• Title/Summary/Keyword: bond characteristics

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Durability Characteristics of Concrete with Nano Level Ceramic Based Coating (나노합성 세라믹계 도장재를 도포한 콘크리트의 내구성능)

  • Kim, Seong-Soo;Lee, Jeong-Bae;Han, Seung-Woo
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.639-646
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    • 2007
  • This study performed several tests for the durability of the concrete coated with nano synthesis ceramics which do not contain volatile organic compounds harmful to environment. The tests were adhesion test on dry and humid concrete, SEM test, MIP analysis, carbonation, chloride diffusion by electronic facilitation, freezing-thawing resistance, alkaline resistance, and brine resistance test. In the adhesion test on dry and humid concrete, nano synthesis ceramics coating produced the highest results among all the coatings tested. Nano synthesis ceramics adhered solidly on the concrete surface. The adhesive strength seemed to result from the hydrogen bond between nano synthesis ceramics which are inorganic and generated by hydrolysis and re-condensation reaction and the concrete's hydrates such as calcium silicate aluminate or calcium silicate hydrate. SEM test and MIP analysis results show surface structure with finest crevices pore in the nano synthesis ceramics coating applied concretes. In the carbonation, chloride diffusion, and freezing-thawing resistance tests, the concretes with nano synthesis ceramics coating indicated the best results. Based on these test results, further progress in application of nano synthesis ceramics coatings to various concrete structures including costal structures and sewerage arrangements can be expected.

A Study on Heat Transfer Characteristics according to Thermal Hydrolysis Reaction of Poultry Slaughter Waste (도계폐기물의 열가수분해 반응에 따른 열전달 특성 연구)

  • Song, Hyoung Woon;Jung, Hee Suk;Kim, Choong Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.95-103
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    • 2015
  • The purpose of this study was performed to quantitatively measure the thermal conductivity of poultry slaughter waste with variation of reaction temperature for optimal design of thermal hydrolysis reactor. We continuously quantified the thermal conductivity of dehydrated sludge related to the reaction temperature. As the reaction temperature increased, the dehydrated sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. Therefore, the bond water in the sludge cells comes out as free water, which changes the dehydrated sludge from a solid phase to slurry of a liquid phase. As a result, the thermal conductivity of the its sludge was more than 2.11 times lower than that of the water at $20^{\circ}C$. However, the thermal conductivity of the sludge approached to $0.677W/m{\cdot}^{\circ}C$ of water at $200^{\circ}C$, experimentally substantiating liquefaction of the dehydrated sludge. Therefore, we confirmed that the change in physical properties due to thermal hydrolysis appears to be an important factor for heat transfer efficiency. And the thermal conductivity function related to reaction temperature was derived to give the boundary condition for the optimal design of the thermal hydrolysis reactor. The consistency of the calculated function was 99.69%.

Characteristics of Low Dielectric Constant SiOF Thin Films with Post Plasma Treatment Time (플라즈마 후처리 시간에 따른 저유전율 SiOF 박막의 특성)

  • Lee, Seok Hyeong;Park, Jong Wan
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.267-267
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    • 1998
  • The fluorine doped silicon oxide (SiOF) intermetal dielectric (IMD) films have been of interest due to their lower dielectric constant and compatibility with existing process tools. However instability issues related to bond and increasing dielectric constant to water absorption when the SiOF films was exposured to atmospheric ambient. Therefore, the purpose of this research is to study the effect of post oxygen plasma treatment on the resistance of moisture absorption and reliability of SiOF film. Improvement of moisture absorption resistance of SiOF film is due to the forming of thin SiO₂layer at the SiOF film surface. It is thought that the main effect of the improvement of moisture absorption resistance was densification of the top layer and reduction in the number of Si-F bonds that tend to associate with OH bonds. However, the dielectric constant was increased when plasma treatment time is above 5 min. In this study, therefore, it is thought that the proper plasma treatment time is 3 min when plasma treatment condition is 700 W of microwave power, 3 mTorr of process pressure and 300℃ of substrate temperature.

Determinants of dividend payout: Advance disclosure and ordinary disclosure (결산배당 사전공시기업과 사후공시기업의 배당 결정요인 비교 분석)

  • Khil, Jaeuk;Han, Sangjeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.86-93
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    • 2018
  • This study examines the differences in the determinants of dividend payout across advance disclosure firms and ordinary disclosure firms using firm-level data from firms listed on the Korea Exchange. Results are as follows: First, firm characteristics of advance disclosure firms significantly differ from those of ordinary disclosure firms in all variables except sales growth and operating risk variables. Second, regression results show that the determinants of dividend payout from ordinary disclosure firms are generally similar to results of previous studies. However, determinants of advance disclosure firms contain only few variables such as Tobin's Q, corporate bond yield, and operating cash flows from conventional factors. Third, logistic regression results show that factors affecting the probability of dividend payment substantially differ across advance disclosure firms and ordinary disclosure firms. These results suggest that the motivation and incentive of dividend payout from firms choosing advance disclosure are substantially and systematically different from those of ordinary disclosure firms.

