• 제목/요약/키워드: boron effect

검색결과 387건 처리시간 0.026초

Effect of Silicon Nitride Whisker Content on the Flexural Strength of Silicon Nitride-Boron Nitride-Silicon Carbide Multi-Layer Composites

  • Park, Dong-Soo;Cho, Byung-Wook
    • 한국세라믹학회지
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    • 제40권9호
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    • pp.832-836
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    • 2003
  • Multi-layer ceramic composites were prepared by tape casting followed by hot pressing using silicon nitride layer with silicon nitride whiskers, silicon nitride layer with silicon carbide particles and boron nitride-alumina layer. The whiskers were aligned during the casting. As the whisker content of the silicon nitride layer was increased up to 10 wt%, the flexural strength of the multi-layer composite was increased. However, further increase of the whisker content in the layer resulted in a rapid decrease of the strength of the composite. The results suggest that the strength of multi-layer ceramic composite showing non-catastrophic failure behavior can be significantly improved by incorporating the aligned whiskers in the layers.

붕소가 도핑된 다이아몬드 전극을 이용한 오존 발생의 효과 및 응용 (Ozone Generation Effect and application using Boron-doped Diamond Electrode)

  • 피영민;;박수길
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.170-172
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    • 2002
  • Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped diamond(BDD) were used as anode for generating ozone gas by electrolysis of acid solution. In this work, we have studied ozone generating system using BDD electrode. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable for electrolyte while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

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고분자 막이 코팅된 Boron doped diamond 전극에 의한 호르몬의 전기화학적 검출 효과 (Electrochemical detection effect of hormone in body by using polymer coated boron doped diamond electrode)

  • 황진희;조은인;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.611-614
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    • 2003
  • The electrochemical oxidation of ascorbic acid(AA), serotonin(SE) and epinephrine(EP) have been performed at poly N,N-dimethylaniline(PDMA) film coated diamond electrode. This cationic polymer film is electrochemically deposited on boron-doped diamond electrode surface. Unlike the bard electrode, the polymer film-coated diamond electrode can well separate the oxidation potential of AA by 200mV. Thus this electrode can be successfully used for the simultaneoud detection of both species. Increases in the concentration of AA do not affect the reponse of EP and SE.

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Boron doped diamond RDE에 의한 혈액내의 serotonin의 전기화학적 선택적 검출 효과 (Selective electrochemical detection effect of serotonin in blood by using boron doped diamond rotating disk electrode)

  • 황진희;조은인;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.930-933
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    • 2003
  • The electrochemical oxidation of ascorbic acid(AA), serotonin(StT) and epinephrine(EP) have been performed ae poly N,N-dimethylanliline(PDMA) film coated diamond electrode. This cationic polymer film is electrochemically deposited on boron-doped diamond electrode surface. Unlike the bard electrode, the polyaer film-coated diamond electrode can well separate the oxidation potential of AA by 330mV. Thus this electrode can be successfully used for the simultaneoud detection of both species. Increases in the concentration of AA donot affect the reponse of EP and ST.

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Flay Ash 비료화(肥料化) 연구(硏究) III. Flay ash의 붕소(硼素) 독성(毒性) (Utilization of Fly Ash as a Source of Mineral Fertilizers III. Boron Phyto-toxicity)

  • 신제성;임동규;성기석
    • 한국토양비료학회지
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    • 제26권4호
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    • pp.299-303
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    • 1993
  • 석탄회중의 B성분의 식물독성을 검토하기 위하여 B함량이 다른 석탄회를 작토중의 20% 해당량을 토양에 시용하고 콩을 재배하여 1년차 비효 및 2년차 잔효시험으로 수행하였다 B함량이 높은 석탄회는 20% 시용구에서 콩의 생육이 극히 불량하였으며 수량도 거의 전무상태이었으나 B함량이 보통인 석탄회의 시용으로 생육과 수량이 대조에 비해 양호하여 석탄회 다량시용시 석탄회중의 B함량의 검토가 요구되었다.

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Nonlinear vibration analysis of MSGT boron-nitride micro ribbon based mass sensor using DQEM

  • Mohammadimehr, M.;Monajemi, Ahmad A.
    • Smart Structures and Systems
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    • 제18권5호
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    • pp.1029-1062
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    • 2016
  • In this research, the nonlinear free vibration analysis of boron-nitride micro ribbon (BNMR) on the Pasternak elastic foundation under electrical, mechanical and thermal loadings using modified strain gradient theory (MSGT) is studied. Employing the von $K{\acute{a}}rm{\acute{a}}n$ nonlinear geometry theory, the nonlinear equations of motion for the graphene micro ribbon (GMR) using Euler-Bernoulli beam model with considering attached mass and size effects based on Hamilton's principle is obtained. These equations are converted into the nonlinear ordinary differential equations by elimination of the time variable using Kantorovich time-averaging method. To determine nonlinear frequency of GMR under various boundary conditions, and considering mass effect, differential quadrature element method (DQEM) is used. Based on modified strain MSGT, the results of the current model are compared with the obtained results by classical and modified couple stress theories (CT and MCST). Furthermore, the effect of various parameters such as material length scale parameter, attached mass, temperature change, piezoelectric coefficient, two parameters of elastic foundations on the natural frequencies of BNMR is investigated. The results show that for all boundary conditions, by increasing the mass intensity in a fixed position, the linear and nonlinear natural frequency of the GMR reduces. In addition, with increasing of material length scale parameter, the frequency ratio decreases. This results can be used to design and control nano/micro devices and nano electronics to avoid resonance phenomenon.

