• Fibers and Polymers
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• 제1권2호
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• pp.76-82
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• 2000

A series of random copolyesters having various compositions were synthesized by bulk copolymerization of bishydroxyethyl terephthalate (BHET) with 1,4-cyclohexane dimethanol (CHDM) or dimethyl isophthalate (DMI). CHDM and DMI content was less than 10 wt%. For the synthesized copolyesters, isothermal crystallization rate, melting behavior, and equilibrium temperature were investigated by calorimetry and by Avrami and Hoffman-Weeks equation. Crystalline lattice and morphology were studied by WAXD and SEM. Regardless of the composition, the value of the Avrami exponent was about 3, which indicates that crystallization mechanism of the copolyester was similar to those of PET homopolymer. Incoporation of CHDM or DMI units in PET backbone decreased the crystallization rate of the copolyesters. Surface free energy of copolyesters was evaluated using the newly proposed equation. The value of surface free energy was about 189$\times$$10^{-6}$/$J^{2}$/$m^{4}$ regardless of comonomer contents. This result is in good agreement with that of PET homopolymer.

• International Journal of Control, Automation, and Systems
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• 제3권2호
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• pp.252-257
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• 2005

In this work, we propose a simple but efficient method to design a target temperature trajectory for pulling speed tracking control of the crystal grower in the Czochralski crystallization process. In the suggested method, the model predictive control strategy is used to incorporate the complex dynamic effect of the heater temperature on the pulling speed into the temperature trajectory design quantitatively. The feedforward trajectories designed by the proposed method were implemented on 200 mm and 300 mm silicon crystal growers in the commercial Czochralski process. The application results have demonstrated its excellent and consistent tracking performance of pulling speed along whole bulk crystal growth.

• 한국산학기술학회논문지
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• 제3권3호
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• pp.183-188
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• 2002

Antibacterial glass ceramics composed of $5Li_2O{\cdot}36CaO{\cdot}20TiO_2{\cdot}27P_2O_5$ were Prepared. After ion exchange in the $AgNO_3$solution, crystallization phases were $AgTi_2(PO_4)_3$, $LiTi_2(PO_4)_3$ and $Ca_3(PO_4)_2$. In case of ion exchange, the crystallization phases started to be transformed from $LiTi_2(PO_4)_3$ to $AgTi_2(PO_4)_3$in 0.5 mole $AgNO_3$ solution and the transformation was almost completed in 1.0 mole. ion exchange rate of glass-ceramics powder, considering ion exchange time, was more fast than that of bulk. The bacteriostatic effect of the glass-ceramics on Staphyloroccus aureus and Salmonella typhi bacteria was more excellent than that of glass when the crystallization phase was transformed from LTP to AgTP.

• 한국분말재료학회지
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• 제14권1호
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• pp.50-55
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• 2007

The hydrogen sorption speeds of $Zr_{57}V_{36}Ti_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature. $Zr_{57}V_{36}Ti_7$ amorphous alloy was prepared by ball milling. The hydrogen sorption rate of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption rate of partially crystallized alloy was explained in terms of grain refinement that has been known to promote the diffusion into metallic bulk of the gases. The grain refinement could be obtained by crystallization of amorphous phase resulting in the observed increase in sorption property.

• 공학논문집
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• 제1권1호
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• pp.15-22
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• 1997

코디어라이트(2MgO.$2Al_2 O_3$.$5SiO_2$)계 유리와 겔을 일반 용융법과 졸겔법으로 제조하여 그 결정화 거동을 비교하여 보았다. 졸겔법으로 제조되는 겔의 치밀화 온도는 $810^{\circ}C$이었으며, IR결과 용융유리와 같은 구조를 가짐을 알 수 있었다. 겔의 결정화 개시온도는 $965^{\circ}C$이었으며, 핵형성제로서 10wt%의 $TiO_2$를 첨가한 용융유리의 $978^{\circ}C$ 보다 낮았다. 겔로부터의 결정상의 변화는 스피넬, $\beta$-석영고용 결정에서 $\alpha$-코디어라이트결정으로, 핵형성제로서 $TiO_2$를 넣은 용융유리에서는 (Mg,Al)TiOn 고용결정상과 $\beta$-석영고용결정에서 $\alpha$-코디어라이트로 전이하여감을 알 수 있었다. 핵형성제를 첨가한 용융유리의 결정화는 핵형성제로부터의 체적결정화였으며, 첨가하지 않은 경우는 $\beta$-석영고용결정으로부터의 표면결정화에 의해 결정화가 일어났으며, 겔로부터의 결정화는 치밀화과정에서 미립자사이에 생겨난 계면으로부터의 표면핵형성에 의한 내부 결정화과정을 거쳐 일어남을 알 수 있었다.

