• Advances in concrete construction
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• v.10 no.2
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• pp.113-125
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• 2020

This paper presents experimental results on bond-slip behavior of steel reinforced high-strength concrete (SRHC) after exposure to elevated temperatures. Three parameters were considered in this test: (a) high temperatures (i.e., 20℃, 200℃, 400℃, 600℃, 800℃); (b) concrete strength (i.e., C60, C70, C80); (c) anchorage length (i.e., 250 mm, 400 mm). A total of 17 SRHC specimens subjected to high temperatures were designed for push out test. The load-slip curves at the loading end and free end were obtained, the influence of various variation parameters on the ultimate bond strength and residual bond strength was analyzed, in addition, the influence of elevated temperatures on the invalidation mechanism was researched in details. Test results show that the shapes of load-slip curves at loading ends and free ends are similar. The ultimate bond strength and residual bond strength of SRHC decrease first and then recover partly with the temperature increasing. The bond strength is proportional to the concrete strength, and the bond strength is proportional to the anchoring length when the temperature is low, while the opposite situation occurs when the temperature is high. What's more, the bond damage of specimens with lower temperature develops earlier and faster than the specimens with higher temperature. From these experimental findings, the bond-slip constitutive formula of SRHC subjected to elevated temperatures is proposed, which fills well with test data.

• Journal of the Korean Chemical Society
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• v.62 no.5
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• pp.412-416
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• 2018

• Particle and aerosol research
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• v.8 no.2
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• pp.75-81
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• 2012

The strength of lumped cokes can be represented by some index numbers. Although some indexes are suggested, these indexes are not enough to enlighten fracture mechanism. To find essential mechanism, a computational way, discrete element method, is applied to the uniaxial compression test for cylindrical specimen. The cylindrical specimen is a kind of lumped particle mass with parallel bonding that will be broken when the normal stress and shear stress is over a critical value. It is revealed that the primary factors for cokes fracture are parallel spring constant, parallel bond strength, bonding radius and packing ratio the parallel bond strength and radius of the parallel combination the packing density. Especially, parallel spring constant is directly related with elastic constant and yield strength.

• KCI Concrete Journal
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• v.13 no.2
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• pp.67-74
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• 2001

In this study, a numerical model for the simulation of reinforced concrete columns subject to cyclic loading is presented. The model consists of three separate models representing concrete, reinforcing steel bars and bond-slip between a reinforcing bar and ambient concrete. The concrete model is represented by the plane stress plastic-damage model and quadrilateral finite elements. The nonlinear steel bar model embedded in truss elements is used for longitudinal and transverse reinforcing bars. Bond-slip mechanism between a reinforcing bar and ambient concrete is discretized using connection elements in which the hysteretic bond-slip link model defines the bond stress and slip displacement relation. The three models are connected in finite element mesh to represent a reinforced concrete structure. From the numerical simulation, it is shown that the proposed model effectively and realistically represents the overall cyclic behavior of a reinforced concrete column. The present plastic-damage concrete model is observed to work appropriately with the steel bar and bond-slip link models in representing the complicated localization behavior.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.1019-1024
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• 2000

Carbon fiber sheet has been widely used for the strengthening of the concrete buildings structures due to its excellent physical properties such as high strength, lightness and high durability. Bond strength or behavior, on the other, hands, between carbon fiber sheet and concrete is very important in strengthening the concrete member using CFS. Also the bond failure mechanism between CFS and concrete should be fully verified and understood. This study is to investigate the bond strength of CFS to th concrete by the direct pull-out test and the tensile-shear test methods. From the tests, the average bond stress, $$\tau$_{y}$ and the effective bond length, $$\ell$_{ｕ}$ are acquired.

• Steel and Composite Structures
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• v.11 no.3
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• pp.233-250
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• 2011

An experimental study has been carried out to reveal the shear-bond failure mechanism of composite deck slabs. Thirteen full scale simply supported composite slabs are studied experimentally, with the influence parameters like span length, slab depth, shear span length and end anchorage provided by steel headed studs. A dozen of strain gauges and LVDTs are monitored to capture the strain distribution and variation of the composite slabs. Before the onset of shear-bond slip, the longitudinal shear forces along the span are deduced and found to be proportional to the vertical shear force in terms of the shear-bond strength in the m-k method. The test results are appraised using the current design procedures. Based on the partial shear-bond connection at the ultimate state, an improved method is proposed by introducing two reduction factors to assess the moment resistance of a composite deck slab. The new method has been validated and the results predicted by the revised method agree well with the test results.