DETERMINATION OF THE 129I IN PRIMARY COOLANT OF PWR

  • Choi, Ke Chon;Park, Yong Joon;Song, Kyuseok
    • Nuclear Engineering and Technology
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    • 제45권1호
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    • pp.61-66
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    • 2013
  • Among the radioactive wastes generated from the nuclear power plant, a radioactive nuclide such as $^{129}I$ is classified as a difficult-to-measure (DTM) nuclide, owing to its low specific activity. Therefore, the establishment of an analytical procedure, including a chemical separation for $^{129}I$ as a representative DTM, becomes essential. In this report, the adsorption and recovery rate were measured by adding $^{125}I$ as a radio-isotopic tracer ($t_{1/2}$ = 60.14 d) to the simulation sample, in order to measure the activity concentration of $^{129}I$ in a pressurized-water reactor primary coolant. The optimum condition for the maximum recovery yield of iodine on the anion exchange resins (AG1 x2, 50-100 mesh, $Cl^-$ form) was found to be at pH 7. In this report, the effect of the boron content in a pressurized-water reactor primary coolant on the separation process of $^{129}I$ was examined, as was the effect of $^3H$ on the measurement of the activity of iodine. As a result, no influence of the boron content and of the simultaneous $^3H$ presence was found with activity concentrations of $^3H$ lower than 50 Bq/mL, and with a boron concentration of less than 2,000 ${\mu}g/mL$.

고탄소강의 흑연화거동에 미치는 B첨가의 영향 (Effects of Boron Addition on the Graphitization Behavior in High Carbon Steel)

  • 우기도;박영구;김석원;진영철;류재화;나종필
    • 열처리공학회지
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    • 제11권2호
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    • pp.140-149
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    • 1998
  • The graphitization is affected by the addition of small amount of the elements, such as Si, Al, Ni, B, Cr and Mn etc. Boron is well known as the most effective element for the graphitization of cementite in high carbon steels. But a study on quantitative analysis of B effect on the graphitization is few reported. Therefore the effect of boron addition in Fe-0.65%C-1.0%Si-0.5%Mn steels on the graphitization is investigated quantitatively using hardness tester, optical microscope and scanning electron microscope, neutron induced microscopic radiography. The graphitization in high carbon steels is promoted with 0.003~0.005%B addition. But the graphitization in steels which has no boron takes long holding time at $680{\sim}720^{\circ}C$. The hardness of quenched steel containing 0.003%B is higher than that of 0.005%B added steel due to complete dissolution of fine graphites into the austenite. The 0.003%B added high carbon steel graphitized at $680^{\circ}C$ for 25hr is useful steel for the agricultural implements and automobile parts which needed a good formability and high hardness.

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열 이온화 질량분석기를 이용한 보론 동위원소 비 측정연구 (Study in the Measurement of Boron Isotopes by Thermal Ionization Mass Spectrometer)

  • 전영신;조기수;한선호;박용준;지광용
    • 분석과학
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    • 제18권1호
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    • pp.27-34
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    • 2005
  • 보론 동위원소 표준물을 이용하여 $Li_2B_4O_7$$Na_2B_4O_7$를 합성하고 이로부터 $Li_2BO_2{^+}$ (질량 56, 57)와 $Na_2BO_2{^+}$ (질량 88, 89)를 열 이온화 질량분석기를 이용하여 양이온 질량분석법(PTIMS)으로 측정하였으며 또한 같은 시료를 음이온 질량분석법 (NTIMS)으로 $^{10}BO_2{^-}$$^{11}BO_2{^-}$ (질량 42와 43)를 보론 (질량 10, 11)대신 측정하였다. 이들 방법 간의 정밀도와 정확도를 비교하고, 각각의 방법에서 동중원소 영향이 있는지를 알아보았다. 세 가지 방법 중에 NTIMS 방법이 제일 좋은 결과를 보여주었으며 작은 시료 양으로도 안정된 피크를 얻을 수 있었다. NTIMS 방법으로 지하수 약 $5{\mu}L$(약 8 ng-B)를 직접시료로 사용하여 보론 동위원소 비를 측정하여 상대 표준편차 0.03%의 결과를 얻었다. 또한 NTIMS-IDMS로 보론을 정량한 결과 $1.65{\pm}0.003{\mu}g-B/mL$을 얻었으며 ICP-AES 결과에 비해 좋은 정밀도를 보였다.

자전연소합성법을 이용한 비정질 나노 붕소 분말 특성에미치는 첨가제의 영향 (Effect of Additives on the Characteristics of Amorphous Nano Boron Powder Fabricated by Self-Propagating High Temperature Synthesis)

  • 주신형;;이태혁;조영희;김홍물;이혁희;이종현
    • 한국재료학회지
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    • 제25권12호
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    • pp.659-665
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    • 2015
  • The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nano-powders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the $B_2O_3+{\alpha}Mg$ system(${\alpha}=1.0-8.0$) in an argon atmospheres. In this study, the exothermic nature of the $B_2O_3-Mg$ reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the $B_2O_3$ and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, $Na_2B_4O_7$ and $H_3BO_3$ additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the $B_2O_3+{\alpha}Mg$ system with 0.5 mole $Na_2B_4O_7$ was identified to be amorphous boron nano-powders(< 100 nm).