• Title/Summary/Keyword: borax

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Development of Micronutrient Fertilizer -I. Characteristics of Raw Materials and Products (종합미량원소비료(綜合微量元素肥料)의 개발(開發)에 관(關)한 연구 -I. 원료(原料) 및 제품(製品)의 특성(特性))

  • Lim, Dong-Kyu;Seong, Ki-Seog;Shin, Jae-Sung;Park, Young-Sun
    • Korean Journal of Soil Science and Fertilizer
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    • v.14 no.2
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    • pp.88-94
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    • 1981
  • A trial manulacturing of the micronutrient fertilizer made of local mineral ores was conducted. A powdered mixture of raw materials was fused in an electric furnance and the molten matrix was quenched, dried and milled. Some informations from the manufacturing were summarized as followings. 1. Of all the ore minerals, only borax and manganese ores could be molten independently. 2. Borax was the best material for decreasing the molten temperature. 3. The molten temperature was increased with increased Ca and Mg content of the mixture. 4. The amounts of 2 % citric acid soluble Fe, Zn, and Mo were increased rapidly with increased temperature, but those of B and Mn were constant. 5. During the manufacturing process, the nutrient loss was high in order of boron, zinc and molybdenium.

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Dimensional Stability, Color Change, and Durability of Boron-MMA Treated Red Jabon (Antochephalus macrophyllus) Wood

  • PRIADI, Trisna;ORFIAN, Gema;CAHYONO, Tekat Dwi;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.3
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    • pp.315-325
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    • 2020
  • Boron compound had many advantages as wood preservative, but it was prone to leaching. Improving boron preservation was required to extend the service life of fast growing and low durability red jabon (Antochephalus macrophyllus) hardwood. This study aimed to evaluate the dimensional stability, color change and durability of modified red jabon wood by double impregnation with boron and methyl methacrylate (MMA) and heat treatment. Impregnation I used boric acid or borax, and impregnation II used MMA, while heat treatment used temperatures of 90 ℃ or 180 ℃ for 4 hours. The dimensional stability, leachability, water absorption, color change and decay resistance of modified red jabon wood were tested. The results showed that MMA impregnation increased the dimensional stability of red jabon wood, while the leaching and water absorption in the wood significantly reduced. Heating at 180 ℃ caused less water absorption and higher dimensional stability of the wood than that of heating at 90 ℃. Impregnation with boric acid and MMA followed by heating at 90 ℃ resulted in the highest wood ASE, 89.9%. The color change (∆E*) of wood increased significantly after MMA impregnation and heating at 180 ℃. Boric acid impregnation caused more resistant wood than borax impregnation against decay fungi and termites. Impregnation with boric acid and MMA followed with heating at 180 ℃ increased significantly the wood resistance against decay fungi and termites.

A Study on the Formation of Carbide Layers on Steels Immerged in Fused Borox Bath Containing Fe-V (Fe-V을 첨가한 용융 붕사욕에서 강의 탄화물 형성에 관한 연구)

  • Lee, Byung-Kwon
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.2
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    • pp.19-26
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    • 1991
  • This study has been constructed to establish the formation of the VC layer on various steels by immersion in fused borax bath containing Fe-V powder. The result obtained from the experiment are as follows. (1) The carbide is supposed to grow on the front surface of the carbide layers by the reaction between carbide-forming elements dissolved in the fused borax and carbon atoms successively supplied through the layer from the matrix. (2) The growth rate of the carbide layers was controlled by the diffusion rate of C in the carbide layer and C content in the matrix. (3) Carbide layer formed on the surface of the specimen is VC layer and the hardness of this layer is above $H_v$ 3000.

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A study on the Bending Fatigue Strength of Die Steels coated with VC(Vanadium Carbide)by Immersing in Molten Borax Bath (용융염 침적법에 의한 VC coating 금형강의 굽힘 피로강도에 관한 연구)

