• Title/Summary/Keyword: bonding network

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Development of High-strength Polyethylene Terephthalate (PET) Sheet Through Low Melting Point Binder Compounding and Compression Process (저 융점 바인더 복합화 및 압착공정을 통한 고강도 폴리에틸렌 테레프탈레이트(PET) 시트 개발)

  • Moon, Jai Joung;Park, Ok-Kyung;Kim, Nam Hoon
    • Composites Research
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    • v.33 no.5
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    • pp.282-287
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    • 2020
  • In the present study, a high-strength polyethylene terephthalate (PET) sheet was fabricated through a densification process of low melting PET fiber (LMF) combined PET sheet. During the thermal heat treatment process of the combined LMF, individual PET fiber was connected, which in turn leads to the improvement of the interfacial bonding force between the fibers. Also, the densification of the PET sheet leads to reduce macrospore density and in return could enhance the binding force between the overlapped PET networks. Consequently, the asprepared LMF-PET sheet showed about 410% improved tensile strength and the same elongation compared to before compression. Besides, the enhanced bonding force can prevent the shrinkage of the PET fiber network and exhibited excellent dimensional stability.

Changes of HwBKP, SwBKP, OCC Handsheets' Drying Behavior and Physical Properties by Refining, Kneading and Wet Pressing (고해, 니딩, 습부압착에 의한 HwBKP, SwBKP, OCC 수초지의 건조 거동 및 물성 변화)

  • Lee, Jin-Ho;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.5
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    • pp.17-26
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    • 2011
  • Drying behavior and physical properties of HwBKP, SwBKP, and OCC handsheets depending on kneading, refining and wet pressing were analyzed. The maximum drying shrinkage velocity was newly adopted to verify the effect of mechanical treatment of pulps by evaluating drying behavior according to varying the kneading, refining and wet pressing treatments. Those various treatments were changed to evaluate the relationship between the maximum drying shrinkage velocity and handsheets properties. When the drying shrinkage and the maximum drying velocity increased by refining and wet-pressing, handsheets strength was increased. The maximum drying shrinkage velocity showed higher correlation with physical properties of paper than WRV at different refining loads at SwBKP and mixed pulp. At high wet-web dryness, drying shrinkage, the maximum drying shrinkage velocity and strength properties of handsheet were increased. It meant that drying shrinkage behavior was highly affected by not only fibers' shrinkage but also fiber bonding. Kneading pre-treatment for KOCC and SwBKP effectively modified fiber properties and increasing paper strength and drying shrinkage. The effect of kneading pre-treatment was also confirmed by the maximum drying shrinkage velocity. Strength properties of mixed pulp handsheets were not increased by the kneading pre-treatment, although the maximum drying shrinkage velocity and WRV was increased. It meant that fibers network bonding of HwBKP was limited because of ves sels and ray cells' interference for bonding. Therefore in order to improve paper strengths containing HwBKP by mechanical treatments, interference of vessels and ray cells for fiber bondings should be carefully controlled.

Formation of Social relationship through SNS and adolescents' life satisfaction (SNS를 통한 사회적 관계 형성과 청소년의 삶의 만족)

  • Park, So-Young;Cho, Sung-Hui
    • Journal of Digital Convergence
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    • v.13 no.2
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    • pp.371-379
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    • 2015
  • The degree of adolescents' life satisfaction is very low and the formation of social relationship through SNS is getting important to adolescents. This study aimed to examine if bridging social capital and bonding social capital through SNS and political-social participation affect the life satisfaction of adolescents. Using 2012 Adolescents Social Media Usage Survey of National Youth Policy Institute, this study analyzed 4708 data by Multiple Regression. The results showed that the life satisfaction of male adolescents was higher than that of female adolescents. And the higher the level of bridging social capital and bonding social capital through SNS and political-social participation was, the higher the level of adolescents' life satisfaction. On the basis of the results, practical suggestions to increase the life satisfaction of adolescents were discussed.

