• Title/Summary/Keyword: blending resin

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A Study on the Preparation of Durable Softening Water-repellent by Blending Acrylic Copolymer and Fatty Carbamide;IV. Water-repellent Finish of P/C Blended Fabrics (아크릴 공중합체와 지방산 카르바미드의 블렌딩에 의한 내구유연발수제의 제조에 관한 연구;IV. P/C 혼방직물에의 발수가공)

  • Ko, Jae-Yong;Hong, Eui-Suk;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.2
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    • pp.39-46
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    • 1996
  • Durable softening water-repellenting agent such as PODCW, PDDCW and PEDCW were prepared by blending cationized compound such as poly(octadecyl methacrylate-co-2-diethylaminoethyl methacrylate)[PODC], poly(2-dodecyl methacrylate-co-2-diethyl-aminoethyl methacrylate)[PDDC] and poly(2-ethylhexyl methacrylate-co-2-diethyl-aminoethyl methacrylate)[PEDC], and cationized compound of fatty carbamide, of which synthetic methods were reported in the previous paper, waxes, and emulsifiers. The results of physical tests of the P/C blended fabrics treated with PODCW, PDDCW and PEDCW with and without textile finishing resin, showed a remarkable improvement of the physical properties. The prepared water-repellenting agents, PODCW-6 and PDDCW-1, were treated on P/C blended fabrics with and without resin. For any cases, there are a little changes between initial water repellency and repellency after 3 times washing of the fabrics. Therefore, the water-repellenting agents proved to be a durable agents, and initial water $100^{+}$ and $90^{+}$ point, respectively.

Effects of Pigment Blending and Thickener Characteristics on Calendering Response and Structure of Coated Paper-Effect of Pigment Blending on Coating Properties- (도공 안과의 혼합과 증점제의 특성과 도공지의 광택 발현성과 구조적 특성에 미치는 영향)

  • 박종열;이학래;김병수;정현채
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.62-73
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    • 1998
  • The aim of this work was to investigate the effects of pigment composition on the calendering response and structure of the coated paper. Calendering response of the coated paper was determined from the gloss values of the uncalendered and calendered coated papers, and the relationship between gloss and coating structure was discussed. The surface and cross section of the coating layer was observed using a scanning electron microscope to examine the coating structure. Coating layers were hardened in epoxy resin and polished with carbimet paper disc for preparing SEM samples. Maximum calendering response was obtained for the coated paper prepared from 80pph of clay and 20pph of ground calcium carbonate (GCC) as pigments. Photomicrographs of the surface and cross section of the coating layer show that clay tends to form dense coating structure, while GCC tends to form bulky coating layer.

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Synthesis of Silicone Softner for Permanent Press Finish and Its Characterization (Permanent Press 가공용 실리콘 유연제의 합성과 그의 특성화)

  • Park, Chang-Hwan;Kim, Seung-Jin;Kim, Young-Geun;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.29-34
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    • 1995
  • Silicone softner(SSN-3) for permanent press(PP) finish was prepared by blending beef tallow hardened oil for Improving softness, water, the emulsion, which was synthesized from pentaerythritol monostearate as a softening component and silicone oil KF-96 as a lubricating component. The prepared SSN-3 and the PP finishing resin were applied to PP finishing cotton broad cloth and P/C gingham samples using one bath method. The properties such as crease recovery, tear strength, bending resistance test were tested. The samples treated with SSN-3 and PP finishing resin have improved properties, compared with nontreated samples, those treated only with PP finishing resin, those treated with commercial PP finishing softners and PP finishing resin. Also from the bending resistance test, the two kinds of fabric samples treated with SSN-3 of 3% showed grade 5 and these were good enough in feeling.

Preparation and Physical Properties of Silicone Softner for PP Finish (PP 가공용 실리콘 유연제의 제조와 물성연구)

  • Im, Wan-Bin;Yang, In-Mo;Jung, Choong-Ho;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.2
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    • pp.117-122
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    • 2002
  • A silicone softner (SS-5), a permanent press (PP) finish, was prepared by blending silicone oil KF-96 (as a lubricating component) and beef tallow hardened oil (as a softening component) which was synthesized from fatty polyamide salts. The prepared SS-5 and the PP finishing resin were applied to PP finishing cotton cloth and P/C gingham sample by one-bath method. The properties such as crease recovery, tear strength, and bending resistance were tested. The samples treated with SS-5 and PP finishing resin showed improved properties when comparing with the untreated ones, with the ones treated only with PP finishing resin, with ones treated with commercial PP finishing softners and PP finishing resin. The grades of fabric samples treated with 3% SS-5 were fifth grade in the bending resistance test.

Mechanical Properties of Rice Husk Flour-Wood Particleboard by Urea-Formaldehyde Resin

  • Lee, Young-Kyu;Kim, Sumin;Yang, Han-Seung;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.3
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    • pp.42-49
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    • 2003
  • The objective of this research was to investigate the possibility of using rice husk flour as a partial substitute for the wood particles used as the raw material for manufacturing particleboards, by examining the physical and mechanical properties of the rice husk flour-wood particleboard as a function of the type of urea-formaldehyde resin used. Commercial wood particles and two types of rice husk flours (A type (30 ㎛), B type (300 ㎛)) were used. E1 and E2 class urea-formaldehyde resin was used as the composite binder, combined with 10 wt.% NH4Cl solution as a hardener. Rice husk flour-wood particleboards with dimensions of 27×27×0.7 (cm) were manufactured at a specific gravity of 0.7 with rice husk flour contents of 0, 5, 10, and 15 (wt.%). We examined the physical properties (specific gravity and moisture content), mechanical properties (three point bending strength and internal bonding) of the composite. In general, it can be concluded that composites made from rice husk flours are of somewhat poorer quality than those made from wood; however, blending in small amounts of rice husk flour (e.g., 5% to 10% by weight) may have no significant impact on quality.

