• Title/Summary/Keyword: boric acid

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Solubility Study of Nickel Ferrite in Boric Acid Using a Flow-Through Autoclave System under High Temperature and High Pressure

  • Park, Yong Joon;Choi, Ke-Chon;Ha, Yeong-Keong
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.554-558
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    • 2016
  • The solubility of nickel ferrite in an aqueous solution of boric acid was studied by varying the pH at the temperatures ranging from $25^{\circ}C$ to $320^{\circ}C$. A flow-through autoclave system was specially designed and fabricated to measure the solubility of Fe in hydrothermal solutions under high temperature and pressure. The performance of this flow-through system was directly compared with the conventional static state technique using a batch-type autoclave system. The stability of fluid velocity for the flow-through autoclave system was verified prior to the solubility measurement. The influence of chemical additives, such as boric acid and $H_2$, on the solubility of nickel ferrite was also evaluated.

Preparation of Boron Compounds from Colemanite Ore : Application of Microwave in Preparation of Boric Acid (II) (Colemanite 광물로부터 붕소화합물의 제조 : 붕산 제조에 있어서 마이크로파 적용 (II))

  • Lim, Hyung-Mi;Jae, Mi-Jung;Jang, Jae-Hun;Paik, Jong-Hoo;Lee, Mi-Jai;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.804-811
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    • 2004
  • We have studied microwave extraction process of boric acid from one of calcium borate ores, colemanite. Calcium and boron have separated by addition of sulfuric acid, and calcium has been separated out as calcium sulfate. It was possible to extract boron with the smaller amount of sulfuric acid and with short heating time in microwave heating compared to conventional heating process. The products of boric acid was the same purity and thermal characteristic, but smaller in particle size.

Reliability of the Impregnated Boron Compounds, Citric Acid- and Heat-Treated Samama (Anthocephalus macrophyllus) Wood against the Fungal and Termite Attacks

  • Trisna PRIADI;Guruh Sukarno PUTRA;Tekat Dwi CAHYONO
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.1
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    • pp.49-57
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    • 2023
  • This research aimed to evaluate the durability of Samama (Anthocephalus macrophyllus) wood treated with boron preservatives, citric acid (CA), and heating against termites. Wood samples were impregnated firstly with 5% boron solutions, such as boric acid, borax and boric acid + borax combination at 1:1 (w/w). The second impregnation used 5% CA. The impregnations were conducted in a pressure tank at 7 kg/cm2 for 4 hours. After impregnation, the samples were heat treated at 80℃ or 160℃. All the treated and control samples were exposed to decay fungi, drywood termites and subterranean termites based on SNI 7207:2014 standard. The results showed that boron preservatives reduced fungal attacks on Samama wood. The combination treatment of boric acid, CA and heat treatment at 160℃ was also effective to increase the resistance of Samama wood against white- and brown rot fungi, and drywood termites. Heat treatment consistently improved the resistance of Samama wood from decay fungi.

A Study of Heavy Metal-Contaminated Soil Remediation with a EDTA and Boric acid Composite(I): Pb (EDTA와 붕산 혼합용출제를 이용한 중금속으로 오염된 토양의 처리에 관한 연구(I): 납)

  • Lee Jong-Yeol;Kim Yong-Soo;Kwon Young-Ho;Kong Sung-Ho;Park Shin-Young;Lee Chang-Hwan;Sung Hae-Ryun
    • Journal of Soil and Groundwater Environment
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    • v.9 no.4
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    • pp.1-7
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    • 2004
  • To choose a organic acid and in-organic acid composite which is the most effective in soil-flushing process cleaning lead-contaminated sites, lead removal rates were investigated in the experiments with some organic acids; 0.01M of EDTA showed the highest lead-extraction rate ($69.4\%$) compared to the other organic acids. Furthermore, the lead removal rates were measured with 0.01M of EDIA and 0.1M of in-organic acid ; a EDTA and boric acid composite showed the highest lead-extraction rate ($68.8\%$) at pH5 compared to the other composites. As the concentration of boric acid was increased from 0.1M to 0.4M in a 0.01M of EDTA and boric acid composite, lead removal rate was decreased from $68\%\;to\;45\%$. But as the concentration of EDTA was increased from 0.01M to 0.04M in a EDTA and 0.1M of boric acid composite, permeability was decreased from $6.98{\times}10^{-4}cm/sec$ (0.01M of EDTA) to $5.99{\times}10^{-4}cm/sec$ (0.04M of EDTA). However, permeability was increased from $4.41{\times}10^{-4}cm/sec$ (0.03M of EDTA) to $6.26{\times}10^{-4}cm/sec$ (0.03M of EDTA and 0.1M of boric acid composite). indicating EDTA could increase lead dissolution/extraction rate and decrease permeability. In this system, lead remediation rate is the function of lead dissolution rate from soils and permeability of the composite into soils, and the optimized [EDTA]/[Boric acid] ratio is [0.01M]/[0.1M].