A Study on Design and Manufacturing Methods of Dual-Polarization Monopulse Feed Structure in Millimeter-wave(W band) (밀리미터파(W대역) 이중편파 모노펄스 급전 구조 설계 및 제작 방안 연구)

  • Jong-Gyun Baek;Hyeong-Ki Lee;Young-Wan Kim;Hee-Duck Chae;Ji-Han Joo;Jaesik Kim
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.23 no.6
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    • pp.47-53
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    • 2023
  • In this paper, We designed a waveguide-type feed structure that converts millimeter wave dual-polarized signals into monopulse signals and presented a manufacturing method. At millimeter-wave such as the W band, the size of the waveguide is very small, making it very difficult to manufacture complex structures. Therefore, because manufacturability is important for the waveguide-type feed structure in the millimeter-wave, electro forming and diffusion bonding were proposed and verified in this study. The designed monopulse feed structure consists of eight 180° hybrids that combine 90° hybrids and self-compensating phase shifters, and four OMTs to separate dual polarization. The designed feed structure was designed to facilitate electro forming and diffusion bonding, and the manufactured feed structure was verified through a network analyzer. It was confirmed that the two proposed production methods produce a monopulse signal well through the measured magnitude and phase of the port.

Effects of Gender and Region on the Relationships between Teenagers' Use of Social Network Sites and Social Capital (청소년들의 소셜 네트워크 사이트 이용과 사회적 자본의 상관관계에 있어서의 성별 및 지역 차이)

  • Lee, Herim Erin;Cho, Jaehee
    • Journal of Internet Computing and Services
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    • v.17 no.1
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    • pp.83-89
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    • 2016
  • This study aimed to examine how gender and regional differences affect the relationships between SNS use and social capital. By analyzing a large set of data from Korean teenagers, significant roles of gender and regional differences could be found. In regards to gender difference, the most notable finding was the negative effects of SNS use on bonding and bridging social capital among male teenagers. Furthermore, it was found that such negative effects of SNS use were significant particularly among urban teenagers. These findings theoretically contribute to broadening the understanding of the relationships between SNS use and social capital.

Self-assembly and Mechanism of L-Alanine-based Dihydrazide Derivative as Excellent Gelator of Organic Solvents

  • Wang, Chuan-Sheng;Wang, Xiao-Hong;Li, Zhi-Yuan;Wei, Wei;Shi, Zhong-Liang;Sui, Zhi-Tong
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1258-1262
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    • 2011
  • A new organogelator, L-Alanine dihydrazide derivative can self-assemble in various organic solvents and turned them into thermally reversible physical supramolecular organogels at extremely low concentrations (< 2 wt %). The gel-sol phase transition temperatures ($T_{GS}$) were determined as a function of gelator concentration and the corresponding enthalpies (${\Delta}H_g$) were extracted. Scanning electron microscopy (SEM) measurements revealed that the interspaces of fiber-like network structures were diminished with the increasing of the LMOG concentration. FT-IR spectroscopy studies revealed that hydrogen-bonding and hydrophobic interaction were the driving forces for the formation of the gels. Based on the data of XRD and molecular modeling, the possible packing modes for the formation of organogelator aggregates were proposed.

Relationship between Local SNS Usage and Social Capital

  • Yao, Chunliang;Joo, Jae-Hun;Shin, M. Minsuk
    • Journal of Distribution Science
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    • v.14 no.8
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    • pp.35-44
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    • 2016
  • Purpose - This study aims to understand the relationship between Chinese local SNS usage and social capital building through Chinese international students in South Korea. A research model that illustrates the relationship between the SNS usage (i.e., intensity, communication and social capital building is proposed. Based on the analysis, this study will provide responses to the question of if SNS really presents the danger of trapping international consumers in their local comfort zone or enhance social capital for the users. Research design, data, and methodology - The survey questionnaire is circulated among the WeChat (a Chinese local SNS) users who are the Chinese international students studying in South Korea. The collected data is analyzed by structural equation method using SPSS and AMOS. Results - Proposed hypotheses of the positive relationships between the attachment of SNS use and both individuals' bridging and bonding social capital are supported. It's also supported that (1) interpersonal communication, (2) interpersonal communication with old friends, and (3) interpersonal communication for making new friends on SNS positively influence individuals' bridging social capital. Conclusions - This paper demonstrates the importance of intensity of WeChat use and interpersonal communication that impact Chinese international students' bridging and bonding social capital on WeChat.

