agency. Since we use wind speed and specific humidity data derived from one DMSP/SSMI sensor in J-OFURO, we obtain two data at most one day. Therefore, there may be large sampling errors for the daily-mean value. In order to escape this problem, multi-satellite data are used in version 2. As a result we could improve temporal resolution from 3-days mean value in version 1 to daily-mean value in version 2. Also we used an Optimum Interpolation method to estimate wind speed and specific humidity data instead of a simple mean method. Finally the data period is extended to 1989-2004. In this presentation we will introduce latent heat flux data version 2 in J-OFURO and comparison results with other surface latent heat flux data such as GSSTF2 and HOAPS etc. Moreover, we will present validation results by using buoy data.

• Journal of Digital Convergence
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• v.13 no.9
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• pp.287-295
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• 2015

The IPTV service has to be converted into an unified media format that fits for a variety of terminal equipments in terms of the bulk high-capacity media contents, and is spending a lot of time in the conversion time of contents including the process of collecting the media contents and extracting the information for conversion. In order to solve the problem, this paper designed the database in accordance with the automatic collection of time, and proposed a system that could increase the productivity of the contents through the automation process of the entire process using the media server and the transcoder. The media server collected contents and extracted information automatically with respect to the contents servers placed in specific locations and the media files of the storage whereas the transcoder conducted the automatic upload of the converted results to a specific server through the process of automatic conversion. As a result, the various convergence through compared to existing conversion method could minimized unnecessary waste of time.

• Journal of Electrochemical Science and Technology
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• v.12 no.2
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• pp.204-211
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• 2021

We report, synthesis of high surface area composite carbon aerogel using additive based polymerization technique by incorporating graphitic porous carbon as additive. This additive was separately prepared using sol-gel polymerization of resorcinol-furfuraldehyde in iso-propyl alcohol medium at much above the routine gelation temperature to yield porous carbon (CA-IPA) having graphitic layered morphology. CA-IPA exhibited a unique combination of meso-pore dominated surface area (~ 700 m²/g) and good conductivity of ~ 300 S/m. The composite carbon aerogel (CCA) was synthesized by traditional aqueous medium based resorcinol-formaldehyde gelation with CA-IPA as additive. The presence of CA-IPA favored enhanced meso-porosity as well as contributed to improvement in bulk conductivity. Based on the surface area characteristics, CCA-8 composition having 8% additive was found to be optimum. It showed specific surface area of ~ 2056 m²/g, mesopore area of 827 m²/g and electrical conductivity of 180 S/m. The electrode formed with CCA-8 showed improved electrochemical behavior, with specific capacitance of 148 F/g & ESR < 1 Ω, making it a better choice as super capacitor for energy storage applications.

• Journal of the Korean Wood Science and Technology
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• v.50 no.4
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• pp.219-236
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• 2022

Wood-based nanocomposite electrode materials were synthesized for application in supercapacitors by mixing nanostructured hematite (Fe₂O₃) with highly porous activated carbon (AC) produced from the wood-waste of Pinus roxburghii. The AC was characterized using various instrumental techniques and the results showed admirable electrochemical properties, such as high surface area and reasonable porosity. Firstly, AC was tested as an electrode material for supercapacitors and it showed a specific capacitance of 59.02 Fg^-1 at a current density of 1 Ag^-1, cycle life of 84.2% after 1,000 cycles (at a current density of 3 Ag^-1), and energy density of 5.1 Wh/kg at a power density of 135 Wkg^-1. However, when the AC was composited with different ratios of Fe₂O₃ (1:1, 2:1, and 1:2), there was an overall improvement in its electrochemical performance. Among the 3 ratios, 2:1 (AC:Fe₂O₃) had the best specific capacitance of 102.42 Fg^-1 at 1 Ag^-1, cycle life of 94.4% capacitance after 1,000 cycles (at a current density of 3 Ag^-1), and energy density of 8.34 Wh/kg at a power density of 395.15 Wkg^-1 in 6 M KOH electrolyte in a 3-electrode experimental setup with a high working voltage of 1.55 V. Furthermore, when Fe₂O₃ was doubled, 1:2 (AC:Fe₂O₃), the electrochemical capacitive performance of the electrode twisted and deteriorated due to either the accumulation of Fe₂O₃ particles within the composite or higher bulk resistance value of pure Fe₂O₃.

• Korean Journal of Agricultural Science
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• v.7 no.2
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• pp.145-155
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• 1980

An engineering design of the machines and equipment for processing grain as well as an understanding of processing itself need the knowledge of thermal properties of grain. Thermal properties of grain are thermal conductivity, thermal diffusivity and specific heat. Knowledge of any two and the bulk density of grain enables the third to be calculated. Several workers have investigated these properties, with special emphasis on thermal conductivity and diffusivity. However, some information is available on the specific heat of rough rice and barley but it is available only for a foreign variety of grain and for as a function of moisture content only. The objectives of this study were to develop a model for the specific heat of rough rice and barley which were a staple products in Korea as a function of initial temperature, moisture content and porosity of grain with cooling curve method, and to analyze the effect of these factors on the specific heat of rough rice and barley. The results of this study are summarized as follows; 1. The specific heat was $1.8209-2.7041kJ/kg\;^{\circ}K$ for Naked barley, 1.8862-2.5625 k.l/kg K for Covered barley, $1.5167-2.3779kJ/kg\;^{\circ}K$ for Japonica rice and $1.5260-2.3981kJ/kg\;^{\circ}K$ for Indica rice. 2. The model for the specific heat of rough rice and barley as a function of initial temperature, moisture content and porosity of grain was developed. 3. Specific heat of rough rice was decreased with initial temperature, but specific heat of barley was increased with initial temperature. 4. On the whole specific heat of sample grain was increased with moisture content of grain. 5. Specific heat of the grain was found to decrease with porosity except Indica rice.