• 제목/요약/키워드: borocarbide

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Phenomenological Theory of Superconductivity and Magnetism in Ho$_{1-x}Dy_xNi_2B_2C$

  • Doh, Hyeon-Jin;Sigrist, Manfred;Cho, B.K.;Lee, Sung-Ik
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.196-199
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    • 1999
  • The coexistence of the superconductivity and magnetism in the Ho1-xDyxNi2B2C is studied by using Ginzburg-Landau theory. This material violates the standard do Gennes scaling showing the coexistence and complex interplay of superconducting and magnetic order yielding an anomalous phase diagram. We propose a phenomenological model which includes two magnetic and two superconducting order parameters accounting for the multi-band structure of this material. We describe the magnetic fluctuations and order and demonstrate that they lead to anomalous behavior of the upper critical field. The doping dependence of Tc in Ho1-xDyxNi2B2C showing a reentrance behavior are analyzed yielding a very good agreement with experimental data.

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저탄소 보론강의 경화능에 미치는 Mo 및 Cr 함량의 영향 (Influence of Mo and Cr Contents on Hardenability of Low-Carbon Boron Steels)

  • 황병철;서동우
    • 한국재료학회지
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    • 제23권10호
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    • pp.555-561
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    • 2013
  • The hardenability of low-carbon boron steels with different molybdenum and chromium contents was investigated using dilatometry, microstructural observations and secondary ion mass spectroscopy (SIMS), and then discussed in terms of the segregation and precipitation behaviors of boron. The hardenability was quantitatively evaluated by a critical cooling rate obtained from the hardness distribution plotted as a function of cooling rate. It was found that the molybdenum addition was more effective than the chromium addition to increase the hardenability of boron steels, in contrast to boron-free steels. The addition of 0.2 wt.% molybdenum completely suppressed the formation of eutectoid ferrite, even at the slow cooling rate of $0.2^{\circ}C/s$, while the addition of 0.5 wt.% chromium did this at cooling rates above $3^{\circ}C/s$. The SIMS analysis results to observe the boron distribution at the austenite grain boundaries confirmed that the addition of 0.2 wt.% molybdenum effectively increased the hardenability of boron steels, as the boron atoms were significantly segregated to the austenite grain boundaries without the precipitation of borocarbide, thus retarding the austenite-to-ferrite transformation compared to the addition of 0.5 wt.% chromium. On the other hand, the synergistic effect of molybdenum and boron on the hardenability of boron steels could be explained from thermodynamic and kinetic perspectives.