• 제목/요약/키워드: bonding mechanism

검색결과 294건 처리시간 0.023초

Tribological Performance of A1203/Ni0r Coating

  • Chae, Young-Hun;Kim, Seock-Sam
    • Journal of Mechanical Science and Technology
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    • 제16권7호
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    • pp.911-918
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    • 2002
  • The tribological performance of A1$_2$O$_3$/NiCr coating deposited on steel (SH45C) was investigated under lubrication. The parameters of sliding wear consist of normal load and coating thickness. Test result showed that there was no evidence of an improved bonding strength in the coating. However, the wear resistance of the A1$_2$O$_3$/NiCr coaling was significantly greater than that of the Al$_2$O$_3$ coating. It was eviclent that the residual stress for the A1$_2$O$_3$coating was higher than that of the A1$_2$O$_3$/NiCr coating from the Scratch test failure of coating. The bond coating played an important role in decreasing the residual stress. Also, it was found that the residual stress had d notable influence on the wear mechanism.

Pulsed laser ablation of hydroxyapatite in ethanol

  • Lee, Jung-Il;Ryu, Jeong Ho
    • 한국결정성장학회지
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    • 제24권5호
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    • pp.219-223
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    • 2014
  • Pulsed laser ablation in liquid medium was successfully employed to synthesize hydroxyapatite colloidal nanoparticles. The crystalline phase, particle morphology, size distribution and microstructure of the hydroxyapatite nanoparticles were investigated in detail. The obtained hydroxyapatite nanoparticles had spherical shape with sizes ranging from 5 to 20 nm. The laser ablation and the nanoparticle forming process were discussed with explosive ejection mechanism by investigating change of surface morphology on target. The analytical results of XPS, FT-IR and Raman spectroscopy confirms that the stoichiometry and bonding properties of the hydroxyapatite nanoparticles are in good agreement with reported bulk hydroxyapatite materials.

초고온융 공기예열식 열교환기의 개발 및 성능 평가 (The Development and Performance Evaluation of the Air-preheating Heat Exchanger for Ultra-high Temperature Applications)

  • 박용환
    • 한국안전학회지
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    • 제14권4호
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    • pp.78-84
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    • 1999
  • A compact air-preheating type heat exchanger was developed and tested for the ultra-high temperature heat recovery applications. For the direct use of exhaust gases up to $1200^{\circ}C$, the heat exchanger adopted a ceramic core with high strength and low thermal expansion coefficient less than $1{\times}10^{-6}^{\circ}C^{-1}$. The ceramic core was fabricated by special extrusion and bonding techniques. To minimize thermal stresses in the core, spring-loaded sealing mechanism was designed and successfully installed. 1-pass air flow scheme was adopted for the compactness and cost-savings. The pressure test for the ceramic core showed no failure under 35 kPa and less than 3% leak under 7 kPa. Flue gas simulation system was developed to investigate the performance of the heat exchanger. The test results showed normal operations of the heat exchanger up to $1200^{\circ}C$ of exhaust gases and relatively high heat recovery efficiencies of 31~39% depending upon exhaust gas temperatures..

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전기재료장 경질탄소 제조에 관한 연구 (A study on Fabrication of Harden Carbon for Electrical Application)

  • 지명학;임대영;김종옥
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.198-201
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    • 1995
  • Carbons are the materials which are known to be usable at highest temperature in existing materials and are being increased their mechanical Properties to 2000$^{\circ}C$. They have many advantageous characteristics such as electrical and thereat conductivity. But, inspire of their properties, this materials have covalant bonding that strong1y link their atoms. the covalant bondings are too strong to occur atomic diffusions or shirinkages during the sintering. because of this sintering mechanism, carbon materials must be produced by using some binders. To obtain a good carton material, it is important that the function of binders. And to obtain a good binder, it reqired the additive which can improve the properties of the binder, so called curing agent. In this study, we make a curing agent that can improve the properties of binders to evaluate the yield of carbon from binders and to shirink the substrate. and compared the carbon materials treated with the binder containing the curing agent to that treated with common binder.

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자동 광섬유 정렬 장치의 설계 및 제작에 관한 연구 (A Study on the Design and Development of Automatic Optical Fiber Aligner)

  • 김병희;엄철;최영석
    • 산업기술연구
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    • 제22권B호
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    • pp.241-249
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    • 2002
  • Optical fiber is indispensable for optical communication systems that transmit large volumes of data at high speed, but super precision technology in sub-micron units is required for optical axis adjustment. We developed the automatic optical fiber by image processing and automatic loading system. we have developed 6-axis micro stage system for I/O optical fiber arrays, the initial automatic aligning system software for a input optical array by the image processing technique, fast I/O-synchronous aligning strategy, the automatic loading/unloading system and the automatic UV bonding mechanism. In order to adjust the alignment it used on PC based motion controller, a $10{\mu}m$ repeat-detailed drawing of automatic loading system is developed by a primary line up for high detailed drawing. Also, at this researches used the image processing system and algorithm instead of the existing a primary hand-line up and fiber input array and waveguide chip formed in line by automatic.

