• Title/Summary/Keyword: boiling point

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A Feasibility Study on Geothermal Power Plant in Korea (한국형 지열발전 타당성 연구)

  • Lim, Hyo-Jae;Kwon, Jung-Tae;Kim, Geum-Soo;Chang, Ki-Chang
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.39-44
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    • 2009
  • Geothermal energy is the heat contained in the earth and its internal fluids. Geothermal energy is stored as sensible or latent heat. Supplied by both internal and external sources, it represents a vast supply which is only started to be tapped for generation of electric power. In general, this is natural dry or wet medium to high enthalpy steam at temperatures above $150^{\circ}C$. For some time, binary systems employing substances with a lower boiling point than water in a secondary circuit have been used to generate vapor for driving turbines at a lower temperature level. The utilization of binary plants and the possibility of production from enhanced geothermal systems can expand its availability on a worldwide basis. The geothermal electricity installed capacity is approaching the 10,000GW threshold. Geothermal energy is not present everywhere, but its baseload capability is a very important factor for its success.

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A Study on Distillation Property of Automotive Gasoline and Diesel Fuel (자동차용 가솔린과 디젤 연료의 증류특성에 관한 연구)

  • Youm, Kwang-Wook;Kim, Sang-Jin
    • Journal of Power System Engineering
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    • v.18 no.5
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    • pp.11-15
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    • 2014
  • Currently, there are active researches being conducted on a new combustion technology that can reduce emission quantity while enhancing vehicle performance as well as Improving fuel quality. In a gasoline engine that uses petroleum, high volatility makes it easy to jump spark ignition and prevent knocking phenomenon that occurs inside an engine. In a diesel engine that uses diesel fuel, high volatility reduces combustion residues and toxic gas and is therefore good for protecting the environment. Therefore, for fuel used in a vehicle, volatility is an important factor that influences not only engine performance but also environmental protection. This research conducted a distillation experiment using gasoline and diesel fuel for vehicles produced by domestic oil companies. The test was conducted in accordance with the method of distillation experiment described in KS M ISO3405. In addition, it used the result of analysis from the experiment to examine visual distillation characteristics of each fuel and developed a formula based on distillation temperature.

Studies on the Nonvolatile Organic Acids in the Extracts of Dried Squid (건오징어 추출물의 유기산 조성에 관한 연구)

  • 김동수;김영명;우상규
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.19 no.4
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    • pp.305-310
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    • 1990
  • The extracts of dried squid(Sepiella maindron) were prepared with water and 70% ethanol at boiling point and the major nonvolatile organic acids in the extracts were investigated. Eight kinds of nonvolatile organic acid were identified as lactic oxalic succinic malic citric pyroglutamic malonic and ${\beta}-ketoglutaric$ acid. Total amount of nonvolatile organic acid in the extracts prepared with water changed from 205.2mg% to 310.1mg% with extraction time while the extracts prepared with 70% ethanol were 272.4 mg% ~ 347.6 mg% The major compo-nents were in the range of 61.7% ~ 70.9% lactic acid 16.4 ~ 22.6% pyroglutamic acid 5.0 ~ 9.9% succinic acid 4.0 ~ 8.2% citric acid and total amount of nonvolatile organic acids in the extracts increased until 2 hour of extraction regardless of extraction solvent and then decreased slowly.

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Impulse Tests for a Composite Solid Insulator for High Voltage Superconducting Power Applications (복합고체절연물의 극저온 절연성능 평가를 위한 임펄스 내전압시험)

  • Kim, W.S.;Ryu, S.D.;Hyun, O.B.;Kim, H.R.;Yim, S.W.;Yang, S.E.;Kim, H.S.
    • Progress in Superconductivity
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    • v.13 no.1
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    • pp.24-27
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    • 2011
  • High voltage insulation in cryogenic environment is one of big issues for development of superconducting power application, such as superconducting fault current limiter, transformer, transmission cable, and so on. We had proposed a composite solid insulator composed of plastics and polymer insulation sheets for a use of high voltage superconducting power applications. It is well known that the G10 FRP keeps its mechanical strength at very low temperature and the PPLP is very good insulator adopted as insulations for superconducting transmission cables. The composition of these two materials will show very good electrical and mechanical properties adequate for the insulation components of superconducting power applications, such as bushing, insulation barrier, and even for a cryostat. Dielectric strengths of prepared samples were measured at the temperature of boiling point of liquid nitrogen at atmospheric pressure, which will be presented in this paper to show a usefulness of this technique.

Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry

  • Kim, Eun-Kyoung;No, Myoung-Han;Koh, Jae-Suk;Kim, Sung-Whan
    • Mass Spectrometry Letters
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    • v.2 no.2
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    • pp.41-44
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    • 2011
  • Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated from vacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. These heavy oils have similar boiling point ranges in the range of 210-$650^{\circ}C$, but they showed different mass ranges and double-bond equivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkyl side chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, and oxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGO is primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO contained mainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful for molecular composition characterization of petroleum heavy oils obtained from different refining processes.