• Structural Engineering and Mechanics
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• v.76 no.1
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• pp.67-81
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• 2020

Pretensioned concrete (PC) is widely used in contemporary construction. Bond of prestressing strand is significant for composite-action between the strand and concrete in the transfer and flexural-bond zones of PC members. This study develops a new methodology for quantifying the bond of 18-mm prestressing strand in PC members based on results of a pullout test, the Standard Test for Strand Bond (STSB). The experimental program includes: (a) twenty-four pretensioned concrete beams, using a wide range of concrete compressive strength; and (b) twelve untensioned pullout specimens. By testing beams, the transfer length, flexural-bond length, and development length were all measured. In the STSB, the pullout forces for the strands were measured. Experimental results indicate a significant relationship between the bond of prestressing strand to the code-established design parameters, such as transfer length and development length. However, the code-predictions can be unconservative for the prestressing strands having a low STSB pullout force. Three simplified bond equations are proposed for the design applications of PC members.

• Bulletin of the Korean Chemical Society
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• v.23 no.1
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• pp.103-106
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• 2002

A new reaction mechanism is proposed for the reaction of thianthrene cation radical perchlorate $(Th^{+{\cdot}}CIO_4^-}$ and tert-butyl peroxide in acetonitrile at room temperature on the basis of experimental and theoretical results. Rapid C-O bond rupture instead of O-O bond cleavage was observed by a good peroxy radical trapping agent, thianthrene cation radical. Products were N-tert-butyl acetamide, thianthrene 5-oxide (ThO), thianthrene 5,5-dioxide $(SSO_2)$, and thianthrene (Th). Thianthrene 5,10-dioxide (SOSO) was not obtained. A comparative computational study of the cation radical of tert-butyl peroxide is made by using B3LYP and CBS-4. The computational results are helpful to explain the reaction mechanism.

• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3218-3222
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• 2013

The aminolyses, anilinolysis and pyridinolysis, of bis(2-oxo-3-oxazolidinyl) phosphinic chloride (1) have been kinetically investigated in acetonitrile at 55.0 and $35.0^{\circ}C$, respectively. For the reactions of 1 with substituted anilines and deuterated anilines, a concerted SN2 mechanism is proposed based on the selectivity parameters and activation parameters. The deuterium kinetic isotope effects ($k_H/k_D$) invariably increase from secondary inverse to primary normal as the aniline becomes more basic, rationalized by the transition state variation from a backside to a frontside attack. For the pyridinolysis of 1, the authors propose a stepwise mechanism with a rate-limiting step change from bond breaking for more basic pyridines to bond formation for less basic pyridines based on the selectivity parameters and activation parameters. Biphasic concave upward free energy relationship with X is ascribed to a change in the attacking direction of the nucleophile from a frontside attack with more basic pyridines to a backside attack with less basic pyridines.

• Journal of the Korean Chemical Society
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• v.63 no.4
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• pp.233-236
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• 2019

In this study, the solvolysis of cyclohexanesulfonyl chloride (1) was studied by kinetics in ethanol-water, methanol-water, acetone-water, and 2,2,2-trifluoroethanol (TFE)-water binary solvent systems. The rate constants were applied to the extended Grunwald-Winstein equation, to obtain the values of m = 0.41 and l = 0.81. These values suggested $S_N2$ mechanism in which bond formation is more important than bond breaking in the transition state (TS). Relatively small activation enthalpy values (11.6 to $14.8kcal{\cdot}mol^{-1}$), the large negative activation entropy values (-29.7 to $-38.7cal{\cdot}mol^{-1}{\cdot}K^{-1}$) and the solvent kinetic isotope effects (SKIE, 2.29, 2.30), the solvolyses of the cyclohexanesulfonyl chloride (1) proceeds via the $S_N2$ mechanism.