• Title/Summary/Keyword: boron effect

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Viscosities of Supercooled Water and Other Liquids

  • Bahng, Jun-Su;Hahn, Sang-Joon;Jhon, Mu-Shik
    • Journal of the Korean Chemical Society
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    • v.15 no.4
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    • pp.171-175
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    • 1971
  • Significant structure theory has been applied to the viscosities of supercooled liquids with success. In the supercooled region, the effect of free volume decrease is so significant that the thermal effects on the solid-like volume must be considered properly. In addition, the two state theories proposed by Jhon and Eyring for water and Litovitz et al. for boron trioxide have been successfully applied to the structure change in the liquid state. Considered liquids are benzene, carbon tetrachloride, p-xylene, water and boron trioxide.

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Effect of MgB6 Addition on Synthesis of Hexagonal Boron Nitride (Hexagonal Boron Nitride의 합성에 있어서 MgB6 첨가의 효과)

  • Lee, Dae-Jin;Jee, Mi-Jung;Choi, Byung-Hyun;Lee, Mi-Jai;Cho, Nam-Hee;Cha, Mi-Sun
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.53-57
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    • 2009
  • The h-BN powder was synthesized by amorphous $B_2O_3$ and activated carbon at $1550^{\circ}C$ in nitrogen atmosphere, whose properties were examined according to $MgB_6$ addition. Amount of $MgB_6$ addition was varied in the range of $0{\sim}$10\;wt% of the initial mixture. It was observed that $MgB_6$ addition led to an increase in the amount and the grain size of h-BN and decrease in the amount of $B_4C$ forming. When $MgB_6$ added 5 wt%, the amount and crystallinity of h-BN increased as the holding time at the synthesis temperature was prolonged. It was also confirmed that the regularity of three-dimensional ordering of h-BN increases.

Analysis on Chemical Ingredients with Anti-microbial Activity in Water-based Metalworking Fluids

  • Park, Dong-Uk;Kim, Bok-Hwan;Lee, Kwon-Sup
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.06a
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    • pp.217-222
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    • 2004
  • This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) ‘A’ can cause anti-microbial activity and health effect. Three water-based MWF products (‘A’, ‘B’, and ‘C’) were studied every week for two months. Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF ‘A’ was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF ‘A’ were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF ‘A’ are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically. To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

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A study on the deep levels in boron ion implanted semi-insulating GaAs by PICTS (PICTS방법에 의한 Boron이온을 주입시킨 반절연성 GaAs의 깊은준위에 관한 연구)

  • 최현태;김인수;이철욱;손정식;김영일;배인호
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.426-433
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    • 1995
  • Effect of boron in GaAs have been investigated by photo induced current transient spectroscopy(PICTS). The starting material was undoped liquid encapsulated Czochralski(LEC) semi insulating GaAs and boron ion implantation at 150keV energy was conducted with dose of 10$\^$12/ and 10$\^$13/ions/cm$\^$2/. In ion implanted samples, the peaks related arsenic vacancy(V$\_$As/) were decreased but complex lattice defect was increased with annealing temperature. U band was observed at ion implanted(10$\^$13/ ions/cm$\^$2/) and thermally treated(550.deg. C) sample. More negative peak was detected after annealing at temperature between 600 and 700.deg. C. The measurement of dark current showed that the formation of B$\_$GA/-V$\_$As/, complex defect and complex lattice defect by ion implantation were a reasonable explanation for the decrease in dark current.

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Leachability of Zinc Borate-Modified Oriented Strandboard (OSB)

  • Lee, Sun-Young;Wu, Qinglin
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.5
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    • pp.46-57
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    • 2007
  • The leachability of boron in zinc borate (ZB)-modified oriented strandboard (OSB) from southern wood species was investigated in this study. The leaching experiments were conducted by exposing edge-sealed OSB samples under running water at $31^{\circ}C$ for 8, 24, 72, and 216 h. The results from leached samples were compared with those from the unleached controls. Boron leaching of the modified OSB occurred upon the initial water exposure, and the leaching rate decreased as the leaching time increased. Initial boric acid equivalent (BAE) level, wood species, and sample thickness swelling significantly influenced the leachability. There was no consistent effect of polyethylene glycol (PEG) on zinc borate leaching. The glue-line washing within OSB due to thickness swelling of the test samples under water and decomposition of the borate to form water-soluble boric acid were thought to be two possible causes for the observed leaching. The relationship between assayed BAE and leaching time followed a decaying exponential function for zinc borate treated OSB. From the boron/zinc ratio after each leaching period, boron element in ZB was more or less leachable. The material constant of the regression models allowed comparing the leachability of the modified OSB for various wood species. An unified leaching method for treated wood composite materials is needed.

