• Title/Summary/Keyword: boiling point

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Improvement of the resistance to Treeing by additive in Low Density Polyethylene (첨가재에 의한 저밀도 폴리에틸렌의 내트리잉성 향상)

  • 김봉협;임기조
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.35 no.1
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    • pp.17-25
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    • 1986
  • Discussions on this paper are related to the effects of organic materials to treeing phenomena of low density polyethylene. As additives, 11 kinds of organic compounds are selected by considering the respective features such as melting point, boiling point, electron affinity as well as molecular structure, and then the specimens of low density polyethylene are prepared by blending with 10wt% of the selected additives. For the comparison of effectiveness of treeing resistance and interpretation of the mechanism of compounds as treeing retardants, several investigations such as the tree acceleration test, the prestressed test and the measurement of internally occurred partial discharge are carried out. As the results, meta-Cresol is regard as the most effective retardant among those, and it is supposed that this aromatic compound to be comprised of radical having large electron affinity has strong capability to accept energetic electron to prevent or delay the growth of discharge streamer. Furthermore, by activating partial discharge at the wall of tree pit through the function of trapped electron at this material, the gas pressure in the pit is increased up to prevent the growth of streamer.

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Miniature J-T cryocooler using argon and nitrous oxide mixture

  • Hwang, Gyu-Wan;Jeong, Sang-Kwon
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.4
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    • pp.38-42
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    • 2008
  • Miniature J-T cryocooler using nitrogen or argon has been widely adopted in cooling infrared sensor for space/military application and cryosurgery. Argon or nitrogen, however, has relatively low specific cooling power compared to nitrous oxide, but the ultimate operating temperature is much lower than nitrous oxide. On the other hand, nitrous oxide has large specific cooling power, but the operating temperature is limited to its boiling point (>183K). To compromise the different characteristics of these gases, the performance of miniature J-T cryocooler using argon and nitrous oxide mixture is investigated in this paper. Three different compositions of mixture (25/75, 50/50, and 75/25 molar fraction) are blended and tested. The results are compared with the experiments of pure argon and pure nitrous oxide. The experimental results show some encouraging potentiality of mixed refrigerant J-T cryocooler. The critical clogging problem, however, was observed with argon and nitrous oxide mixture, and the lowest achievable temperature with this mixture was limited to the freezing point of nitrous oxide. The paper discusses detailed clogging process of the mixture and suggests an alternative.

Experimental Study on the Thermal Characteristics According to the Content Change of Biodiesel Mixture (바이오디젤 혼합물의 함량변화에 따른 열적 특성에 대한 실험적인 연구)

  • Ju Suk Kim;Jae Sun Ko
    • Journal of the Society of Disaster Information
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    • v.19 no.3
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    • pp.532-544
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    • 2023
  • Purpose: To identify and evaluate the risk of chemical fire causative substances by using thermal analysis methods (DSC, TGA) for the hazards and physical property changes that occur when newly used biofuels are mixed with existing fuels It is to use it for identification and evaluation of the cause of fire by securing data related to the method and the hazards of the material according to it. Method: The research method used in this experiment is the differential scanning calorimeter (DSC: Difference in heat flux) through quantitative information on the caloric change from the location, shape, number, and area of peaks. flux) was measured, and the weight change caused by decomposition heat at a specific temperature was continuously measured by performing thermogravimetric analyzer (TGA: Thermo- gravimetric Analyzer). Result: First, in the heat flux graph, the boiling point of the material and the intrinsic characteristic value of the material or the energy required for decomposition can be checked. Second, as the content of biodiesel increased, many peaks were identified. Third, it was confirmed through analysis that substances with low expected boiling points were contained. Conclusion: It was shown that the physical risk of the material can be evaluated by using the risk of biodiesel, which is currently used as a new energy source, through various physical and chemical analysis techniques (DSC + TGA).In addition, it is expected that the comparison of differences between test methods and the accumulation and utilization of know-how on experiments in this study will be helpful in future studies on physical properties of hazardous materials and risk assessment of materials.

