• Title/Summary/Keyword: boron oxide

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Oxide Layer Analysis of Uncoated Boron Steel Sheet for Hot Stamping According to the Atmosphere Oxygen Content (비도금 핫스탬핑용 보론강판의 분위기 산소량에 따른 산화층 분석)

  • J. H. Lee;T. H. Choi;J. H. Song;G. H. Bae
    • Transactions of Materials Processing
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    • v.32 no.3
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    • pp.160-165
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    • 2023
  • As the supply of eco-friendly vehicles increases, the application rate of hot stamping components is rising to reduce vehicle weight and improve safety. Although Al-Si coated steel sheets are commonly used in hot stamping processes, their manufacturing costs are elevated due to process patents and royalties. Various hot stamping studies have been conducted to reduce these production costs. In this study, we derived a process control method for suppressing the oxide layer of hot stamping parts using uncoated boron steel sheets. Firstly, hat-shaped parts were hot stamped under atmospheric conditions to analyze the tendency of oxide layer formation by location. Then, the Gleeble system was used to observe oxide layer formation based on oxygen content under various atmospheric conditions. Finally, the oxide layer thickness was quantitatively measured using SEM images.

Study on P-type in-situ doped Polysilicon Films (P형 in-situ 도핑 폴리실리콘 막질에 관한 연구)

  • Oh, Jung-Sup;Lee, Sang-Eun;Noh, Jin-Tae;Lee, Sang-Woo;Bae, Kyoung-Sung;Roh, Yong-Han
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.208-212
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    • 2008
  • This paper reports physical properties of in situ boron doped silicon films made from boron source gas and silane ($SiH_4$) gas in a conventional low-pressure chemical vapor deposition vertical furnace. If the p-type polysilicon is formed by boron implantation into undoped polysilicon, the plasma nitridation (PN) process is added on the oxide in order to suppress boron penetration that can be caused during the thermal treatments used in fabrication. In-situ boron doped polysilicon deposition can complete p-type polysilicon film with only one deposition process and need not the PN process, because there is not interdiffusion of dopant at the intermediate temperatures of the subsequent steps. Since in-situ boron doped polysilicon films have higher work function than that of n-type polysilicon and they are compatible with the underlying oxide, they may be promising materials for improving memory cell characteristics if we make its profit of these physical properties.

A Study on Environment- Friendly Grinding by Using Cold Air (냉각 공기장치에 의한 환경 친화 연삭 연구)

  • 김남경;이동호;성낙창;송지복
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.9
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    • pp.145-151
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    • 1998
  • In this study, the experimental and analytic investigation with cold air system has been performed for improving the working environment of the conventional grinding fluid. Very simple cold air system was developed which could replace by the conventional grinding fluid system. The identification of heat of grinding Bone is very important for precision grinding. The experimental data was analysed to investigate the heat which was transferred to the workpiece. It was found that 45∼55% of the total energy for dry grinding, 22∼28% for wet grinding, and 32∼35% for cold air system are conducted to the workpiece in grinding with cubic boron nitride wheel. Cubic boron nitride wheel could reduce the residual stress and thermal demage comparing with aluminium oxide wheel, because cubic boron nitride wheel has very high extreme thermal conductivity.

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On the Gate Oxide Scaling of Sub-l00nm CMOS Transistors