A Study on PCP Adsorption in Various Paddy Soils of the Choongbook Area (충북지방(忠北地方) 답토양(沓土壤)에 대(對)한 PCP 흡착에 관한 연구(硏究))

  • Ok, Hwan-Suk;Lee, Jae-Koo
    • Applied Biological Chemistry
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    • v.15 no.3
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    • pp.229-240
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    • 1972
  • Not only in order to determine reasonable application amounts of PCP in terms of soil texture, but also to get basic data for fish-toxicity-free treatment by estimating fish toxicity, some aspects of PCP adsorption were observed taking various paddy soils with different physico-chemical characteristics in the Choongbook Area as samples. The results obtained are summarized as follows: 1. There was a positive correlation between PCP adsorption and clay contents, total nitrogen, organic matter, cation exchange capacity, exchangeable bases, and phosphorus absorption coefficients, respectively; whereas there was a negative one between PCP adsorption and pH. Although they were not significant, it was remarkable that there was a relatively large amount of correlation between PCP adsorption and clay contents, $H^+,\;Mg^{++}$, and CEC, respectively. 2. PCP adsorption in terms of soil texture was in the order of Clay>Loam>Sandy loam. 3. Although PCP adsorption in the $H_2O_2-treated$ soils decreased remarkably, it was not proportional to the humus contents. 4. The order of PCP adsorption in the exchangeable base-treated soils was H^+-exchanged soil>$K^+-soil$>$Na^+-soil$>$Ca^{++}-soil$>Mg^{++}-soil. 5. Langmuir's and Freundlich's adsorption isotherms were applicable to the PCP adsorption, and thereby were able to be calculated maximum adsortion amounts of PCP, bond energy, and the depths of adsorption layers. 6. Maximum adsorbed amounts of PCP were 212.14 mg/100gr in Clayey loam, 97.28 to 121.59mg/100gr in Loam, and 32.92 to 91.74mg/100gr in Sandy loam, respectively. 7. The depths of mixed layers of limiting application for fish-toxicity-free treatment were 0.88cm of the Jinchun soil, the shallowest and 4.29 cm of the Naesan-ri Sandy loam, the deepest.

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Studies on Glycolipids in Bacteria -Part I Occurrence of Glycolipids in Various Bacteria- (세균(細菌)의 당지질(糖脂質)에 관(關)한 연구(硏究) -제1보(第一報) 세균(細菌)에 있어서의 당지질(糖脂質)의 분포(分布)-)

  • Kim, Kyo-Chang
    • Applied Biological Chemistry
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    • v.17 no.2
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    • pp.117-124
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    • 1974
  • The 23 representative bacteria were studied for the glucosamine contents which represent the glycolipid content of the cell wall. The distribution of glycolipid in various bacteria was examined and the relationship between the glycolipid contents and the Gram stain was elucidated. The results were as follows: 1. The contents of glucosamine in the glycolipid of Gram negative and variable bacterial cell wall were large ranging from the least 0.04 ${\mu}g$ of Proteus vulgaris to the largest 2.48 ${\mu}g$ of Aerobacter aerogenes. The Gram positive bacteria and only those Gram positive among Bacilli contained less than 0.02 ${\mu}g$ of glucosamine contents. The least glucosamine containing Gram positive bacteria were Corynebacterium sepedonicum and Staphylococcus aureus. It could generally be said that the Gram negative and variable bacteria contain the higher content of glucosamine in the cell wall than the positives. 2. The bacteria were better stained by the Gram solution after the extraction of glycolipid from the cell wall than those without extraction. 3. The four infrared spectra of glycolipids obtained from Aerobacter aerogenes, Bacillus circulans, Pseudomonas fluorescens, and Salmonella typhirurium showed all the similar characteristics. All showed the existence of groups; OH, C-O, C-O-C, $CH_2+CH_3$, amide band, fatty acid ester band and ester carbonyl bond.

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Study on Poverty of the Middle Aged Men Living in Chokbang Area (쪽방거주 중고령 남성의 빈곤 사례연구)

  • Kim, Dong-Seon;Mo, Seon-Hee
    • The Journal of the Korea Contents Association
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    • v.20 no.5
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    • pp.222-235
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    • 2020
  • This study examines the poverty progress and its factors which drove the lives of the middle-aged men in Chokbang area. The observed examples are the retired government officials and the self-employed who have been classified as the ones in the economically-middle class but currently as the welfare recipients. According to the results of in-depth interview and observation, the poverty of the observed has undergone the progress of trigger, worsening, breakup, desperation and stabilizing stages. The poverty factors found in this study could be categorized into two factors; circumstantial factors(bankruptcy after IMF, debt guarantee for relatives) and inner factors(the participants' behavior and characteristics). The circumstantial factors worked mainly in the trigger stage and the inner factors contributed to worsening economic crisis and facilitating the progress. According to the result, this study suggests not only individual-scale measures such as encouragement of familial bond or medical treatment of the alcoholism but also social measures including proper regulation of shark loan and opportunity supply to exit from poverty.

