• Polymer(Korea)
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• v.34 no.4
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• pp.386-389
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• 2010

Thermal behaviors of water in the poly(acrylic acid) (PAA)/water mixtures with 0.1 M NaCl, HCl, and NaOH were investigated by DSC. It showed that adding ions in the mixtures affected the crystallization of water evidently. Compared with the PAA/water mixtures, the $T_m$ of freezable bound water in the mixtures with ions moved to lower values and varied with different cations and anions, due to the stabilization or destabilization of the hydrogen-bonding hydration between polymers and water molecules through ionic hydration. The content of non-freezable bound water in the non-crystalline phase of the PAA/water mixtures with ions was not constant, it increased with total water content gradually, owing to the more binding sites created by ions. The ions could change the distribution of different states of water in the polymer aqueous solutions evidently.

• Bulletin of the Korean Chemical Society
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• v.24 no.6
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• pp.802-804
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• 2003

The relative stabilities of weak binding clusters are sensitive to temperature due to the entropy effect. Thus, here we report significant changes in relative stabilities between two low-energy electron-water trimer structures and those between three low-energy electron-water pentamer structures, as the temperature increases. The trimer and pentamer show structural changes around 200 K.

• Journal of the Korean Wood Science and Technology
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• v.20 no.2
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• pp.73-80
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• 1992

The effect of presteaming on native oak specimens(Quercus serrata) of 2.5cm thick were investigated by measuring specific gravities, internal moisture gradients, residual extractives, and transport rates of free and bound water. The specific gravities and internal moisture gradients of the presteamed samples did not much deviate from those of the controls, but after presteaming discrepancy in moisture content between specimens lessened. The amount of residual hot-water extractives of the presteamed samples were less than those of the controls by 25%. The transport rates of bound water were determined by measuring steady-state diffusion coefficients with a vapormeter cup. After presteaming the diffusion coefficients in radial direction increased by 35%, but decreased those in the tangential direction.

• Proceedings of the SCSK Conference
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• 2003.09a
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• pp.570-577
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• 2003

The importance of cornified envelope (CE)-bound lipids to epidermal barrier function is increasingly being recognized. In the present study, we intentionally damaged the cornified layer of hairless mice by ultraviolet irradiation and sodium dodecyl sulfate (SDS) treatment, and assessed the changes in epidermal barrier function by measuring Trans Epidermal Water Loss (TEWL). We also measured changes in the amount of CE-bound lipids using thin layer chromatography (TLC). The results showed that both treatments increased TEWL and decreased CE-bound lipids (omega-hydroxy cerami de and omega-hydroxy acid). In addition, investigation of the chronological changes in TEWL revealed an inverse relationship between TEWL and CE-bound lipids, and a correlation between CE-bound lipids and epidermal barrier function. We then measured the amount of CE-bound lipids in the cheek and the medial side of the upper arm in humans. The results showed that because the cheek receives external stimulation on a daily basis, the amount of CE-bound lipids was significantly lower, while the level of TEWL was higher. These observations, together with those from the animal study, indicate that CE-bound lipids are related to epidermal barrier function.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.253-254
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• 2012

In this study, it carried out measurement experiment Ca(OH)₂ and chemically bound water to verify Ca(OH)₂ and chemically bound water prediction model out of hydration model of cement incorporating blast furnace slag. It compared and analyzed prediction results using prediction model with measurement results of Ca(OH)₂ quantity using thermogravimetric differential temperature analysis and chemically bound water quantity using electronic furnace. It agrees well experiments results with prediction results.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.201-201
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• 2016

The asymptotic extreme value distributions of maxima are a natural choice when designing against future extreme events like flood peaks or wave heights, given a stationary time series. The generalized extreme value distribution (GEV) is often utilised in this context because it is seen as a convenient single expression for extreme event analysis. However, the GEV has a drawback because the location of the distribution bound relative to the data is a discontinuous function of the GEV shape parameter. That is, for annual maxima approximated by the Gumbel distribution, the data is also consistent with a GEV distribution with an upper bound (no lower bound) or a GEV distribution with a lower bound (no upper bound). A more consistent single extreme value expression for design purposes is proposed as the Weibull distribution of smallest extremes, as applied to transformed annual maxima. The Weibull distribution limit holds here for sufficiently large sample sizes, irrespective of the extreme value domain of attraction applicable to the untransformed maxima. The Gumbel, Type 2, and Type 3 extreme value distributions thus become redundant, together with the GEV, because in reality there is only a single asymptotic extreme value distribution required for design purposes - the Weibull distribution of minima as applied to transformed maxima. An illustrative synthetic example is given showing transformed maxima from the normal distribution approaching the Weibull limit much faster than the untransformed sample maxima approach the normal distribution Gumbel limit. Some New Zealand examples are given with the Weibull distribution being applied to reciprocal transformations of annual flood maxima, where the untransformed maxima follow apparently different extreme value distributions.