  • Seungheon Song;Jihye Yi;Kim, Woosik;Kazuyuki Fujihara;Kang, Ho-Kyu;Moon, Joo-Tae;Lee, Moon-Yong
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.1 no.2
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    • pp.103-110
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    • 2001
  • Gate oxide scaling for sub-l00nm CMOS devices has been studied. Issues on the gate oxide scaling are reviewed, which are boron penetration, reliability, and direct tunneling leakage currents. Reliability of Sub-2.0nm oxides and the device performance degradation due to boron penetration are investigated. Especially, the effect of gate leakage currents on the transistor characteristics is studied. As a result, it is proposed that thinner oxides than previous expectations may be usable as scaling proceeds. Based on the gate oxide thickness optimization process we have established, high performance CMOS transistors of $L_{gate}=70nm$ and $T_{ox}=1.4nm$ were fabricated, which showed excellent current drives of $860\mu\textrm{A}/\mu\textrm{m}$ (NMOS) and $350\mu\textrm{A}/\mu\textrm{m}$ (PMOS) at $I_{off}=10\mu\textrm{A}/\mu\textrm{m}$ and $V_dd=1.2V$, and CV/I of 1.60ps (NMOS) and 3.32ps(PMOS).

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The Thermal and Mechanical Properties of Epoxy Composites Including Boron Carbide Surface Treated with Iron Oxide and Tungsten (철산화물과 텅스텐으로 표면 처리된 보론카바이드를 포함하는 에폭시 조성물의 열적·기계적 물성)

  • Kim, Taehee;Lee, Wonjoo;Seo, Bongkuk;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.19 no.3
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    • pp.113-117
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    • 2018
  • Boron carbide is lower in hardness than diamond or boron nitride but has a hardness of more than 30 GPa and is used for manufacturing tank armors and ammo shells due to its high hardness. It is also used as a neutron absorber due to its ability to absorb neutrons, which is increasing its use in nuclear power projects. Neutrons have no interaction with electrons and are known to pass through the material without interactions. Along with boron carbide, the atoms with high interaction with neutrons are hydrogen, and high hydrogen concentration polyesters and epoxy polymers including boron are used as materials for manufacturing products for nuclear power generation waste. In this paper, the surface of boron carbide is treated with iron oxide and tungsten to improve interaction between modified boron carbide and epoxy polymer. XRD and XPS were used to confirm that iron oxide and tungsten are well attached on the surface of boron carbide, respectively. The mechanical strength of the surface treated boron carbide was measured by a universal testing machine (UTM) and the dynamic characteristics of the cured product were observed by using a dynamic analyzer (DMA).

Local Back Contact의 Boron-BSF 최적화에 따른 태양전지의 특성에 관한 연구

  • An, Si-Hyeon;Park, Cheol-Min;Jo, Jae-Hyeon;Jang, Gyeong-Su;Baek, Gyeong-Hyeon;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.394-394
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    • 2011
  • 최근 태양전지의 후면에서 통상적으로 사용되는 Al을 이용한 후면의 BSF형성과 그에 관한 연구보다 계면의 recombination을 줄이기 위하여 passivation 특성이 좋은 층을 후면에 형성하고 국부적으로 BSF를 형성하는 back contact을 형성하여 특성을 향상시키는 연구가 많이 이루어지고 있다. 본 연구는 이러한 local back contact을 boron-BSF를 이용하여 형성하고 passivation layer는 oxide를 이용한 구조를 SILVACO 2-dimension simulation을 이용하여 그 특성을 분석하였다. Boron-local back contact 구조에서 boron-BSF의 doping concentration, depth, lateral width, boron-BSF spacing 가변을 통해 태양전지의 특성변화에 대해서 spectrum response를 통한 QE 분석 및 I-V를 분석하여 최적화하였다.

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Fabrication and properties of in-situ Al/AlB2 composite reinforced with high aspect ratio borides

  • Kayikci, Ramazan;Savas, Omer
    • Steel and Composite Structures
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    • v.19 no.3
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    • pp.777-787
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    • 2015
  • Production and properties of metal matrix composites reinforced with an in-situ high aspect ratio $AlB_2$ flake have been investigated. Boron 2.2wt.% was dissolved in pure Al and Al-Cu alloy at $1300^{\circ}C$ by adding directly boron oxide which resulted in 4 vol.% reinforcing phase. The in-situ $AlB_2$ flake concentration was increased up to 30 vol.% in order to increase the tensile strength of the composites. Hardness, compressive strength and tensile strength of the composite were measured and compared with their matrix. Results showed that 30 vol.% $AlB_2/Al$ composite show a 193% increase in the compressive strength and a 322% increase in compressive yield strength. Results also showed that ductility of composites decreases with adding $AlB_2$ reinforcements.

