• Title/Summary/Keyword: bulk decay

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1차원 무기 반도체 신 물질 재료의 연구 개발 동향

  • Ryu, Hak-Gi
    • Ceramist
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    • v.21 no.2
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    • pp.29-37
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    • 2018
  • In order to overcome the problems of existing low-dimensional materials (carbon nanotubes, graphene, transition metal dichalcogenides, etc) researches on new 1D materials have been studied. In the case of $LiMo_3Se_3$ and $Mo_6S_{9-x}I_x$, continuous researches have been carried out for 3D bulk synthesis and atomic scale dispersion. Recently, quantum confinement effect of $LiMo_3Se_3$ and bio-stability of $Mo_6S_{9-x}I_x$ have been proven and various applications have started to be studied. In addition, device application results using new 1D materials such as $Sb_2Se_3$ (optoelectronic devices using the property of effectively reducing exciton decay due to no dangling bond) and $VS_4$ (electrochemical energy storage using the space between 1-D nanostructures) have been reported very importantly. Therefore, it can be claimed that it has reached a very important time to find and synthesize new 1D materials and to report various characteristics not existing.

Investigation of short-term stability in high efficiency polymer : nonfullerene solar cells via quick current-voltage cycling method

  • Lee, Sooyong;Seo, Jooyeok;Kim, Hwajeong;Song, Dong-Ik;Kim, Youngkyoo
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2496-2503
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    • 2018
  • The short-term stability of high efficiency polymer : nonfullerene solar cells was investigated by employing a quick (ten cycles) current density-voltage (J-V) cycling method. Polymer : nonfullerene solar cells with initial power conversion efficiency (PCE) of >10% were fabricated using bulk heterojunction (BHJ) films of poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)-benzo[1,2-b:4,5b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5,7'-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T) and 3,9-bis(2-methylene-((3-(1,1-dicyanomethylene)-6/7-methyl)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3'-d']-s-indaceno[1,2-b:5,6-b']dithiophene (IT-M). One set of the BHJ (PBDB-T : IT-M) films was thermally annealed at $160^{\circ}C$ for 30min, while another set was used without any thermal treatment after spin-coating. The quick J-V scan (cycling) measurement disclosed that the PCE decay was relatively slower for the annealed BHJ layers than the unannealed (as-cast) BHJ layers. As a result, after ten cycles, the annealed BHJ layers delivered higher PCE than the unannealed BHJ layers due to higher and more stable trend in fill factor. The present quick J-V cycling method is simple but expected to be useful for the prediction of short-term stability in organic solar cells.

Space Charge Phenomena in Polyimide Films and Effects of Absorbed Water (폴리이미드 박막의 공간전하현상 및 수분의 영향)

  • Yun, Ju-Ho;Choi, Yong-Sung;Hwang, Jong-Sun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.82-85
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    • 2008
  • Polyimide is widely used as a high-temperature insulating material. Space charge distributions in polyimide (PI) films strongly depend upon electric field, temperature, water content and so on. We observed space charge distributions in PI films with various water contents. When a dc field was applied to as-received PI films or water-treated PI films, positive and negative homo space charges were observed near the respective electrodes at 333 K. In dried PI films, the homo space charges were much reduced, and positive and negative hetero space charges in the bulk were clearly observed. The space charge amounts in water-treated PI films were smaller than in as-received ones, while the current density in water-treated PI film was larger than that in as-received one by two or more orders of magnitude. These suggest not only that the charge injection from the electrode is enhanced by absorbed water but also that absorbed water makes carriers mobile. The decay of space charge was also faster in water-treated PI than in as-received or dried one. This also supports the enhancement of apparent mobilities of carriers in PI by absorbed water.

