• Title/Summary/Keyword: built-in potential

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Transport Properties of Lennard-Jones Mixtures: A Molecular Dynamics Simulation Study

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.641-646
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    • 2008
  • Equilibrium molecular dynamics simulations in a canonical ensemble are performed to evaluate the transport coefficients of several Lennard-Jones (LJ) mixtures at a liquid argon states of 94.4 K and 1 atm via modified Green-Kubo formulas. Two component mixture of A and B is built by considering the interaction between A and A as the attractive (A) potential, that between A and B as the attractive potential (A), and that between B and B as the repulsive potential (R), labelled as AAR mixture. Three more mixtures - ARA, ARR, and RAR are created in the same way. The behavior of the LJ energy and the transport properties for all the mixtures is easily understood in terms of the portion of attractive potential (A %). The behavior of the thermal conductivities by the translational energy transport due to molecular motion exactly coincides with that of diffusion constant while that of the thermal conductivities by the potential energy transport due to molecular motion is easily understood from the fact that the LJ energy of AAR, ARR, and RAR mixtures increases negatively with the increase of A % from that of the pure repulsive system while that of ARA changes rarely.

Purification of Biohydrogen Produced From Palm Oil Mill Effluent Fermentation for Fuel Cell Application

  • Rohani, Rosiah;Chung, Ying Tao;Mohamad, Izzati Nadia
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.469-474
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    • 2019
  • Fermentation of palm oil mill effluent (POME) produces biohydrogen in a mixture at a specific set condition. This research was conducted to purify the produced mixed biohydrogen via absorption and membrane techniques. Three different solvents, methyl ethanolamine (MEA), ammonia ($NH_3$) and potassium hydroxide (KOH) solutions, were used in absorption technique. The highest $H_2$ purity was found using 1M MEA solution with 5.0 ml/s feed mixed gas flow rate at 60 minutes absorption time. Meanwhile, the purified biohydrogen using a polysulfone membrane had the highest $H_2$ purity at 2~3 bar operating pressure. Upon testing with proton exchange membrane fuel cell (PEMFC), the highest current and power produced at 100% $H_2$ were 1.66 A and 8.1 W, while the lowest were produced at 50/50 vol% $H_2/CO_2$ (0.32 A and 0.49 W). These results proved that both purification techniques have significant potential for $H_2$ purification efficiency.

Characteristics of titanium polarization curve and formation of nanomesh by electrochemical method (전기화학적 방법에 의한 타이타늄 분극특성 및 나노메쉬 형성)

  • Park, Jin-Seo;Kim, Bu-Sub
    • Journal of Technologic Dentistry
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    • v.38 no.2
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    • pp.79-84
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    • 2016
  • Purpose: The aim of this study was to make nanomesh on the surface of titanium by potentiostatic technique which was done at the suitable potential level. Methods: In order to find the suitable potential level, use a $25^{\circ}C$ NaCl, NaOH and NH4F solution of 1 M and 5 M as supporting electrolyte, working electrode(positive potential) was contact to the titanium specimen and counter electrode(negative potential) was contact to the Pt substrate. At the transpassive potential which was observed by potentiostatic technique, potentiostatic technique was done for 2hours. Results: As a result, 1 M NaOH solution was suitable as a supporting electrolyte, potentiostatic technique used a $25^{\circ}C$ NaOH solution of 1 M for 2hours, nanomesh was formed. Conclusion: The potentiostatic technique was used $25^{\circ}C$ NaOH solution of 1 M and 5 M as supporting electrolyte for 2hours. Nanomesh was built more uniform and fine in 1 M NaOH solution than 5 M NaOH solution.

EPAR V2.0: AUTOMATED MONITORING AND VISUALIZATION OF POTENTIAL AREAS FOR BUILDING RETROFIT USING THERMAL CAMERAS AND COMPUTATIONAL FLUID DYNAMICS (CFD) MODELS