Determination of Trace Silicon in Uranium Dioxide by UV-VIS Spectrophometry (UV-VIS 분광광도법을 이용한 이산화우라늄 중 미량 규소 분석)

  • Choi, Kwang-Soon;Joe, Kihsoo;Han, Sun-Ho;Song, Kyuseok
    • Analytical Science and Technology
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    • v.21 no.5
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    • pp.397-402
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    • 2008
  • Uranium dioxide was dissolved with nitric acid and a trace amount of HF. The analytical conditions of a spectrophotometer were investigated to determine a trace amount of silicon in the uranium matrices without a separation process. The effects of a trace amount of HF on the determination of silicon were examined. Boric acid was used to eliminate HF the interference in the colorimetric process. The recovery of silicon in the presence of a trace amount of HF in uranium solutions with or without saturated boric acid was $103.3{\pm}0.8$ and $76.6{\pm}6.8%$, respectively. The amount of saturated boric acid did not affect the recovery of the silicon. Therefore it was possible for this procedure to measure a trace amount of silicon in a uranium matrix without a separation by a UV-VIS spectrophotometry.

Combustibility of Cellulose Insulation Treated with Boric acid-Borax-Aluminium sulfate Formulation (붕산-붕사-Aluminium sulfate 계 셀룰로오스 단열재의 연소특성 연구)

  • Kim, Hong;In, Se-Jin
    • Journal of the Korean Society of Safety
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    • v.7 no.4
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    • pp.7-12
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    • 1992
  • The smouldering combustibility of cellulose insulation treated with boric acid-borax-aluminium sulfate as combustion retardants are examined by cigarette ignition method and electrical cardrige heater method. The effectiveness of Aluminium sulfate as a third combustion are acceptable both smouldering resistance and flame resistance at 18% level of all examined formulation. As the proportion of Aluminium sulfate in the formulation was increased, the flame resistance of cellulose insulation was improved.

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Enhanced Effectiveness of Spodoptera litura Nucleopolyhedrovirus with Organic Acids and Functional Matters (유기산, 기능성물질 혼합에 의한 담배거세미나방 핵다각체병바이러스의 병원성 증진효과)

  • 김선곤;박종대;김도익;박진영;최형국
    • Korean journal of applied entomology
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    • v.43 no.1
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    • pp.55-60
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    • 2004
  • This experiment was conducted to improve activity of Spodoptera litura Nucleopoly-hedrovirus (SINPV) combined with organic and functional matters. In combination of SINPV mixed with organic matters, LT$_{50}$ values of SINPV 1.0${\times}$10$^{5}$ PIBs/$m\ell$ combined with boric acid of 2,000 ppm were 4.5 days. It was 1.5 days shorter than SINPV 1.0${\times}$10$^{5}$ PIBs/$m\ell$ alone. The body weight of larva infected with SINPV 1.0${\times}$10$^{5}$ PIBs/$m\ell$ combined with boric acid of 2,000ppm was not increased, and S. litura was completely dead in 7 days after treatment. It suggested that addition of boric acid in SINPV application enhanced the pathogenicity against S. litura larvae. In laboratory experiment of combination of SINPV with functional matters, LT$_{50}$values of SINPV 1.0${\times}$10$^4$ PIBs/$m\ell$ alone were 7.3 days, but those of SINPV 1.0${\times}$10$^4$ PIBs/$m\ell$ with electrolyzed oxidizing water, pyroligneous liquor or kitosan were 10.4, 9.3 and 11.2 days, respectively. Functional matter could be suppressed the insecticidal activity of SINPV

The Leaching Behavior of Unirradiated $UO_2$ Pellets in Wet Storage and Disposal Conditions