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Theoretical Study of the Interaction of N2O with Pd(110)

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2369-2376
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    • 2007
  • N2O has been found from experimental and theoretical considerations to bind on-top to the Pd(110) surface in a tilted end-on fashion via its terminal N atom. We use a frontier orbital description of the bonding interactions in the Pd-N2O system to obtain molecular insight into the catalytic mechanism of the activation of N2O by the Pd(110) surface giving rise to the formation of N2 and O on the surface. For the tilted end-on N2O binding mode, the LUMO 3π of N2O has good overlap with the Pd dσ and dπ orbitals which can serve as the electron donors. The donor-acceptor orbital overlap is favorable for electron transfer from Pd to N2O and is expected to dominate the surface reaction pathway of N2O decomposition.

Surface Analysis of Papers Treated with N-chloro-polyacrylamide Using X-ray Photoelectron Spectroscopy: Mechanism of Wet Strength Development

  • Chen Shaoping;Wu Zonghua;Tanaka Hiroo
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 1999년도 Pre-symposium of the 10th ISWPC Recent Advances in Paper Science and Technology
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    • pp.276-281
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    • 1999
  • The surfaces of sheets added with N-chloro-polyacrylamide (N-Cl-PAM) are analyzed using X-ray photoelectron spectroscopy (XPS) to clarify the chemical bonding involved in the paper strength development induced by N-Cl-PAM. The comparison of the observed N1s chemical shift of the sheet with those of the paper strength additives and the model compound, 1-butyryl-3-propyl urea, illustrated the presence of covalent bonds of alkyl acyl urea and urethane on the fiber surfaces. Thus the formation of the covalent bonds by N-Cl-PAM themselves and by N-Cl-PAM with cellulose and hemicellulose may be an explanation for much higher effectiveness of N-Cl-PAM on the improvement of wet strength of paper than A-PAM.

강판으로 보강된 철근콘크리트 부재의 박리기준 유도 (Derivation of Plate Separation Criteria for Reinforced Concrete Members Strengthened with Steel Plates)

  • 오병환;박대균;조재열
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.745-750
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    • 2000
  • Steel plate bonding technique is most widely used in strengthening of existing concrete structures, but it has inherently a problem of the premature failure such as interface separation and rip off. So far, many studies have been arid out in the manner of laboratory tests for the reinforced concrete beams to find out he mechanism of the premature failure. However, in order to verify the characteristics of the premature failure, more reasonable local investigations are needed rather than such relatively global experimental works. In this study, therefore, the double lap test which simulate the pure shear loadings and the half beam tests which consider combined flexure-shear force have been done. There are, however, difficulties in getting the normal stress caused to premature failure, so that finite element analysis was performed, too. In numerical study, material nonlinearity was considered, and the interface element was applied to model the interface between steel plate and adhesive. From the results of experimental and numerical studies, a realistic failure criterion on the separation of steel plates has been derived.

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Navigation Connection용 ACF(Anisotropic Conductive Film)의 수명 예측 (Lifetime Estimation of an ACF in Navigation)

  • 유영창;신승중;곽계달
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1277-1282
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    • 2008
  • Recently LCD panels have becom very important components for portable electronics. In the high density interconnection material, ACF's are used to connect the outer lead of the tape automated bonding to the transparent indium tin oxide electrodes of the LCD panel. ACF consists of an adhesive polymer matrix and randomly dispersed conductive balls. In this study, we analyzed Failure Mode / Mechanism of ACF which is identified Conductive ball Corrsion, Delamination, Crack and Polymer Expansion / Swelling. In ALT(Accelerated Life Test), we select primary stress factors as temperature and humidity. As time passes by, an increase of connection resistance was observed. In conclusion, we have found that high temperature / humidity affects the adhesion.

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黃의 親核性 置換反應(제10보). 鹽化페닐메탄술포닐의 加溶媒分解反應 (Nucleophilic Displacement at Sulfur Center (X). Solvolysis of Phenylmethanesulfonyl Chloride)

  • 이익춘;김왕기
    • 대한화학회지
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    • 제22권3호
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    • pp.111-116
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    • 1978
  • 메탄올-물, 에탄올-물, 아세톤-물 및 아세토니트릴-물의 二成分 混合溶媒에서 鹽化페닐메탄술포닐의 加溶媒分解反應을 速度論的으로硏究하였다. 反應速度는 反陽性子溶媒에서 보다 陽性子溶媒에서 더 빨랐으며, 이온化能力에 對한 反應速度의 感度 즉 Winstein 圖示의 m와 轉移狀態의 溶媒和數는 陽性子溶媒에서 훨씬 작았다. 이것은 陽性子溶媒의 水素結合溶媒和에 依한 初期狀態의 安定化로서 생각할 수 있다. 反應은 모든 溶媒系에 있어서 轉移狀態의 結合形成이 結合破壤을 앞지르는$S_N2$ 메카니즘으로 일어난다 할 수 있다.

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