Retention Behaviors of Natural Gas Components on a Single Column by Gas Chromatography (기체 크로마토그래피에 의한 단일 컬럼상에서 천연가스 성분의 머무름 거동)

  • Choi, Yong-Wook;Choe, Kun-Hyung;Lee, Dai-Woon
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.329-338
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    • 1994
  • The retention behaviors of natural gas components were studied on a single column by gas chromatography. The dead time, $t_0$ was obtained by using extrapolation of homologous series to determine capacity factors. The plots of retention data for homologous series and carbon number at different temperatures were shown to converge into a single point, which point was determined as a dead time. The results of the effect of temperature on the column efficiency for n-butane exhibited the plate number, N incerased with temperature, but the resolution among the fast eluted components decreased. The adsorption enthalpy (${\Delta}H^0{_{ads}}$) for each component on 28% DC 200 stationary phase was determined, and in order to investigate the retention behaviors of natural gas components the regression analysis of log $t_R$, log k' and log ${\alpha}$ vs. van der Waals volume(Vw), molecular connectivity index(X) and hydrophobic fragmental constant(f) were carred out. Good correlation was found between log k' vs. Vw, and log k' vs. f. The correlations between the physical properties of natural gas and the physical parameters were investigated by the linear regression analysis. The relationships between Vw vs. molecular weight and heating value(${\Delta}H_{comb}$), X vs. boiling point, and f vs. molecular weight, boiling point and heating value exhibited the high correlation coefficient more than 0.99. Using the regression equation between the heating value of natural gas and Vw the predicted heating values from $C_6$ to $C_{10}$ showed good agreement with those reported in the literature within 0.2% relative error.

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Blending effect of pyrolyzed fuel oil and coal tar in pitch production for artificial graphite

  • Bai, Byong Chol;Kim, Jong Gu;Kim, Ji Hong;Lee, Chul Wee;Lee, Young-Seak;Im, Ji Sun
    • Carbon letters
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    • v.25
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    • pp.78-83
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    • 2018
  • Pyrolyzed fuel oil (PFO) and coal tar was blended in the feedstock to produce pitch via thermal reaction. The blended feedstock and produced pitch were characterized to investigate the effect of the blending ratio. In the feedstock analysis, coal tar exhibited a distinct distribution in its boiling point related to the number of aromatic rings and showed higher Conradson carbon residue and aromaticity values of 26.6% and 0.67%, respectively, compared with PFO. The pitch yield changed with the blending ratio, while the softening point of the produced pitch was determined by the PFO ratio in the blends. On the other hand, the carbon yield increased with increasing coal tar ratio in the blends. This phenomenon indicated that the formation of aliphatic bridges in PFO may occur during the thermal reaction, resulting in an increased softening point. In addition, it was confirmed that the molecular weight distribution of the produced pitch was associated with the predominant feedstock in the blend.

Development of an Hazard Analysis Critical Control Point (HACCP) Application Model for Dried Anchovy Workplace (마른멸치 작업장의 식품안전관리인증기준(HACCP)모델 개발)

  • YOON, Hyun-Jin;HAM, In-Tae;Kim, Sang-Hyeon;CHOI, Jong-Duck
    • Journal of Fisheries and Marine Sciences Education
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    • v.28 no.3
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    • pp.713-726
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    • 2016
  • This study were attempted to apply the HACCP system adopted in the dried anchovy workplace to ensure the hygiene safety of dried anchovy workplace. In this study, HACCP system procedures, including HACCP team organization, determination of critical control point(CCP), establishment of critical limits, mornitering and verification etc., were established using KFDA 12 procedures. To determine whether hazards were critical elements, we evaluated the likelihood and seriousness of each hazard element. The likelihood of residual microorganism and metal piece exceeding the acceptable limit in dried anchovy products were demonstrated to be a critical hazard element. Management of the boiling(CCP-1B) and metal detection(CCP-2P) were determined to be a critical control point. The standards for acceptable residual microorganism and metal piece were set based on relevant laws and regulations, and then the limits were adapted and established for the CCP. An HACCP plan applicable to dried anchovy workplace was established.

Estimation of Pollution Using Load Duration Curves at Streams in Sapgyo Watershed (부하지속곡선을 이용한 삽교호수계 지류하천의 오염원인 분석)