  • Lee, B.K.;Nam, T.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.3
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    • pp.166-177
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    • 1993
  • Bending fatigue strength tests were made for VC coated die steels which were coated by immersing in a molten borax bath and for hardened die steels which were quenched and tempered, in order to clarify the effect of VC coating at $1000^{\circ}C$ and $1025^{\circ}C$. The material used in this investigation was a representative cold and hot die steels STD11, STD61. The results obtained are as follows. 1) The endurance limit of VC coated die steels was a little lower than that of hardened die steels. It is considered to be mainly due to the decfl.lase of hardness in the substrates. Accordingly, the endurance limit reo covered almost to the level of hardened die steels by an additional diffusion treatment. 2) The initiation point of fatigue fracture of VC coated die steels in reversed bening was on the substrate just under the VC layer. Hence, the endurance limit is corrected to the hardness of this part. 3) But, there is a considerable scatter in this relationship and the endurance limit of VC coated die steels was a little lower than that of hardened die steels with equal hardness. These results suggest that the fatigue strength of VC coated die steels is determined not only by the hardness but also by other factors. For example. the residual stress in the substrate just under VC coating layer is one of the factors besides hardness which is mainly related to the retained austenite(${\gamma}_R$).

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Oxygen Index of Fire-Retardant-Treated Plywood in Burning Test (산소지수법(酸素指數法)에 의한 내화처리합판(耐火處理合板)의 연소시험(燃燒試驗))

  • Lee, Phil Woo;Eom, Young Geun;Kim, Hyun Joong
    • Journal of Korean Society of Forest Science
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    • v.78 no.4
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    • pp.419-424
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    • 1989
  • To obtain relative effectiveness in fire resistance among fire retardant chemicals, oxygen indices were determined for 3.5 mm thick, three-ply, meranti plywoods, treated with 5 commercial chemicals and water and then press-dried, through Up and Down method following oxygen index test of ASTM D 2863-77. The oxygen indices obtained were 28.4 for ammonium sulfate, 26.9 for monoammonium phosphate, 43.4 for diammonium phosphate, 30.1 for borax-boric acid, 32.4 for minalith, and 25.5 for water. Therefore, diammonium phosphate was found to rank first in fire-retardant effectiveness, followed by minalith, borax-boric acid, ammonium sulfate, and monoammonium phosphate in turn, judging from the fact that highly flammable materials are likely to have a low oxygen index.

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Proper Mixing Ratio for Securing Quality of Free-form Panel (비정형 패널의 형상 품질확보를 위한 적정 배합비 도출)

  • Kim, Min-Sik;Park, Chae-Wool;Kim, Ki-Hyuk;Do, Sung-Lok;Lee, Dong-Hoon
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.5
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    • pp.449-456
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    • 2019
  • Recent developments in architectural technologies and programs have enabled architects to think creatively and design free-form architecture. however, there are many problems in the production technology of FCP(Free-Form Concrete Panel). In particular, reduced accuracy due to lack of free-form panel production technology can lead to redesign of buildings as a result, problems such as an increase in construction cost and period. Therefore, this experiment aimed to compensate the decrease of the accuracy according to the displacement difference and to derive the proper mixing ratio for maintaining the shape during the free-form panel curing. In this study, molds were made using paraffin that is a recyclable phase change material. Concrete Panel is usually produced from Portland cement, dead burn magnesia, phosphate, borax and fine aggregate. In this study, four mixing ratios of FCP were selected after each material was blended to determine the proper blending ratio of the fluidity phase, the water absorption rate and the water content of the test piece. FCP was fabricated on the basis of the selected four compounding ratios and thickness and error rate were measured. Based on the error rate of the measured FCP, the quality standard was satisfied among the four compounding ratios.