  • Youngjib Ham;Mani Golparvar-Fard
    • International conference on construction engineering and project management
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    • 2013.01a
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    • pp.279-286
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    • 2013
  • This paper introduces a new method for identification of building energy performance problems. The presented method is based on automated analysis and visualization of deviations between actual and expected energy performance of the building using EPAR (Energy Performance Augmented Reality) models. For generating EPAR models, during building inspections, energy auditors collect a large number of digital and thermal imagery using a consumer-level single thermal camera that has a built-in digital lens. Based on a pipeline of image-based 3D reconstruction algorithms built on GPU and multi-core CPU architecture, 3D geometrical and thermal point cloud models of the building under inspection are automatically generated and integrated. Then, the resulting actual 3D spatio-thermal model and the expected energy performance model simulated using computational fluid dynamics (CFD) analysis are superimposed within an augmented reality environment. Based on the resulting EPAR models which jointly visualize the actual and expected energy performance of the building under inspection, two new algorithms are introduced for quick and reliable identification of potential performance problems: 1) 3D thermal mesh modeling using k-d trees and nearest neighbor searching to automate calculation of temperature deviations; and 2) automated visualization of performance deviations using a metaphor based on traffic light colors. The proposed EPAR v2.0 modeling method is validated on several interior locations of a residential building and an instructional facility. Our empirical observations show that the automated energy performance analysis using EPAR models enables performance deviations to be rapidly and accurately identified. The visualization of performance deviations in 3D enables auditors to easily identify potential building performance problems. Rather than manually analyzing thermal imagery, auditors can focus on other important tasks such as evaluating possible remedial alternatives.

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Determinants for Students Perceived Potential of BIM Use

  • Linderoth, Henrik C.J.;Peansupap, Vachara;Wong, Johnny
    • International conference on construction engineering and project management
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    • 2020.12a
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    • pp.291-300
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    • 2020
  • Newly graduated students are shown to constitute an important source of innovation within the architectural, engineering and construction (AEC) industry. In relation to digital technologies like BIM (Building Information Modelling) that is claimed to have a potential to transform the industry, newly graduated students may play a vital role in innovating with BIM. The paper aims to explore determinants for students perceived potential of BIM use (PPBU) and the role of the educational background. The aim will be achieved by analysing the results from a survey conducted among third- and fourth-year students in construction and civil engineering in Hong Kong, Sweden, and Thailand (n = 194). When the different groups are compared Swedish and Thai students perceive a significant higher PPBU than Hong Kong students. In a step-wise multiple regression analysis five predictors for PPBU were identified for Thai respectively Swedish students, and one predictor was identified for Hong Kong students. It is concluded that in the contemporary BIM-discourse it is claimed that BIM can/should transform the industry, and BIM is even seen as a disruptive technology, and newly graduated students will contribute to (digitally driven) innovation. However, from the predictors of PPBU, the question can raised if the awareness of the need for structural changes is lacking in the education, if students later in their working life should contribute to a BIM-induced transformation of the industry?

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Estimation of GHG emission and potential reduction on the campus by LEAP Model (LEAP 모델을 이용한 대학의 온실가스 배출량 및 감축잠재량 분석)

  • Woo, Jeong-Ho;Choi, Kyoung-Sik
    • Journal of Environmental Impact Assessment
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    • v.21 no.3
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    • pp.409-415
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    • 2012
  • Post-kyoto regime has been discussing with the GHG reduction commitment. GHG energy target management system also has been applied for the domestic measures in the country. Universities are major emission sources for GHG. It is very important for campus to built the GHG inventory system and estimate the potential GHG emission reduction. In general, GHG inventory on the campus was taken by the IPCC guidance with the classification of scope 1, 2, and 3. Electricity was the highest portion of GHG emission on the campus as 5,053.90 $tonsCO_2eq/yr$ in 2009. Manufacturing sector was the second high emission and meant GHG in laboratory. Potential GHG reduction was planned by several assumptions such as installation of occupancy sensor, exchanging LED lamp and photovoltaic power generation. These reduction scenarios was simulated by LEAP model. In 2020, outlook of GHG emission was estimated by 17,435.98 tons of $CO_2$ without any plans of reduction. If the reduction scenarios was applied in 2020, GHG emission would be 16,507.60 tons of $CO_2$ as 5.3% potential reduction.

Fouling behaviours of two stages microalgae/membrane filtration system applied to palm oil mill effluent treatment

  • Teow, Yeit Haan;Wong, Zhong Huo;Takriff, Mohd Sobri;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.373-383
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    • 2018
  • Fouling by solids and microorganisms is the major obstacle limiting the efficient use of membrane wastewater treatment. In our previous study, two stages microalgae/membrane filtration system was proposed to treat anaerobic digested palm oil mill effluent (AnPOME). This two stages microalgae/membrane filtration system had showed great potential for the treatment of AnPOME with high removal of COD, $NH_3-N$, $PO_4{^{3-}}$, TSS, turbidity, and colour. However, fouling behavior of the membrane in this two stages microalgae/membrane filtration system was still unknown. In this study, empirical models that describe permeate flux decline for dead-end filtration (pore blocking - complete, intermediate, and standard; and cake layer formation) presented by Hermia were used to fit the experimental results in identifying the fouling mechanism under different experimental conditions. Both centrifuged and non-centrifuged samples were taken from the medium with 3 days RT intervals, from day 0 to day 12 to study their influence on fouling mechanisms described by Hermia for ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO) filtration mode. Besides, a more detailed study on the use of resistance-in-series model for deadend filtration was done to investigate the fouling mechanisms involved in membrane filtration of AnPOME collected after microalgae treatment. The results showed that fouling of UF and NF membrane was mainly caused by cake layer formation and it was also supported by the analysis for resistance-in-series model. Whereas, fouling of RO membrane was dominated by concentration polarization.

