• 한국지진공학회논문집
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• 제10권3호
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• pp.113-123
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• 2006

콘크리트 부재의 내진설계에 있어 강도와 더불어 변형 능력은 중요한 요소이다. 연결보는 전단 지배 부재임에도 항복 이후 소성 변형을 요구하는 부재인데 본 연구에서는 연결보의 변형 능력에 대한 실험을 통해 변형 모형을 제시하였다. 일반적인 배근 형태를 가진 철근 콘크리트 연결보를 대상으로 단조하중실험을 수행하였다. 경간-깊이비, 휨 철근비, 전단 철근비를 변수로 하여 연결보의 거동을 평가하였다. 전단 지배 부재인 연결보는 아치작용과 트러스 작용으로 전단력에 대해 저항하는데 실험 결과를 통해 전단력을 두 작용의 구분과 항복 강도 발현 이후 소성 변형에 따른 두 작용의 구성비 변화에 대해 분석하였다. 실험결과에 기초한 전단 철근과 휨 철근의 변형률 분포 모형을 이용하여 휨 철근의 응력 상태를 산정하였다. 휨 철근의 부착-미끄러짐에 의해 결정되는 균열폭을 고려하는 연결보의 변형 모형을 제시하였다. 항복 상태는 휨 철근의 항복 시점으로 정의하였고, 극한 상태는 변형 증가에 따른 스트럿의 압축 강도 저하에 의해 결정되었다. 이 변형 모형은 변위기초설계에 활용될 수 있을 것으로 기대된다.

• Journal of Mechanical Science and Technology
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• 제16권7호
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• pp.911-918
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• 2002

The tribological performance of A1$_2$O$_3$/NiCr coating deposited on steel (SH45C) was investigated under lubrication. The parameters of sliding wear consist of normal load and coating thickness. Test result showed that there was no evidence of an improved bonding strength in the coating. However, the wear resistance of the A1$_2$O$_3$/NiCr coaling was significantly greater than that of the Al$_2$O$_3$ coating. It was eviclent that the residual stress for the A1$_2$O$_3$coating was higher than that of the A1$_2$O$_3$/NiCr coating from the Scratch test failure of coating. The bond coating played an important role in decreasing the residual stress. Also, it was found that the residual stress had d notable influence on the wear mechanism.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.5-8
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• 2002

The use of the co-cured joining method for composite structures is attractive due to several benefits. However, since the design stress level in cyclic loads is often smaller than the joint strength obtained from the static tensile load test, it is important to establish proper fatigue design criteria. Although some researchers have reported on co-cured joints, there are only a few papers published on the fatigue characteristics of co-cured joints. In this paper, the effect of bond parameters on the fatigue characteristics of a steel-composite co-cured double lap joint under cyclic tensile loads was experimentally investigated. We considered the surface roughness of the steel adherend and the stacking sequence of the composite adherend as bond parameters. A fatigue failure mechanism of the co-cured double lap joint was explained systematically by investigating the surfaces of failed specimens.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.65-69
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• 2002

An Al film deposited on the Kovar alloy substrate was anodically-bonded to the borosilicate glass, and the bond interfaces was closely investigated by transmission electron microscopy. Al oxide was found to form a layer ~l0 nm thick at the bond interface, and fibrous structure of the same oxide was found to grow epitaxially in the glass from the oxide layer. The fibrous structure grew with the bonding time. The mechanism of the formation of this fibrous structure is proposed on the basis of the migration of Al ions under the electric field. Penetration of Al into glass beyond the interfacial Al oxide was not detected. The comparison of the amount of excess oxygen ions generated in the alkali depletion layer with that incorporated in the Al oxide suggests that the growth of the alkali-ion depletion layer is controlled by the consumption of excess oxygen to form the interfacial Al oxide.

• 대한치과교정학회지
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• 제19권2호
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• pp.155-163
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• 1989

Indirect bonding is done by placing the brackets on a model in the laboratory and using a template or tray to transfer the laboratory positioning to the teeth. The advantages of this technique are 1. decreased chair time 2. less patient discomfort 3. accuracy of a attachment placement 4. good adaptation of attachment to tooth contour 5. occlusal relationship of brackets and opposing teeth can be checked The disadvantages of the technique are 1. complex laboratory procedure 2. sometimes difficult on very short clinical crowns 3. teeth with crowns, large buccal restoration will not bond 4. may not be fitted close, if poor adaptation 5. likely to be disturbed setting Several indirect bonding techniques have proved reliable in clinical practice. However, they differ in the way the brackets are attached temporarily to the model, the type of transfer tray or other mechanism used, the adhesive or sealant employed, whether segmented or full bonding used, and the way the transfer is removed so as not to exert excessive force on a still maturing bond.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3591-3596
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• 2013