  • Park, Geun-Il;Lee, Hoo-Kun
    • Nuclear Engineering and Technology
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    • v.28 no.4
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    • pp.349-358
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    • 1996
  • The leaching behavior of uranium from unirradiated CANDU UO$_2$ fuel pellet in the spent fuel wet storage and disposal conditions has been investigated. A modified IAEA leach test method was used, and then the extent of leaching was monitored by analysis for uranium in the leachant. The leach test has been performed in various leachants(demineralized water and boric acid solution at pH=6, synthetic granite groundwater) for a long-term period of 5.4 years, and the effect of temperature on the leach rate of uranium has been analyzed. The leach rates of uranium at $25^{\circ}C$ were dependent on the leachants. Over initial 100 days of leach periods, the leach rate in groundwater was the highest in three leachants and no significant differences of leach rates ore observed in the demineralized oater and boric acid solution. But these leach rates in three leachants around 2,000 days at $25^{\circ}C$ appeared to be reached the steady rates in the range of 1~5$\times$10$^{-8}$ g/$\textrm{cm}^2$ day. The leach rate of uranium in groundwater shooed to be independent of the temperature, but those in both demineralized water and boric acid solution increased with temperature. These results show that the leaching behavior of uranium from UO$_2$ fuel in both the demineralized water ann boric acid may be controlled tv the surface oxidative.dissolution reaction of UO$_2$ and the leach rate of uranium in groundwater at room temperature could mainly be controlled by the complex reaction of dissolved uranyl ions with carbonate ions and no variation of leach rate of UO$_2$ in groundwater with temperature may be due to the local deposition of passivating uranyl phases on the surface.

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Dimensional Stability, Color Change, and Durability of Boron-MMA Treated Red Jabon (Antochephalus macrophyllus) Wood

  • PRIADI, Trisna;ORFIAN, Gema;CAHYONO, Tekat Dwi;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.3
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    • pp.315-325
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    • 2020
  • Boron compound had many advantages as wood preservative, but it was prone to leaching. Improving boron preservation was required to extend the service life of fast growing and low durability red jabon (Antochephalus macrophyllus) hardwood. This study aimed to evaluate the dimensional stability, color change and durability of modified red jabon wood by double impregnation with boron and methyl methacrylate (MMA) and heat treatment. Impregnation I used boric acid or borax, and impregnation II used MMA, while heat treatment used temperatures of 90 ℃ or 180 ℃ for 4 hours. The dimensional stability, leachability, water absorption, color change and decay resistance of modified red jabon wood were tested. The results showed that MMA impregnation increased the dimensional stability of red jabon wood, while the leaching and water absorption in the wood significantly reduced. Heating at 180 ℃ caused less water absorption and higher dimensional stability of the wood than that of heating at 90 ℃. Impregnation with boric acid and MMA followed by heating at 90 ℃ resulted in the highest wood ASE, 89.9%. The color change (∆E*) of wood increased significantly after MMA impregnation and heating at 180 ℃. Boric acid impregnation caused more resistant wood than borax impregnation against decay fungi and termites. Impregnation with boric acid and MMA followed with heating at 180 ℃ increased significantly the wood resistance against decay fungi and termites.

Depositing Rate of Electroless Nickel Plating Bath Contained Triethanolamine as a Complexing Agent (트리에탄올아민을 錯化劑로 사용한 無電解니켈鍍金浴의 析出速度에 관한 硏究)

  • Yeo, Woon-Kwan
    • Journal of the Korean institute of surface engineering
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    • v.18 no.4
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    • pp.153-163
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    • 1985
  • In the electroless nickel plating bath which contained nickel sulfate, sodium hypophosphite, boric acid and triethanolamine, effect of their concentration on the rate of deposition was tested by gravimetric method and polarization method. The polarization method that polarize small range of voltage anodicaly and cathodicaly at the mixed potential in the electroless plating bath can calculate mixed current (depositing rate) from $i_{mp}=\frac {i}{\eta}\;\frac{RT}{nF}\;or\;i_{mp}=\frac{i}{\eta}\;\frac{1}{2.3}(\frac{b_a\;\;b_c}{b_c+b_a})$ Where $i_{mp}$ is the depositing current, i is the polarized current, ${\eta}$ is the polarized voltage, $b_a\;and\;b_c$ are the Tafel slop of anodic and cathodic polarization curves respectively. The calculated mixed current ($i_{mp}$) is proportional to the depositing rate obtained by gravimetric method and corresponded mostly to the real depositing rate by multifying supplementary constant. The polarization method can be used for founding inclination of reaction on various concentration of each composition. Decreasing or increasing concentration of triethanolaminc as a complexing agent , the depositing rate is decreased and when the bath contained 25-50mL/L of triethanoloamine, the depositing rate is increased. The depositing rate is increased with increasing the concentration of boric acid, and when the bath contained 0.5M of boric acid, the depositing rate is increased abruptly. The optimum composition of the electroless nickel bath was estimated 0.1M of nickel sulfate, 0.25M of sodium hypophosphite, 0.5M of boric acid, and 25-50mL/L of triethanalamine.

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