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Fabrication arid Performance Tests of Flywheel Energy Storage System using High Tc Superconducting Bearing (고온초전도체 베어링을 사용하는 에너지 저장용 플라이휠 장치의 제작 및 성능 평가)

  • Lee, Ho-Jin;Kim, Ki-Baik;Koh, Chang-Seop;Lee, Soo-Hoon;Hong, Gye-Won
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.310-314
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    • 1999
  • A prototype of Flywheel Energy Storage System with high Tc superconducting bearings was fabricated and tested to verify its applicability for the energy industry. The moment of inertia of assembled wheel with rotor magnets is about 1.072${\times}$10$^{-1}$ Kg-m$^2$. The wheel was designed to withstand its integrity up to the rotation speed of 20,000 rpm. YBCO bulk superconductors prepared by seed growth method were used as bearing to levitate and stabilize the rotating wheel. High speed rotation of the flywheel without mechanical contact was achieved by using specially designed Halbach type motor. The flywheel system showed very high stability during test operation performed up to the speed of about 10,000rpm. The energy loss measured by free decay test performed between 9,300 rpm and 7,000 rpm was calculated as about 45 W.

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Application of Rechlorination for Adequate Disinfection Ability in Water Distribution System (관로 내 적정소독능 확보를 위한 재염소 기법의 적용)

  • Lee, Doo-Jin;Kim, Young-Il;Lee, Jong-Min;Jung, Nam-Jung;Kim, Yong-Woon
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.5
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    • pp.701-707
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    • 2006
  • Disinfectant residual should be maintained to achieve biological stability during distribution of treated water. The wide distribution of retention times associated with storage and transport of water in a network and the reactivity of disinfectants make it difficult to maintain adequate residuals at critical locations. Rechlorination at some intermediate locations may reduce the total disinfectant dose while keeping residuals within specified limits throughout the water distribution system. In order to select the adequate location of rechlorination for achieving to maintain of residual chlorine throughout the distribution system, EPANET was used in this study. EPANET was well predicted chlorine transport and residual loss in the distribution system. Location of rechlorination was selected to maintain 0.4mg/L of residual chlorine throughout a water distribution system by field investigation and model simulation. The quantity of chlorine may reduced 36.7% and provided smooth residual between 0.42 and 0.60mg/L, when rechlorination would be used continuously at strategic location within the distribution system.

Turbulent Flow Field Structure of Initially Asymmetric Jets

  • Kim, Kyung-Hoon;Kim, Bong-Whan;Kim, Suk-Woo
    • Journal of Mechanical Science and Technology
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    • v.14 no.12
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    • pp.1386-1395
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    • 2000
  • The mear field structure of round turbulent jets with initially asymmetric velocity distributions is investigated experimentally. Experiments are carried out using a constant temperature hot-wire anemometry system to measure streamwise velocity in the jets. The measurements are undertaken across the jet at various streamwise stations in a range starting from the jet exit plane and up to a downstream location of twelve diameters. The experimental results include the distributions of mean and instantaneous velocities, vorticity field, turbulence intensity, and the Reynolds shear stresses. The asymmetry of the jet exit plane was obtained by using circular cross-section pipes with a bend upstream of the exit. There pipes used here include a straight pipe, and 90 and 160 degree-bend pipes. Therefore, at the upstream of the upstream of the pipe exit, secondary flow through the bend mean streamwise velocity distribution could be controlled by changing the curvature of pipes. The jets into the atmosphere have two levels of initial velocity skewness in addition to an axisymmetric jet from a straight pipe. In case of the curved pipe, a six diameter-long straight pipe section follows the bend upstream of the exit. The Reynolds number based on the exit bulk velocity is 13,400. The results indicate that the near field structure is considerably modified by the skewness of an initial mean velocity distribution. As the skewness increases, the decay rate of mean velocity at the centerline also increases.

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Direct Numerical Simulation of Strongly-Heated Internal Gas Flows with Large Variations of Fluid Properties (유체의 물성치변화를 고려한 수직원형관내 고온기체유동에 관한 직접수치모사)