A Stud on the Fabrication and Characteristics of Al-Sn Alloy Strips by Twin-Roll Process (쌍롤법에 의한 Al-Sn합금 Strip의 제조 및 특성에 관한 연구)

  • Lee, Jeong-Keun;Joo, Dae-Heon;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.22 no.4
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    • pp.174-183
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    • 2002
  • Twin-roll process is a relatively new continuous casting process which can produce high-quality strip products directly, and solidification rate can reach $10^3$ to $10^4$ K/s, leading to fine and uniform microstructures with enhanced mechanical properties. The strip casting condition for producing fine Al-Sn alloy strip was obtained experimentally, and defects appearing on the strip was examined. Crack formation and surface quality of the strip was found to depend mainly on process parameters such as melt temperature, roller gap and rolling speed. Sn structure of network type was observed in Al-20Sn and Al-40Sn alloy strips, and cell spacing of Al-40Sn alloy was smaller than that of Al-20Sn. Banding strength of the heat treated specimens increased with increasing of soaking time and temperature, and bonding strength of Al-20Sn alloy was more superior than that of Al-40Sn alloy. However wear resistance of Al-40Sn alloy contained large amount of soft Sn which possess good anti-friction characteristics was superior than that of Al-20Sn alloy.

First Principles Study on Hydrolysis of Hazardous Chemicals PCl3 and POCl3 Catalyzed by Water Molecules (제일원리 계산을 통한 유해화학물질 PCl3와 POCl3의 물분자 촉진 수화반응 연구)

  • Jeong, Hyeon-Uk;Gang, Jun-Hui;Jeon, Ho-Je;Han, Byeong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.126-126
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    • 2017
  • Using first principles calculations we unveil fundamental mechanism of hydrolysis reactions of two hazardous chemicals $PCl_3$ and $POCl_3$ with molecular water clusters nearby. It is found that the water molecules play a key role as a catalyst significantly lowing the activation barriers by transferring its protons to the reaction intermediates. Interestingly, torsional angles of molecular complexes at transition states are identified as a vital descriptor on the reaction rate. Analysis of charge distribution over the complexes further reinforces the finding with atomic level correlation between the torsional angle and variation of the orbital hybridization state of P in the complex. Electronic charge separation (or polarization) enhances thermodynamic stability of the activated complex at transition state and reduces the activation energy through hydrogen bonding network with water molecules nearby. Calculated potential energy surfaces (PES) for the hydrolysis reactions of $PCl_3$ and $POCl_3$ depict their two contrastingly different profiles of double- and triple-deep wells, respectively. It is ascribed to the unique double-bonding O=P in the $POCl_3$. Our results on the activation free energy show well agreements with previous experimental data within $7kcalmol^{-1}$ deviation.

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Molecular Design for the Formation of Two-dimensional Molecular Networks: STM Study of ${\gamma}$-phenylalanine on Au(111)

  • Jeon, A-Ram;Youn, Young-Sang;Lee, Hee-Seung;Kim, Se-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.205-205
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    • 2011
  • The self-assembly of ${\gamma}$-phenylalanine on Au(111) at 150 K was investigated using scanning tunneling microscopy (STM). Phenylalanine can potentially form two-dimensional (2D) molecular networks through hydrogen bonding (through the carboxyl and amino groups) and ${\pi}-{\pi}$ stacking interactions (via aromatic rings). We found that ${\gamma}$-phenylalanine molecules self-assembled on Au(111) surfaces into well-ordered structures such as ring-shaped clusters (at low and intermediate coverages) and 2D molecular domains (intermediate and monolayer coverages), whereas ${\alpha}$-phenylalanine molecules formed less-ordered structure on Au(111). The self-assembly of ${\gamma}$- but not ${\alpha}$-phenylalanine may be related to the flexibility of the carboxyl and amino groups in the molecule. Moreover, as expected, the 2D molecular network of ${\gamma}$-phenylalanine on Au(111) was mediated by a combination of hydrogen bonding and ${\pi}-{\pi}$ stacking interactions.

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