• Title/Summary/Keyword: bond reduction coefficient

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The Analysis for Reinforced Concrete Beams Strengthened with Externally Unbonded Prestressed CFRP Plates (비부착 탄소섬유판 긴장재로 외부 긴장 보강된 철근콘크리트 보의 해석)

  • Park, Jong Sup;Jung, Woo Tai;Park, Young Hwan;Kim, Chul Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.4A
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    • pp.439-445
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    • 2008
  • This paper suggests a modified bond reduction coefficient considering the average CFRP (Carbon Fiber Reinforced Polymer) strain concept for the unbonded prestressed CFRP plate strengthening system. The strengthened length and the pure bending length were seen to influence the variation of the strain of unbonded CFRP plate. Therefore, a new bond reduction coefficient considering such effect was suggested. Comparison with the experimental data revealed that the analytic results obtained by considering the proposed bond reduction coefficient were effective in estimating the strain of the unbonded CFRP plate in the CFRP plate prestressing system.

Electrochemical Behaviors and Square Wave Voltammetric Determinations of Cefotaxime Sodium and Ceftriaxone Sodium (세포탁심나트륨과 세프트리악손나트륨의 전기화학 거동 및 네모파 전압전류법 정량)

  • Kim, Min-Kyung;Hahn, Young-Hee
    • YAKHAK HOEJI
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    • v.50 no.1
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    • pp.40-46
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    • 2006
  • Square wave voltammetric (SWV) and cyclic voltammetric (CV) behaviors of cefotaxime sodium and ceftriaxone sodium have been investigated in the potential range between -0.10 V and -1.30 V using the phosphate buffers of various pH values ($2.00{\sim}9.10$). Two main peaks observed were irreversible and protons were involved in their electrochemical reductions. The first peaks of these cephalosporin antibiotics are due to the reduction of the azomethine double bond in the methoxyimino group of the side chain at position 7. The second peaks of cefotaxime sodium and ceftriaxone sodium are related to the reductions of the ${\Delta}^3$ double bond and the dioxo moiety of the side chain at position 3, respectively. The calibration curve of cefotaxime sodium in the concentration range between $1.0{\times}10^{-7}M$ and $1.0{\times}10^{-5}M$ yielded the linearity with the correlation coefficient of 0.9998 when the first peak of the antibiotic in a phosphate buffer of pH 3.02 was measured at the conditions of frequency of 120 Hz and pulse height of 50 mV by SWV. The present fast, simple and accurate SWV assay method was applied to determine cefotaxime sodium in the commercial antibiotic powder of injection.

Engineering Property of Basalt Fiber as a Reinforcing Fiber (보강 섬유로서 현무암 섬유의 공학적 특성)

  • Choi, Jeong-Il;Jang, Yu-Hyun;Lee, Jae-Won;Lee, Bang-Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.1
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    • pp.84-89
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    • 2015
  • Basalt fiber has many advantages as a reinforcing fiber such as high tensile strength and similar density to concrete. This study investigated the bonding property and the effect of fiber orientation on tensile strength of basalt fiber. Single fiber pullout tests for basalt and polyvinyl alcohol (PVA) fibers were performed to evaluate the bonding property between basalt fiber and mortar. And then tensile strength of basalt, PVA, and polyethylene (PE) fibers according to fiber orientation were measured. From the test results, it was exhibited that the chemical bond, frictional bond, and slip-hardening coefficient of basalt fiber were 1.88, 1.03, 0.24 times of PVA fibers, respectively. And the strength reduction coefficient of basalt fiber was 9 times of PVA fiber and 3 times of PE fiber.

The Effect of the Oxygen Flow Rate on the Electronic Properties and the Local Structure of Amorphous Tantalum Oxide Thin Films

  • Denny, Yus Rama;Lee, Sunyoung;Lee, Kangil;Kang, Hee Jae;Yang, Dong-Seok;Heo, Sung;Chung, Jae Gwan;Lee, Jae Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.398-398
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    • 2013
  • The electronic properties and the local structure of tantalum oxide thin film with variation of oxygen flow rate ranging from 9.5 to 16 sccm (standard cubic centimeters per minute) have been investigated by X-ray photoelectron spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and X-ray absorption spectroscopy (XAS). The XPS results show that the Ta4f spectrum for all films consist of the strong spin-orbit doublet $Ta4f_{7/2}$ and $Ta4f_{5/2}$ with splitting of 1.9 eV. The oxygen flow rate of the film results in the appearance of new features in the Ta4f at binding energies of 23.2 eV, 24.4 eV, 25.8, and 27.3 eV, these peaks attribute to $Ta^{1+}$, $Ta^{2+}$, $Ta^{4+}$/$Ta^{2+}$, and $Ta^{5+}$, respectively. Thus, the presence of non-stoichiometric state from tantalum oxide ($TaO_x$) thin films could be generated by the oxygen vacancies. The REELS spectra suggest the decrease of band gap for tantalum oxide thin films with increasing the oxygen flow rate. The absorption coefficient ${\mu}$ and its fine structure were extracted from the fluorescence mode of extended X-ray absorption fine structure (EXAFS) spectra. In addition, bond distances (r), coordination numbers (N) and Debye-Waller factors (${\sigma}^2$) each film were determined by a detailed of EXAFS data analysis. EXAFS spectrapresent both the increase of coordination number of the first Ta-O shell and a considerable reduction of the Ta-O bond distance with the increase of oxygen flow rate.

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Data-driven SIRMs-connected FIS for prediction of external tendon stress

  • Lau, See Hung;Ng, Chee Khoon;Tay, Kai Meng
    • Computers and Concrete
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    • v.15 no.1
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    • pp.55-71
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    • 2015
  • This paper presents a novel harmony search (HS)-based data-driven single input rule modules (SIRMs)-connected fuzzy inference system (FIS) for the prediction of stress in externally prestressed tendon. The proposed method attempts to extract causal relationship of a system from an input-output pairs of data even without knowing the complete physical knowledge of the system. The monotonicity property is then exploited as an additional qualitative information to obtain a meaningful SIRMs-connected FIS model. This method is then validated using results from test data of the literature. Several parameters, such as initial tendon depth to beam ratio; deviators spacing to the initial tendon depth ratio; and distance of a concentrated load from the nearest support to the effective beam span are considered. A computer simulation for estimating the stress increase in externally prestressed tendon, ${\Delta}f_{ps}$, is then reported. The contributions of this paper is two folds; (i) it contributes towards a new monotonicity-preserving data-driven FIS model in fuzzy modeling and (ii) it provides a novel solution for estimating the ${\Delta}f_{ps}$ even without a complete physical knowledge of unbonded tendons.