Adsorption Characteristic of L-tryptophan of Affinity Membrane (친화막의 L-tryptophan 흡착특성)

  • Byun, Hong-Sik;Hong, Byung-Pyo
    • Membrane Journal
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    • v.18 no.3
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    • pp.214-218
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    • 2008
  • Protain affinity membranes based on PES-BSA was preapared by the electrospinning method. The process problem caused by the electrospining was solved by using HFB having high solubility and boiling point. It was expecting that the mass production of protein affinity membrane would be possible with broad range of optimized temperature and humidity. BSA in the PES nanofiber was confirmed by the color change from colorless to violet during the biuret test. The buffer solution with DMSO showed that the amount of elution was 5 times higher than the one when the buffer solution without DMSO was used. This is due to the restriction effect of DMSO on the dissociation of L-tryptophan from BSA during the washing step.

Comparison between Head Space Gas Sampling and Purge & Trap Sampling in Water Analysis

  • Nagayanagi, Yutaka;Nakagawa, Katsuhiro;Saito, Yoshihiro;Kim, Poongzag
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.739-744
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    • 1995
  • The two main methods to prepare water samples for analyzing volatile organic compounds(VOC's) were investigated. One is the purge and trap(PT) method and another is the head space(HS) sampling method. Both methods were effective to transfer the low boiling point components from the water sample onto the capillary column. The cryo-focusing at the top of the main capillary column was an effective way to obtain the sharpness of the chromatographic peaks but could be avoided when a semi-wide bore column was used. The recovery from the same amount of the sample was better in PT than in HS but a larger sample volume in HS method could compensate the lower efficiency. Therefore PT is suitable to the analysis of drinking water where the very low concentration must be determined. HS is suitable to waste water analysis because of the easiness of the operation. The repeatability was good and similar in both methods. For the contamination of the former sample, both methods were tough and could be used without any problems. The matrix effect which could change the equilibrium parameters in HS method was find negligible in many components. The actual samples such as tap water and river water were analyzed with both methods concerning 16 components regulated in Korea.

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Effect of Solvents on the Structure of Electrospun PVP Fiber (PVP의 전기방사 섬유 제조에서 용매에 따른 구조 변화)

  • Park, Ju-Young;Lee, In-Hwa
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.484-490
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    • 2008
  • Electrospun of PVP (polyvinylpyrrolidone) ultra fine fibers were fabricated using various solvents including methanol, ethanol, 2-propanol, butanol, acetone, methylene chloride, and DMF, which possess different properties such as boiling point, dielectric constant, and dipole moment. Electrospun PVP fiber was influenced by viscosity, conductivity, and surface tension of spinning solution. Therefore, the electrospun PVP fiber was successfully prepared under critical conditions of viscosity > $0.114kg/m{\cdot}s$, conductivity > 1.02 mS/m, surface tension < 30.0 mN/m. In case of an ethanol solvent system, average diameter of PVP fiber increased from 1701 nm to 5454 nm as increased the applied voltage from 10 kV to 20 kV.

The Characteristics of Exhaust Emissions by using Oxygenated Fuels and EGR in IDI Diesel Engine (함산소연료(Diglyme, DEE)와 EGR 방법을 이용한 간접분사식 디젤기관의 배기가스 배출 특성)

  • 유경현;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.6
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    • pp.108-116
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    • 2002
  • The diesel engine is one of the most effective transport options available in all sizes and covering a wide range of applications. But, many researchers developing the diesel engine are facing tough challenges in view of the increasingly lower emissions standards. Thus, this study will explore the possible fuel additive technology to further reduce the emissions from the IDI diesel engine. The purpose of this study is to investigate the effects of oxygenated fuels on the exhaust emissions and to attain a better trade-off relation between smoke and NOx in four cylinder diesel engine. Experiments were conducted with oxygenated fuels as an effective way to improve the combustion efficiency. Some of oxygenated fuel(Diglyme and DEE) were added to the conventional diesel fuel which had no an oxygen content. Also, EGR was adopted for reducing NOx without any strong adverse effects on other exhaust emissions. This study concluded that exhaust emissions in diesel engine could be reduced by adding the oxygenated fuels which had lower boiling point, and the combustion efficiency was also improved as the oxygen content in fuel increased.

Studies on Preparation of $TiO_2$Powder with Purity and Fine Particle -A Study of High Purifying(I)- (고순도.미립 $TiO_2$분말 제조에 관한 연구 -고순도화 연구(I)-)

  • Lee, Mi-Jai;Jee, Mi-Jung;Kim, Hwan;Lee, Chul-Tae;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.37 no.10
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    • pp.933-937
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    • 2000
  • 고기능성 전자재료용 TiO$_2$분말 및 박막제조에 사용되는 중간생성물인 TiCl$_4$는 99% 이상의 고순도가 요구된다. 고순도.미립의 TiO$_2$분말 및 TiCl$_4$는 황산법으로 제조한 저순도 TiO$_2$원료를 사용하여 염소화법으로 Ti-염화물 및 염화불순물로 제조한 후, 대부분의 염화불순물들은 3단계 과정을 거쳐 고순화 하였다. 대부분의 염화불순물은 분리.응축 및 분별증류로, VOCl$_3$는 mineral oil을 첨가하여 비등점을 변화시켜, 그리고 미량의 염화불순물은 열가수분해하여 침전시킨 후 유기용제 처리하여 제거하였다. 유기용제 처리는 TiO$_2$분말의 고순도화에 도움이 되었으며, 입자간의 응집을 적게 하여 TiO$_2$입자크기도 작아졌다. 또한 anatase에서 rutile 결정구조로의 전이온도도 낮아지는 부수적인 효과를 보였다.

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