The enantioselective aza-Morita Baylis Hillman reaction of nitroalkene and N-tosylimine catalyzed by thiourea-tertiary amine has been investigated using density functional theory. Enantioselectivity is dominated by the cooperative effect of non-covalent and weak covalent interactions imposed by different units of catalyst. As Lewis base, the tertiary amine unit activates nitroalkene via weak covalent bond. The weak covalent interaction orients the reaction in a major path with smaller variations of this bond. The aromatic ring unit activates N-tosylimine via ${\pi}-{\pi}$ stacking. The non-covalent interaction selects the major path with smaller changes of the efficient packing areas. Thiourea unit donates more compact H-bonded network for species of the major path. The calculated ee value in xylene solution phase (97.6%) is much higher than that in N,N-Dimethylformamide (27.2%). Our conclusion is also supported by NBO analysis.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.543-546
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• 1999

The purpose of the present study is to identify the damage characteristics of concrete structures due to cracking by employing the acoustic emission techniques. A comprehensive experimental study has been done. The cracking damages under tensile and flexural loadings have been identified and the bond damage between steel and concrete have been also characterized. It is seen that the amplitudes and energy level of AE events is found to be smaller for bond cracking damages and larger for tensile cracking damages. The characteristic equations of the AE events for various cracking damages have been proposed based on the present test data. The internal microcracks are progressively developed ahead of a visible actual crack and the present study clearly exhibits thses damage mechanism for various types of cracking in concrete. The present study provides very useful data which can be used to identify the various types of cracking damages in concrete structures. This will allow very efficient maintenance of concrete structures through monitoring of internal cracking based on acoustic emission.

• 대한기계학회논문집A
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• 제23권7호
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• pp.1245-1252
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• 1999

The sliding wear behavior of $Al_2O_3/NiCr$ coating deposited on steel(SM45C) was investigated under lubrication. The parameters of sliding wear are normal loads, coating thickness. As a result, the wear resistance of $Al_2O_3/NiCr$ coating was remarkably greater than that of $Al_2O_3$ coating. The optimized coating thickness was found to be $300{\mu}m$ to ensure good anti-wear. The bond coating played important role in decreasing residual stress. The residual stress had much influence on wear mechanism. These results were correlated with the stress state of coating and the microstructure of coating.

• 대한화학회지
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• 제14권2호
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• pp.161-168
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• 1970

In order to obtain the more effective evidence, supporting the hypothesis which have been previously described by former report that pepsin (EC 3.4. 4.1) forms a hydrophobic bond with the nonpolar side chain of its substrate, the inhibitory effect of carboxylic acids(from formic acid to iso-butyric acid) on the activity of pepsin to the synthetic dipeptide, N-Carbobenzoxy-L-glutamyl-L-tyrosine, was discussed. The kinetic study showed that the inhibition by carboxylic acids was competitive. The Kidecreased with increasing size of the inhibitor molecule. The $-{\Delta}F^{\circ}$increased linearly with increasing number of carbon atoms in the hydrocarbon chain of the inhibitor. It was confirmed that the hydrophobic bond between more than one side chain of amino acid residues(phenylalanine) in the binding region of the active center of pepsin and the side chain of amino acid residues in the substrate was formed as the first step of its enzymic mechanism. The inhibitory effect of carboxylic acids was due to the competition of the hydrocarbon group of the carboxylic acids with the side chain of the substrate for the hydrophobic binding site(the side chain of phenylalanine) of the pepsin.

• 대한화학회지
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• 제22권3호
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• pp.111-116
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• 1978

메탄올-물, 에탄올-물, 아세톤-물 및 아세토니트릴-물의 二成分 混合溶媒에서 鹽化페닐메탄술포닐의 加溶媒分解反應을 速度論的으로硏究하였다. 反應速度는 反陽性子溶媒에서 보다 陽性子溶媒에서 더 빨랐으며, 이온化能力에 對한 反應速度의 感度 즉 Winstein 圖示의 m와 轉移狀態의 溶媒和數는 陽性子溶媒에서 훨씬 작았다. 이것은 陽性子溶媒의 水素結合溶媒和에 依한 初期狀態의 安定化로서 생각할 수 있다. 反應은 모든 溶媒系에 있어서 轉移狀態의 結合形成이 結合破壤을 앞지르는$S_N2$ 메카니즘으로 일어난다 할 수 있다.