• 한국주조공학회지
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• 제26권5호
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• pp.227-231
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• 2006

Liquid formability of bulk amorphous alloys is known to be very poor due to their high viscosity comparing with conventional metallic materials. It is important to have the fabricating technology of bulk amorphous alloys in order to make the components with complicated shape. Liquid formability includes the mold cavity filling ability and the hot tear(crack) resistance during solidification. A mold made of a commercial tool steel for the formability test was designed. Melting was performed by the arc melting furnace with melting capacity of 200 g in an argon atmosphere. Liquid formability and glass forming ability of Cu base and Ni base bulk amorphous alloys were measured and evaluated. Mold filling ability of Ni-Zr-Ti-Si-Sn alloy was better than that of Cu-Ni-Zr-Ti alloy, however the reverse is the hot tear resistance. Bulk amorphous alloy is very susceptible to crack if partial crystallization occurs during solidification. Crack resistance was thought to be closely related with the glass forming ability.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.1145-1150
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• 2003

Zr-based bulk metallic glasses have a significant mechanical properties such as high strength and elastic strain limit, and a good processing ability due to the deformation behavior such as superplasticity under supercooled liquid region. Recently, many researches on the determination of optimum working condition in various bulk metallic glasses have been carried out. In this study, the deformation behavior and forming conditions of $Zr_{55}Cu_{30}Al_{10}Ni_{5}$ bulk metallic glass were investigated under three different strain rates and at various temperatures between 627K and 727K. The glass transition temperature, crystallization temperature and supercooled liquid region of $Zr_{55}Cu_{30}Al_{10}Ni_{5}$ bulk metallic glass are 680K, 762K and 82K, respectively.

• Applied Microscopy
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• 제26권2호
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• pp.235-241
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• 1996

Amophization and decomposition behaviour in $Mg_{62}Cu_{26}Y_{12}$ alloy prepared by melt spinning method and wedge type metal mold casting method have been investigated by a detailed transmission electron microscopy. Amorphous phase has formed in melt-spun ribbon. In the case of the wedge type specimen, however, the amorphous phase has formed only around the tip area within about 2 mm thickness. The remaining part of the wedge type specimen consists of crystalline phases, $Mg_{2}Cu\;and\;Cu_{2}Y$. The supercooling for crystallization behaviour of the amorphous $Mg_{62}Cu_{26}Y_{12}$ alloy, ${\Delta}T_x$ has been measured to be about 60 K. Such a large undercooling of the crystallization bahaviour enables formation of the amorphous phase in the $Mg_{62}Cu_{26}Y_{12}$ alloy under the cooling rate of $10^{2}K/s$. The amorphous $Mg_{62}Cu_{26}Y_{12}$ has decomposed into crystalline phases, $Mg_{2}Cu\;and\;Cu_{2}Y$ after heat treatment at $170^{\circ}C\;and\;250^{\circ}C$.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.337-341
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• 2004

Bulk metallic glasses(BMG) with good mechanical properties have problems that engineering application fields have been limited because of limitation of the alloy size. In order to solving this problem, the friction welding of BMG has been tried using the superplastic-like deformation behavior under the supercooled liquid region. The apparatus for friction welding test was designed and constructed using pneumatic cylinder and gripper based on a conventional lathe. Friction welding have been tried to combination of same BMG alloy and crystalline alloys. The results of welding test were evaluated by X-ray diffraction, measurement of hardness and mechanical properties test. In order to obtain the optimized welding test conditions the temperature of friction interface was measured using Infrared thermal imager.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2006년도 춘계학술대회 논문집
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• pp.409-412
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• 2006

Bulk metallic glass (BMG) strips of $Cu_{54}Ni_6Zr_{22}Ti_{18}$ were produced by warm rolling of the amorphous powder canned with copper. Controlling of temperatures of the rolled sample and rolls was essential for the successive rolling process. Because improper controlling of the sample temperature gave rise to the crystallization of BMG loading to the catastrophic fracture of BMG strips, the temperature of rolls should be properly controlled for achieving successful powder rolling of BMG. The variations of the strain state and temperature in the roll gap was simulated by the finite element method(FEM) using various roll temperatures.