The basic study about streaming potential generated by specimen fracture (시료 파괴 시 발생하는 SP에 관한 기초 연구)

  • Kim, Jong-Wook;Cho, Sung-Jun;Park, Sam-Gyu;Sung, Nark-Hoon;Song, Young-Soo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.06a
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    • pp.291-296
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    • 2007
  • We measured potential waveform of load, displacement, micro electric signal generated by rock and mortar fracture using PXI A/D Converter. The rock type used for measurement was used granite, limestone and sandstone, and mortar specimen. we made measuring equipment of physical properties to confirm basic information of physical properties, measured physical properties of rock engineering, electric resistivity and seismic velocity. Potential waveform system was built using PXI A/D Converter and measured potential waveform of load, displacement, micro-electric signal generated using this during uniaxial compressive test by the specimen finished such test of physical properties. Using the saturated rock and mortar specimen, micro electric signal increased, and It didn't increase a signal in dried rock and mortar specimen according as load and strain rate increases. But signal also increased in saturated or dried specimen in case of sandstone. It was possible to check the close correlation relationship the signal and fracture behavior by a compressive load as the signal of fracture position was increased bigger than the other position. It was also possible to check the correlation relationship between physical properties and micro geo-electric signal.

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A study on membrane technology for surface water treatment: Synthesis, characterization and performance test

  • Haan, Teow Yeit;Shah, Mubassir;Chun, Ho Kah;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.69-77
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    • 2018
  • The use of membrane as an innovative technology for water treatment process has now widely been accepted and adopted to replace the conventional water treatment process in increasing fresh water production for various domestic and industrial purposes. In this study, ultrafiltration (UF) membranes with different formulation were fabricated via phase inversion method. The membranes were fabricated by varying the polymer concentration (16 wt%, 18 wt%, 20 wt%, and 21 wt%). A series of tests, such as field emission scanning electron microscope (FESEM), pore size and porosity, contact angle, and zeta potential were performed to characterize the membranes. The membrane performance in terms of permeation flux and rejection were evaluated using a laboratory bench-scale test unit with mine water, lake water and tube well as model feed solution. Long hour filtration study of the membranes provides the information on its fouling property. Few pore blocking mechanism models were proposed to examine the behaviour of flux reduction and to estimate the fouling parameters based on different degree of fouling. 21 wt% PVDF membrane with smaller membrane pore size showed an excellent performance for surface water treatment in which the treated water complied with NWQS class II standard.

Microstructural, Mechanical, and Durability Related Similarities in Concretes Based on OPC and Alkali-Activated Slag Binders

  • Vance, Kirk;Aguayo, Matthew;Dakhane, Akash;Ravikumar, Deepak;Jain, Jitendra;Neithalath, Narayanan
    • International Journal of Concrete Structures and Materials
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    • v.8 no.4
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    • pp.289-299
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    • 2014
  • Alkali-activated slag concretes are being extensively researched because of its potential sustainability-related benefits. For such concretes to be implemented in large scale concrete applications such as infrastructural and building elements, it is essential to understand its early and long-term performance characteristics vis-a'-vis conventional ordinary portland cement (OPC) based concretes. This paper presents a comprehensive study of the property and performance features including early-age isothermal calorimetric response, compressive strength development with time, microstructural features such as the pore volume and representative pore size, and accelerated chloride transport resistance of OPC and alkali-activated binder systems. Slag mixtures activated using sodium silicate solution ($SiO_2$-to-$Na_2O$ ratio or $M_s$ of 1-2) to provide a total alkalinity of 0.05 ($Na_2O$-to-binder ratio) are compared with OPC mixtures with and without partial cement replacement with Class F fly ash (20 % by mass) or silica fume (6 % by mass). Major similarities are noted between these binder systems for: (1) calorimetric response with respect to the presence of features even though the locations and peaks vary based on $M_s$, (2) compressive strength and its development, (3) total porosity and pore size, and (4) rapid chloride permeability and non-steady state migration coefficients. Moreover, electrical impedance based circuit models are used to bring out the microstructural features (resistance of the connected pores, and capacitances of the solid phase and pore-solid interface) that are similar in conventional OPC and alkali-activated slag concretes. This study thus demonstrates that performance-equivalent alkali-activated slag systems that are more sustainable from energy and environmental standpoints can be proportioned.