Effects of Blending Fatty Acid-Glycerol-pMDI with Urea-Formaldehyde Resin Adhesives to Their Adhesion for the Use of Soybean Oil (콩기름 이용을 위한 지방산-글리세롤-pMDI와 요소수지 혼용 접착제가 접착성능에 미치는 영향-)

  • You, Young-Sam;Choi, Jin-Lim;Seo, Jun-Won;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.31-36
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    • 2006
  • This study was conducted to improve the bond strength of plywood bonded with F/U molar ratio urea-formaldehyde (UF) resins modified with the selected FGMDI prepolymer contents for various purposes. The amount of FGMDI was mixed with liquid UF resin at 0 wt% (as control), 2 wt%, 5 wt%, 10 wt%, 25 wt%, and 50 wt% based on the resin solids. As results, in bonding strength, plywood with F/U molar ratio of 1.4 showed the highest value in Type 2 test and all molar ratio UF resins modified with over 25 wt% of the FGMDI showed more than $11kgf/cm^2$, which was satisfied the minimum requirement of KS standard, $7.5kgf/cm^2$, after Type1.5 testing. As F/U molar ratio was increased and the FGMDI addition in the UF resin was increased, average reduction rate of Type 1.5 bonding strength compared with Type 2 was significantly decreased.

Synthesis of Polyurethane/Epoxy Hybrid Resin used for Damper of Loudspeaker (스피커용 댐퍼에 사용되는 폴리우레탄/에폭시 하이브리드 수지의 합성)

  • Choi, Hyun-Seuk;Choi, Dong-Ho;Huh, Man-Woo
    • Textile Coloration and Finishing
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    • v.28 no.1
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    • pp.40-47
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    • 2016
  • As a coating material for loudspeaker dampers, resilient polyurethane/epoxy hybrid resins were synthesized to replace conventional phenol resin and examined the physical properties, which are not only environmentally friendly but also not harmful to human. Five types of polyurethane resins were synthesized in the step-shot method using methylene diisocyanate, three polyols such as poly tetramethylene ether glycol(PTMEG, MW:2000), poly(1,4-buthylene adipate(PBAP, MW:2000), and poly carbonatediol(PCD, MW:2000), and three chain extenders such as ethylene glycol(EG), neopentyl glycol(NPG), and 1,4-buthandiol(1,4-BD). The five types of synthesized polyurethane resins and commercially available bisphenol A type epoxy resin were blended in weight ratios of 90:10, 70:30, and 50:50 to synthesize 15 types of polyurethane/epoxy hybrid resins. Among the polyurethane resins, the one that was synthesized using PCD and 1,4-BD showed excellent tensile strength, 100% modulus, low extension, and relatively high viscosity. Polyurethane/epoxy hybrid resins with higher epoxy resin contents showed better thermal properties and water resistance while those with higher polyurethane contents showed higher flexibility. The polyurethane/epoxy hybrid resin made by blending the polyurethane based on PCD and 1,4-BD with a bisphenol A type epoxy resin in a weight ratio of 70:30 was identified to be the most suitable to be used in speaker dampers.

Low temperature curable organic gate insulator for organic field-effect transistors

  • Kim, Joo-Young;Jung, Myung-Sup;Lee, Sang-Yoon;Kim, Jong-Min;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.664-666
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    • 2008
  • Low-temperature curable organic insulator was prepared through blending of polyimide type base resin and cross-linking agent. The newly developed resin can be formed into films using a wet process and cured at $130^{\circ}C$. Using the low temperature cured film as the gate dielectric layer, the field effect mobility of $0.15\;cm^2/V{\cdot}s$ was obtained from a pentacene field effect transistor in the saturation regime and no hysteresis behavior was observed in transfer curves.

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Curing Behavior by Rheovibron of Acrylic High-Solid Coatings (아크릴계 하이솔리드 도료의 Rheovibron에 의한 경화거동 연구)

  • Kim, Dae-Won;Hwang, Kyu-Hyun;Kim, Seung-Jin;Wu, Jong-Pyo;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.2
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    • pp.142-152
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    • 2001
  • Acrylic resin(ACR) was blended with a curing agent, hexamethoxymethylmela-mine(HMMM), in which blending ratio was 70:30. The curing behavior was examined using Rheovibron. Cross-linking reaction started at $170^{\circ}C$ in 2 min of reaction and curing was completed in 10 min. It was found that the extent of cross-linking increased with the content of acetoacetoxyethyl methacrylate monomer in the ACR.

Physical Properties of High-Solid Coatings with Acrylic Resins Containing Acetoacetoxy Group and HDI-Trimer (Acetoacetoxy기 함유 아크릴수지와 HDI-Trimer에 의한 하이솔리드 도료의 도막물성)

  • You, Hyuk-Jae;Chung, Dong-Jin;Hahm, Hyun-Sik;Park, Hong-Soo;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.3
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    • pp.237-242
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    • 2003
  • The high-solid coatings were prepared by blending the synthesized acrylic resin in the previous paper and hexamethylene diisocyanate-trimer and curing it at room temperature. The characterization of the films of the prepared coatings was performed. The impact resistance, $60^{\circ}C$ specular gloss, cross-hatch adhension, and heat resistance of the films proved to be good, and the pencil hardness and drying time proved to be slightly poor. Especially, there was a remarkable improvement in the heat resistance. This improvement may stem from the regular arrangement of ethyl groups introduced into the acrylic resin. From a viscoelastic measurement using a rigid-body pendulum, curing was accelerated with the $T_g$ value. With the increase in $T_g$, log damp value was lowered and dynamic viscoelasic $T_g$ of a cured film was increased.