• Membrane and Water Treatment
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• v.8 no.4
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• pp.337-353
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• 2017

Membrane fouling at different solids retention times (SRT) (7, 12 and 20 days) was studied under well-controlled conditions in a laboratory-scale aerobic submerged membrane bioreactor under constant biomass concentration using a synthetic high strength wastewater. An increase in SRT was found to improve membrane performance and this correlated to changes in the total production of bound extracellular polymeric substances (EPS), and the composition and properties of bound EPS using X-ray photoelectron spectroscopy (XPS) and Fourier transform-infrared spectroscopy (FTIR) and floc sizes. A larger amount of total bound EPS was found at the lowest SRT (7 days) tested but the ratio of proteins (PN) to carbohydrates (CH) in bound EPS increased with an increase in SRT. Similarly, the quantity of soluble microbial products (SMP) decreased with an increase in SRT and the SMP PN/CH ratio increased with an increase in SRT. SMP concentrations positively correlated to the percentage of membrane pore blocking resistance. The quantity of total bound EPS and total SMP positively corresponded to the membrane fouling rate, while the PN/CH ratio in the bound EPS and SMP negatively correlated to the membrane fouling rate. The results show that both the quantity and composition of bound EPS and SMP and floc sizes are important in controlling membrane fouling.

• Korean Journal of Food Science and Technology
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• v.30 no.5
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• pp.1236-1242
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• 1998

Korean Lentinus edodes SR-1 was cultured to multiply the mycelia in the complete broth medium (C/N=13.1) for mushroom, and protein-bound polysaccharides were extracted from the cultured broth containing mycelia (The whole cultured broth was used to increase the yields: 80% of protein-bound polysaccharides were existed at the cell wall of mycelia and 20% of those were secreted extracellularily in this culture). Protein-bound polysaccharides in the cultured broth containing mycelia were extracted by using three different methods: 1) Extraction with hot water, 2) Disintegration of cell wall by glass bead mill treatment before extraction with hot water, and 3) Cellulase treatment before extraction with hot water. The highest yield was obtained (930 mg polysaccharides/100 mL culture broth) when protein-bound polysaccharides were extracted with 2) method. The extracted crude protein-bound polysaccharides were purified using protease, DEAE-cellulose and Sephadex G-100. The growth inhibition activity for $P_{388}$, mouse leukemic cell, increased (53.7, 62.2, 93.7% and 97.4%) as the purification level increased. Protein-bound polysaccharides contained 46.1% of polysaccharides, 7.3% of protein, and trace amounts of minerals. Polysaccharides contained glucose, galactose, xylose and mannose. The content of proline and glycine were high, however, methionine and leucine were not found. The major minerals were Na, K, Zn, and Ca.

• Proceedings of the Korean Geotechical Society Conference
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• 1999.10a
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• pp.193-200
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• 1999

Since Broms and Bennermark(1967) suggested the face stability criterion based on laboratory extrusion tests and field observations, the face stability of a tunnel driven in cohesive material has been studied by several authors. And recently, more general solution for the tunnel front is given by Leca and Panet(1988). They adopted a limit state design concept to evaluate the face stability of a shallow tunnel driven into cohesionless material and showed that the calculated upper bound solution represented the actual behavior reasonably well. In this study, two factors are simultaneously considered for assessing tunnel face stability: One is the effective stress acting on the tunnel front calculated by upper bound solution; and the other is the seepage force calculated by numerical analysis under the condition of steady state ground water flow. The model tests were performed to evaluate the seepage force acting on the tunnel front and these results were compared with results of numerical analysis. Consequently, the methodology to evaluate the stability of a tunnel face including limit analysis and seepage analysis is suggested under the condition of steady state ground water flow.

• Korean Journal of Environmental Biology
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• v.20 no.2
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• pp.101-108
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• 2002

Benthic organisms dwell in sediment-water interface that contains significant amount of organic and inorganic contaminants. Their feeding behavior is highly related with sediment itself and pore water in the sediments, especially in ease of deposit feeder (i.e. polychaete, amphipod). The acid volatile sulfide (AVS) is one of the important binding phases of sediment-bound metals in addition to organic matter and Fe and Mn oxide fractions in sediments, particularly in anoxic sediments. The AVS model is a powerful tool to predict metal bioavailability and bioaccumulation in benthic organisms considering SEM/AVS mole ratios in surficial sediments. However, several biogeochemical factors must be considered to use AVS model in the sediment-bound metal bioavailability.