  • Bae, Joong-Hun;Yoo, Jung-Yul;Choi, Hae-Cheon;You, Jong-Woo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.11
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    • pp.1289-1301
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    • 2004
  • Direct numerical simulation (DNS) of strongly-heated air flows moving upward in a vertical tube has been conducted to investigate the effect of gas property variations on turbulence modification. Three heating conditions(q$_1$$^{+}$=0.0045, 0.0035 and 0.0018) are selected to reflect the experiment of Shehata and McEligot (1998) at the inlet bulk Reynolds numbers of 4300 and 6000. At these conditions, the flow inside the heated tube remains turbululent or undergoes a transition to subturbulent or laminarizing flow. Consequently, a significant impairment of heat transfer occurs due to the reduction of flow turbulence. The predictions of integral parameters and mean profiles such as velocity and temperature distributions are in excellent agreement with the experiment. The computed turbulence data indicate that a reduction of flow turbulence occurs mainly due to strong flow acceleration effects for strongly-heated internal gas flows. Thus, buoyancy influences are secondary but not negligible especially for turbulent flow at low heating condition. Digital flow visualization also shows that vortical structures rapidly decay as the heating increases.s.

Correlation between the temperature and elastic properties of the light guide plate in edge-lit light-emitting-diode backlights

  • Kim, Jae-Hyun;Kim, Tae-Hyun;Lee, Byung-Woo;Seo, Jae-Seok;Ko, Jae-Hyeon
    • Journal of Information Display
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    • v.12 no.1
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    • pp.23-27
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    • 2011
  • The correlation between the temporal and spatial variations of the elastic constant and temperature change was examined for a light guide plate (LGP) adopted in the edge-lit light-emitting-diode backlight for mobile applications, using the micro- Brillouin light scattering method. The velocity of sound and the elastic constant $C_{11}$ of an LGP made from bisphenol-A polycarbonate (PC) were investigated as functions of temperature, time, and position on the LGP. The temporal variation of $C_{11}$ exhibited an exponential decay, while the spatial variation of $C_{11}$ reflected the temperature distribution on the LGP. The glass transition temperature of the PC LGP was found to be located at $155^{\circ}C$. The result showed that systematic transformation between the elastic property and the temperature is possible and that the temperature distribution on the bulk LGP can be accurately probed via the present experiment method, without using any special temperature measurement equipment.

Space Charge Phenomena in Polyimide Films (폴리이미드 박막의 공간전하현상)

  • Yun, Ju-Ho;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.311-312
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    • 2007
  • Polyimide is widely used as a high-temperature insulating material. Space charge distributions in polyimide (PI) films strongly depend upon electric field, temperature, water content and so on. We observed space charge distributions in PI films with various water contents. When a dc field was applied to as-received PI films or water-treated PI films, positive and negative homo space charges were observed near the respective electrodes at 333 K. In dried PI films, the homo space charges were much reduced, and positive and negative hetero space charges in the bulk were clearly observed. The space charge amounts in water-treated PI films were smaller than in as-received ones, while the current density in water-treated PI film was larger than that in as-received one by two or more orders of magnitude. These suggest not only that the charge injection from the electrode is enhanced by absorbed water but also that absorbed water makes carriers mobile. The decay of space charge was also faster in water-treated PI than in as-received or dried one. This also supports the enhancement of apparent mobilities of carriers in PI by absorbed water.

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A Research Trend on High Density Polyethylene Electrical Strength (폴리이미드 박막의 공간전하현상에 관한 연구 동향)

  • Choi, Keun-Ho;Oh, Chang-Keun;Shin, Hyun-Man;Hwang, Jong-Sun;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1984-1985
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    • 2007
  • Polyimide is widely used as a high-temperature insulating material. Space charge distributions in polyimide (PI) films strongly depend upon electric field, temperature, water content and so on. We observed space charge distributions in PI films with various water contents. When a dc field was applied to as-received PI films or water-treated PI films, positive and negative homo space charges were observed near the respective electrodes at 333 K. In dried PI films, the homo space charges were much reduced, and positive and negative hetero space charges in the bulk were clearly observed. The space charge amounts in water-treated PI films were smaller than in as-received ones, while the current density in water-treated PI film was larger than that in as-received one by two or more orders of magnitude. These suggest not only that the charge injection from the electrode is enhanced by absorbed water but also that absorbed water makes carriers mobile. The decay of space charge was also faster in water-treated PI than in as-received or dried one. This also supports the enhancement of apparent mobilities of carriers in PI by absorbed water.

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