• 대한토목학회논문집
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• 제28권4A호
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• pp.439-445
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• 2008

본 논문에서는 비부착 CFRP판으로 긴장 보강된 철근콘크리트 보를 해석하기 위한 수정된 부착감소계수를 제안하였다. 기존의 비부착 강연선의 극한응력 해석식에 대한 분석을 통해 비부착 CFRP판 긴장재로 보강된 철근콘크리트 보에 대한 적용성을 검토하였으며, 적용상의 문제점을 도출하였다. 합리적인 비부착 CFRP판 극한응력 해석식을 제안하기 위해 부착 CFRP판 긴장재의 평균변형률 개념으로부터 비부착 CFRP판 긴장재의 보강길이와 하중 재하 형태에 따른 순수휨구간 길이가 고려된 확장된 부착감소계수를 제안하였다. 최종 부착감소계수는 기존의 비부착 CFRP판 긴장 보강보에 대한 실험연구 문헌의 실험결과를 이용한 통계적 방법으로 결정되었으며, 제안된 부착감소계수를 포함한 극한응력 해석식에 의해 계산된 값을 실험결과와 비교하여 제안식의 유효성을 검토하였다.

• 약학회지
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• 제50권1호
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• pp.40-46
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• 2006

Square wave voltammetric (SWV) and cyclic voltammetric (CV) behaviors of cefotaxime sodium and ceftriaxone sodium have been investigated in the potential range between -0.10 V and -1.30 V using the phosphate buffers of various pH values ($2.00{\sim}9.10$). Two main peaks observed were irreversible and protons were involved in their electrochemical reductions. The first peaks of these cephalosporin antibiotics are due to the reduction of the azomethine double bond in the methoxyimino group of the side chain at position 7. The second peaks of cefotaxime sodium and ceftriaxone sodium are related to the reductions of the ${\Delta}^3$ double bond and the dioxo moiety of the side chain at position 3, respectively. The calibration curve of cefotaxime sodium in the concentration range between $1.0{\times}10^{-7}M$ and $1.0{\times}10^{-5}M$ yielded the linearity with the correlation coefficient of 0.9998 when the first peak of the antibiotic in a phosphate buffer of pH 3.02 was measured at the conditions of frequency of 120 Hz and pulse height of 50 mV by SWV. The present fast, simple and accurate SWV assay method was applied to determine cefotaxime sodium in the commercial antibiotic powder of injection.

• 한국건설순환자원학회논문집
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• 제3권1호
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• pp.84-89
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• 2015

현무암섬유는 높은 인장강도와 콘크리트와 유사한 밀도를 갖기 때문에 콘크리트 보강 섬유로서 장점을 갖고 있다. 이 연구에서는 현무암섬유의 부착 특성과 섬유 배향각에 따른 현무암섬유의 인장 강도 특성을 조사하였다. 이를 위하여 현무암섬유와 폴리비닐알코올섬유에 대한 섬유 인발 실험을 수행하였고, 현무암, 폴리비닐알코올, 폴리에틸렌섬유에 대하여 섬유 배향각에 따른 인장 강도를 측정하였다. 실험 결과 현무암섬유의 화학적 부착, 마찰 부착, 미끌림 경화 계수는 폴리비닐알코올섬유와 비교하여 각각 1.88, 1.03, 0.24배로 나타났다. 현무암섬유의 배향각에 따른 강도 감소 계수는 폴리비닐알코올섬유의 9배, 폴리에틸렌섬유의 3배로 나타났다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.398-398
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• 2013

The electronic properties and the local structure of tantalum oxide thin film with variation of oxygen flow rate ranging from 9.5 to 16 sccm (standard cubic centimeters per minute) have been investigated by X-ray photoelectron spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and X-ray absorption spectroscopy (XAS). The XPS results show that the Ta4f spectrum for all films consist of the strong spin-orbit doublet $Ta4f_{7/2}$ and $Ta4f_{5/2}$ with splitting of 1.9 eV. The oxygen flow rate of the film results in the appearance of new features in the Ta4f at binding energies of 23.2 eV, 24.4 eV, 25.8, and 27.3 eV, these peaks attribute to $Ta^{1+}$, $Ta^{2+}$, $Ta^{4+}$/$Ta^{2+}$, and $Ta^{5+}$, respectively. Thus, the presence of non-stoichiometric state from tantalum oxide ($TaO_x$) thin films could be generated by the oxygen vacancies. The REELS spectra suggest the decrease of band gap for tantalum oxide thin films with increasing the oxygen flow rate. The absorption coefficient ${\mu}$ and its fine structure were extracted from the fluorescence mode of extended X-ray absorption fine structure (EXAFS) spectra. In addition, bond distances (r), coordination numbers (N) and Debye-Waller factors (${\sigma}^2$) each film were determined by a detailed of EXAFS data analysis. EXAFS spectrapresent both the increase of coordination number of the first Ta-O shell and a considerable reduction of the Ta-O bond distance with the increase of oxygen flow rate.

• Computers and Concrete
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• 제15권1호
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• pp.55-71
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• 2015

This paper presents a novel harmony search (HS)-based data-driven single input rule modules (SIRMs)-connected fuzzy inference system (FIS) for the prediction of stress in externally prestressed tendon. The proposed method attempts to extract causal relationship of a system from an input-output pairs of data even without knowing the complete physical knowledge of the system. The monotonicity property is then exploited as an additional qualitative information to obtain a meaningful SIRMs-connected FIS model. This method is then validated using results from test data of the literature. Several parameters, such as initial tendon depth to beam ratio; deviators spacing to the initial tendon depth ratio; and distance of a concentrated load from the nearest support to the effective beam span are considered. A computer simulation for estimating the stress increase in externally prestressed tendon, ${\Delta}f_{ps}$, is then reported. The contributions of this paper is two folds; (i) it contributes towards a new monotonicity-preserving data-driven FIS model in fuzzy modeling and (ii) it provides a novel solution for estimating the ${\Delta}f_{ps}$ even without a complete physical knowledge of unbonded tendons.