The effect of nitrogen flow rate in a predeposition with Boron nitride (보론 나이트라이드를 사용하는 Predeposition 공정에서 질소류량의 영향)

  • 박형무;김충기
    • 전기의세계
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    • v.30 no.4
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    • pp.227-230
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    • 1981
  • The variation of sheet resistance and the reduction of masking oxide thickness with the flow rate of nitrogen gas has been measured in Boron predeposition process with Planar Diffusion source, BN-975. At 900.deg. C, the sheet resistance varied as much as 75% when the nitrogen flow rate was changed from 0.4 liters/min to 2.0 liters/min. At 975.deg. C, however, only 12% of sheet resistance variation was observed under the same flow rate change. The reduction of masking oxide thickness at 975.deg. C for a 5 min predeposition was 600 nm when the nitrogen flow rate was 0.4 liters/min. When the flow rate incresased to 1.9 liters/min, however, only 100nm of masking oxide was consumed in a similar predeposition process.

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Characterization of Tribolayers and Sliding wear at High Temperature between AlCrN Coated Tool Steels and Ultra-high Strength Boron Steels

  • Choi, Byung-Young;Gu, Yoon-Sik
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.1
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    • pp.37-44
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    • 2011
  • High temperature wear of AlCrN coated tool steels sliding against the ultra-high strength boron steels used for hot press forming has been studied. The sliding wear tests have been carried out using a pin-on-disc of configuration under applied normal load of 50 N for 20 min with heating the ultra-high strength boron steels up to $800^{\circ}C$. Characterizations of tribolayers formed on the contacting surfaces between the tribopairs of the AlCrN coated tool steels and the ultra-high strength boron steels have been studied. It was found on the tribolayers of the AlCrN coated tool steels that microcracking and oxides containing Fe and Cr to increase friction coefficient were formed at the early stage of sliding wear, followed by the generation of the smeared oxide layers containing Fe transferred from the tribopair to decrease friction coefficient. This may mainly contribute to very low specific wear rate of the AlCrN coated tool steels sliding against the ultra-high strength boron steels, resulting from oxideoxide contact between the tribopair.

EELS and electron diffraction studies on possible bonaccordite crystals in pressurized water reactor fuel CRUD and in oxide films of alloy 600 material

  • Chen, Jiaxin;Lindberg, Fredrik;Wells, Daniel;Bengtsson, Bernt
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.668-674
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    • 2017
  • Experimental verification of boron species in fuel CRUD (Chalk River Unidentified Deposit) would provide essential and important information about the root cause of CRUD-induced power shifts (CIPS). To date, only bonaccordite and elemental boron were reported to exist in fuel CRUD in CIPS-troubled pressurized water reactor (PWR) cores and lithium tetraborate to exist in simulated PWR fuel CRUD from some autoclave tests. We have reevaluated previous analysis of similar threadlike crystals along with examining some similar threadlike crystals from CRUD samples collected from a PWR cycle that had no indications of CIPS. These threadlike crystals have a typical [Ni]/[Fe] atomic ratio of ~2 and similar crystal morphology as the one (bonaccordite) reported previously. In addition to electron diffraction study, we have applied electron energy loss spectroscopy to determine boron content in such a crystal and found a good agreement with that of bonaccordite. Surprisingly, such crystals seem to appear also on corroded surfaces of Alloy 600 that was exposed to simulated PWR primary water with a dissolved hydrogen level of $5mL\;H_2/kg\;H_2O$, but absent when exposed under $75mL\;H_2/kg\;H_2O$ condition. It remains to be verified as to what extent and in which chemical environment this phase would be formed in PWR primary systems.