Analysis on Chemical Ingredients with Anti-microbial Activity in Water-based Metalworking Fluids

  • Park, Donguk;Lee, Jonghang;Lee, Kwonsup
    • KSTLE International Journal
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    • v.4 no.2
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    • pp.52-55
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    • 2003
  • This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) "A" can cause anti-microbial activity and health effect. Three water-based MWF products ("A", "B", and "C") were studied every week for two months (from June 1, 2002 to July 30, 2002). Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF "A" was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF "A" were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF "A" are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically. To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

Analysis on Chemical Ingredients with Anti-microbial Activity in Water-based Metalworking Fluids

  • Park, Dong-Uk;Lee, Jong-Hang;Yoon, Chung-Sik;Lee, Kwon-Sup;Park, Deok-Mook
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2003.06a
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    • pp.213-216
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    • 2003
  • This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) “A” can cause anti-microbial activity and health effect. Three water-based MWF products (“A”, “B”, and “C”) were studied every week for two months (from June 1, 2002 to July 30, 2002). Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF “A” was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF A were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF “A” are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically, To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

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Cyclic Oxidation Behavior of Fe-Cr-Al Joint Brazed with Nickel-Base Filler Metal (Ni계 합금으로 브레이징된 Fe-Cr-Al 합금 접합부의 주기산화거동)

  • Mun, Byeong-Gi;Choe, Cheol-Jin;Park, Won-Uk
    • 연구논문집
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    • s.29
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    • pp.141-149
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    • 1999
  • Brazing of Fe-Cr-Al alloy was carried out at $1200^{\circ}C$ in vacuum furnace using nickel-based filler metals : BNi-5 powder(Ni-Cr-Si-Fe base alloy} and MBF-50 foil (Ni-Cr-Si-B). The effect of boron content on the stability of oxide scale on the brazed joint was investigated by means of cyclic oxidation test performed at $1050^{\circ}C$ and $1200^{\circ}C$. Apparently, the joints brazed with MBF-50 containing boron showed relatively stable oxidation rates compared to boron-free BNi-5 at both temperatures. However, it was considered that the slower weight loss of MBF-50 brazed specimen wasn’t resulted from the low oxidation rate but from the spallation of oxide layer. The oxide layer consisted of thick spinel oxide on the surface and $Al_2 O_3$ internal oxide layer along the interface between mother alloy and braze, the mother alloy was also eroded seriously by the formation of spinel oxides such as $FeCr_2 O_4$ and $NiCr_2 O_4$ on the surface, likely to be induced by the change of oxide forming mechanism due to diffusion of boron from the braze. On the contrary, the joint brazed with BNi-5 showed the good oxidation resistance during the cyclic oxidation test. It seems that the oxidation can be retarded by the formation of stable $Al_2 O_3$ layer at the surface.

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Three-dimensional monte carlo simulation and mask effect of low-energy boron ion implantation into <100>single-crystal silicon (<100>방향 실리콘 단결정에서의 저 에너지 붕소 이온 주입 공정에 대한 3차원 몬테 카를로 시뮬레이션 및 마스크 효과)

  • 손명식;이준하;송영진;황호정
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.8
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    • pp.94-106
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    • 1995
  • A three-dimensional(3D) Monte Carlo simulator for boron ion implantation into <100>single-crystal silicon considering the mask structure has been developed to predict the mask-dependent impurity doping profiles of the implanted boron at low energies into the reduced area according to the trend of a reduction in the size of semiconductor devices. All relevant important parameters during ion implantation have been taken into account in this simulator. These are incident energy, tilt and rotation of wafer, orientation of silicon wafer, presence of native silicon dioxide layer, dose, wafer temperature, ion beam divergence, masking thickness, and size and structure of open window in the mask. The one-dimensional(1D) results obtained by using the 3D simulator have been compared with the SIMS experiments to demonstrate its capabilities and confirem its reliability, and we obtained relatively accurate 1D doping profiles. Through these 3D simulations considering the hole structure and its size, we found the mask effects during boron ion implantation process.

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