  • Cho, Jeongho;Kim, Hongsu;Cho, Byunguk;Park, Sanghyun;Lee, Mukyu;Lee, byeonggu
    • Journal of Korean Society on Water Environment
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    • v.37 no.3
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    • pp.175-189
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    • 2021
  • In this study, 48 streams in the Sapgyo Watershed were selected, and the Load Duration Curves (LDC) were drawn up for each stream using water quality and flow monitoring over the last three years (2018-2020), and it was evaluated whether the target water quality was achieved for each flow section. As a result of evaluating whether or not the target water quality exceeded according to the LDC, it was found that 22 rivers exceeded the target water quality. Five rivers exceeded the target water quality due to point pollutant sources, 13 rivers exceeded the target water quality due to non-point pollutant sources, and 4 rivers exceeded the target water quality due to both point and non-point pollutant sources. Among the rivers that exceeded the target water quality due to point pollutant sources, which included domestic sewage of the untreated population, there is a need to reduce the influx of polluted loads by the untreated population. The use of eco-friendly fertilizers is recommended for rivers with a relatively high farmland ratio among rivers exceeding the target water quality due to non-point pollutant sources, and installation of boiling point reduction facilities that can reduce the amount of polluted load introduced during rainfall or manage water shores. In rivers with a large number of livestock breeding heads, the livestock houses located in these rivers need to be preferentially transferred to livestock manure treatment plants. Due to the high ratio of land area because of urbanization, initial rainwater treatment facilities are required to reduce the amount of pollutant load flowing into the river through the impermeable layer during rainfall.

Effect of Parameters in Evaporative Removal Process by Absorption of a CW Laser (연속 레이저 흡수에 의한 증발제거 과정의 관련 인자 영향 고찰)

  • 김진윤;송태호
    • Journal of Biomedical Engineering Research
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    • v.16 no.1
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    • pp.67-76
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    • 1995
  • Explosive evaporative removal process of biological tissue by absorption of a CW laser has been simulated by using gelatin and a multimode Nd: YAG laser. Because the point of maximun temperature of laser-irradiated gelatin exists below the surface due to surface cooling, evaporation at the boiling temperature is made explosively from below the surface. The important parameters of this process are the conduction loss to laser power absorption (defined as the conduction-to-laser power parameter, Nk), the convection heat transfer at the surface to conduction loss (defined as Bi), dimensionless extinction coefficient (defined as BrJ, and dimensionless irradiation time (defined as Fo). Dependence of Fo on Nk and Bi has been observed by experiment, and the results have been compared with the numerical results obtained by solving a 2-dimensional conduction equation. Fo and explosion depth (from the surface to the point of maximun temperature) are increased when Nk and Bi are increased. To find out the minimum laser power for explosive evaporative removal process, steady state analysis has been also made. The limit of Nk to induce evaporative removal, which is proportional to the inverse of the laser power, has been obtained.

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The Weldability of Primer-coated Steel for Shipbuilding by $CO_2$ Laser (조선용 Primer코팅강판의 $CO_2$레이저 용접성)

  • Park, Hyun-Joon;Kim, Jong-Do;Kim, Young-Sik
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.316-321
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    • 2003
  • The spatter and porosity could be occurred during $CO_2$ CW laser welding of Primer-coated Steel for Shipbuilding. This study has suggested an alternative idea by examining of weld-defect formation mechanism. The primer-coated plate has caused the spatter, humping bead and porosity and these are main part of the welding defect, attributed to the powerful vaporizing pressure of primer attached on the base metal. The zinc of primer has a boiling point that is the lower temperature than melting point of steel. Zinc va}X)f will build up at the interface between the two sheets and this tends to deteriorate the quality of the weld by ejecting weld material from lap position or leaving porosity. Therefore introducing a small gap clearance in the lap position, the zinc vapor could escape through it and sound weld beads can be acquired. In conclusion, we suggested the occurred and prevented mechanism of weld defects with searching the factor.

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Extingushiment by the Colling Effect of the Fuel Surface with Pool Fires (Pool 화재에서의 표면 냉각에 의한 소화)

  • 한용식;김명배;신현동
    • Fire Science and Engineering
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    • v.11 no.4
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    • pp.15-23
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    • 1997
  • A series of measurements and visualization to investigate the extingushiment of water sprays with pool fires is presented. Fire source is a small-scale pool burner with methanol, ethanol and gasoline. Measurements of temperature, O2, CO2, and CO concentrations along the plume centerline are carried out to observe pool structures without water sprays. Visualization by the Ar-ion laser sheet flow pattern of droplets of the sprays above the pool fires. It is observed than in the case of methanol and ethanol, water sprays continuously penetrate into the center of fuel surfaces. The gasoline pool fire allows intermittent penetration of water sprays because of pulsating characteristics of the gasoline flame. To evaluate the cooling effect of the fuel surface by the sprays, the temperature was measured at the fuel surface. As soon as the mists reach the fuel surface of methanol and ethanol, the temperatures of the fuel surface decrease rapidly below the boiling point, and then the fires are extinguished. Due to the application of mist upon the gasoline fire, though the fuel temperature decrease abruptly at the time of the injection, such a repid decrease do not continue till the extinction point.

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