A Study on the Viscosity Characteristics of Dewatered Sewage Sludge according to Thermal Hydrolysis Reaction (열가용화 반응에 의하여 탈수된 하수슬러지의 점도 특성에 관한 연구)

  • Song, Hyoung Woon;Han, Seong Kuk;Kim, Choong Gon;Shin, Hyun Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.1
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    • pp.27-34
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    • 2014
  • demand for a low-cost treatment technology is high because the sewage sludge has an 80% or higher water content and a high energy consumption cost. This study apply the thermal hydrolysis reaction that consumes a small amount of energy for sludge treatment. The purpose of this study is to quantify the viscosity of sewage sludge according to reaction temperature. we measured continuously the torque of dewatered sludge by the reaction temperature. As the reaction temperature increased, the dewatered sludge is thermal hydrolysis under a high temperature and pressure. Therefore, the bond water in the sludge cells comes out as free water, which changes the dewatered sludge from a solid phase to slurry of a liquid phase. The results of the viscosity measurements according to the reaction temperature showed that the viscosity was very high at $270,180kg/m{\cdot}sec$ at a temperature of 293K, but rapidly decreased with increases in the reaction temperature to $12kg/m{\cdot}sec$ at a temperature of 400K and to $4kg/m{\cdot}sec$ at a temperature of 460K or higher, similar to the changes in the viscosity of water. And we was obtained the viscosity function of boundary condition for the optimal design of thermal hydrolysis reactor by numerical modeling based on the this results.

Effect of Fluorination and Ultrasonic Washing Treatment on Surface Characteristic of Poly(ethylene terephthalate) (불소화 및 초음파 수세가 폴리(에틸렌 테레프탈레이트) 필름의 표면 특성에 미치는 영향)

  • Kim, Do Young;In, Se Jin;Lee, Young-Seak
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.316-322
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    • 2013
  • In this study, poly(ethylene terephthalate) (PET) was treated with fluorination and ultrasonic washing treatment for hydrophilic modification of PET film. We measured the change of surface modified PET film surface characteristics using contact angle, surface free energy, FE-SEM, AFM and XPS. After direct fluorination and ultrasonic washing treatment, the water contact angle was measured to be $10.81^{\circ}$, 85% reduction compared to the untreated PET film. Total surface free energy has been measured to be $42.25mNm^{-1}$, 650% increase compared to the untreated PET film. Also RMS roughness has been measured to be 1.965 nm, 348% increase compared to the untreated PET film. Hydrophilic functional group C-OH bond concentration has increased approximately 3 times. These results are attributed to the hydrophilic functional group and cavitation due to chemical etching. From this result, it was suggested that the fluorination-ultrasonic washing treatment method could be useful to make PET film surface hydrophilic.

Identification of NMR Data for ginsenoside Rg1 (Ginsenoside Rg1의 NMR 데이터 동정)

  • Lee, Dae-Young;Cho, Jin-Gyeong;Lee, Min-Kyung;Lee, Jae-Woong;Park, Hee-Jeong;Lee, Youn-Hyung;Yang, Deok-Chun;Baek, Nam-In
    • Journal of Ginseng Research
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    • v.32 no.4
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    • pp.291-299
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    • 2008
  • The fresh ginseng roots were extracted in aqueous methanol (MeOH), and the obtained extracts were partitioned using ethyl acetate (EtOA), n-butanol (n-BuOH), and water, successively. The repeated silica gel column chromatography for n-BuOH fraction afforded a purified ginsenoside $Rg_1$. The physico-chemical, spectroscopic and chromatographic data of ginsenoside $Rg_1$, such as crystallization characteristics, melting point, specific rotation, infrared spectrometry (IR) data, fast atom bombardment/mass spectrometry (FAB/MS) data, nuclear magnetic resonance (NMR) data, retention factor (Rf) in thin layer chromatography (TLC) experiment, and retention time (r.t.) in HPLC analysis, were measured and compared with those reported in literatures. Especially, the previous literatures reported different data for ginsenoside $Rg_1$ in the $^{1}H-$ and $^{13}C$-NMR experiments. This paper gives the exactly assigned NMR data through 2D-NMR experiments, such as $^{1}H-^{1}H$ correlation spectroscopy (COSY), hetero nuclear single quantum correlation (HSQC), and hetero nuclear multiple bond connectivity (HMBC).