Studies on Fire-Retardant-Treatment and Press Drying of Plywood (합판(合板)의 내화처리(耐火處理)와 열판건조(熱板乾燥)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Kim, Jong-Man
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.1
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    • pp.5-37
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    • 1982
  • Plywood used for construction as a decorative inner material is inflammable to bring large fire accidents and burn out human life and their properties. To diminish the fire disaster, fire retardant plywood has been required indeed. In the methods of manufacturing the fire retardant plywood the soaking method is occasionally used. However after soaking plywood into fire retardant chemical solutions, redrying of soaked plywood is the most important. In this study, 3.5mm thin and 5.0mm thick plywoods were selected for fire retardant treatment. Treating solutions were prepared for 20% dilute solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, borax-boric acid and minalith, and water solution. 1-, 3-, 6-, and 9 hour-soaking treatments were applied and after treatments hot plate drying was applied to those treated plywoods at $90^{\circ}C$, $120^{\circ}C$ and $150^{\circ}C$, of press temperature. Drying rates, drying curves, water absorption rates of fire retardant chemicals, weight per volume and fire retardant degree of plywood were investigated. The results may be summarized as follows: 1. The plywoods treated with ammonium sulfate, monoammonium phosphate and diammonium phosphate and diammonium phosphate showed increase of chemical absorption rate with proportion to increase of treating time, but not in case of the plywood treated with borax-boric acid and minalith. 2. In the treatment of definite time, the absorption rate per unit of volume of plywood showed higher in thin plywood (thickness of 3.5mm) than in thick plywood (thickness of 5.0mm). In both thin and thick plywoods, the highest absorption rate was observed in 9 hour-treatment of ammonium sulfate. The value was 1.353kg/$(30cm)^3$ in thin plywood and 1.356kg/$(30cm)^3$ in thick plywood. 3. The volume per weight of plywood after chemical treatment increased remarkably and. after hot plate drying, the values were to a little extent higher than before chemical treatment. 4. The swelling rates of thickness in chemical-treated plywoods increased similarly with that of water-treated plywood in 1- and 3 hour-treatment of both thin and thick plywoods. But in 6- and 9 hour-treatment, the greater increased value showed in water-treated ply wood than any other chemical, especially in thick plywood. 5. The shrinkage rates after hot plate drying showed the same tendency as the swelling rate, and the rate showed the increasing tendency with proportion to increase of treating time in thick plywood of both chemical and water treatments. 6. Among drying curves, the curves of water-treated plywood placed more highly than chemical-treated plywood without-relation to thickness in 6- and 9 hour-treatment except in 1- and 3 hour-treatment. 7. The drying rate related to thickness of treated plywood, was twice above in thin plywood compared with thick plywood. 8. The drying rate remarkably increased with proportion to increase of the plate temperature and, the values were respectively 1.226%/min., 6.540%/min., 25.752%/min. in hot plate temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in thin plywood and 0.550%/min., 2.490%/min, 8.187%/min, in hot plate temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in thick plywood. 9. In the treatment at $120^{\circ}C$ of hot plate temperature, the drying rates of chemical-treated plywood showed the highest value in monoammonium phosphate of thin plywood and in diammonium phosphate of thick plywood. But the drying rate of water-treated plywood was highest in 6- and 9 hour-treatment. 10. The fire retardant degree of chemical-treated plywood was higher than that of the untreated plywood as shown in loss of weight, burning time, flame-exhausted time and carbonized area. 11. The fire-retardant effect among fire retardant chemicals were the greatest in diammonium phosphate, the next were in monoammonium phosphate and ammonium sulfate, and the weakest were in borax-boric and minalith.

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A Study on Combustion Property of Cellulose Insulation according to Particle Size (입도에 따른 셀룰로오스 단열재의 연소특성에 관한 연구)

  • Choi, Jeong-hwa;Kim, Hong;Yoo, Kyong-Ok
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1996.11a
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    • pp.62-67
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    • 1996
  • The smouldering combustion of cellulose Insulation treated with boric acid - borax - aluminium sulfate as combustion retardants are examined by candle type combustibility tester. The flammability behavior of combustion process is LOI, Smouldering region, Smouldering, Flamming spread region and Flame spread region. In this experiment, Particle size of four examined LOI, L.Point, H.Point, at the biggest size show high LOI. The surface area is connected with thermal conduction. The phenomena of combustion transition are governed by quantity of combustible gas generation in heating zone of cellulose insulation.

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The effect of Reductants on the electro-boronizing (전해침붕처리에서 환원제 첨가의 영향)

  • 최진일
    • Journal of the Korean institute of surface engineering
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    • v.28 no.2
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    • pp.110-118
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    • 1995
  • The effect of reductants (Ti, Si, Al, Mn, Fe) addition into molten Borax has been studied on oxidation resistance and the growth of boronized layer formed during electro-boronizing on the substrate such as carbon steel and STS 430. Experiments have been carried out at the current density of 0.5 A/$\cm^2$ and in temperature range of 600~$1000^{\circ}C$ for 1~5 hours. The penetrated depth of the boron increased with addition of reductants (Ti, Si, Al) and decreased with addition of Mn and Fe. But excessive addition of reductants inhibited the boronizing due to an increase in viscosity of electrolyte. Oxidation resistance of the boronized carbon steel was improved but that of the boronized STS 430 decreased.

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