• 제목/요약/키워드: blended structure

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Rheological properties and thermal degradation behaviors of sonochemically treated polycarbonate/polysiloxanes blends

  • Choi, Mi-Kyung;Kim, Yu-Bin;Kim, Ji-Hye;Kim, Hyung-Su
    • Korea-Australia Rheology Journal
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    • 제20권4호
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    • pp.245-251
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    • 2008
  • Two polysiloxanes having different chemical structures were blended with polycarbonate (PC) under ultrasonic irradiation in solution. The polysiloxanes used were poly(methylphenyl siloxane) and vinyl-terminated poly(dimethyl siloxane). It was of primary interest to investigate the effect of polysiloxane structure on the rheological properties of PC/polysiloxane blends. It was found that a small amount (1.5 phr) of polysiloxanes greatly altered the melt viscosities and elasticity of PC. In particular, incorporation of poly(methylphenylsiloxane) led to a notable increase in elasticity with greater shear sensitivity of PC. The observed rheological behaviors of PC/polysiloxane blends were partly explained in conjunction with the tendencies found in ultrasonic degradation of polysiloxanes. Thermal stability and morphology in sonicated blends of PC/polysiloxane blends were also discussed.

무기계난연제 첨가형 상용화블렌드/층상실리케이트 나노복합재료의 제조 및 난연특성에 관한 연구 (A Study on the Preparation and Flame Retardancy of Compatibilized Blend/Layered Silicate Nanocomposites with Inorganic Flame Retardant)

  • 강영구;송종혁
    • 한국안전학회지
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    • 제21권1호
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    • pp.79-85
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    • 2006
  • Olefinic compatibilized blend(R-PP/R-PE)/layered silicate composites have been prepared by melt intercalation technique directed from $Na^{+}$ montmorillonite(MMT) or organophilic montmorillonites while using magnesium hydroxide as flame retardant. Morphology and flammability properties were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), thermogravimetry analysis(TGA), limiting oxygen index(LOI), UL94 test. It is found that the compatibilized blend/layered silicate(Cloisite 20A) nanocomposites have a mixed immiscible-intercalated structure and there is better intercalation when a compatibilizer is combined with the polymer and layered silicate to be melt blended. A very large increase in the LOI value was observed with hybrid filler addition and further enhancement in thermal stability and compatibility of blend was obtained for the compatibilized blend containing small amount of layered silicate.

기계적 밀링 및 방전 플라즈마 소결 공정을 이용한 벌크 비정질 복합재의 제조 (Fabrication of Bulk Metallic Glass Composites by Mechanical Milling with Subsequent Spark Plasma Sintering Process)

  • 이진규;김택수;김정곤
    • 한국분말재료학회지
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    • 제14권3호
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    • pp.197-201
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    • 2007
  • Bulk metallic glass (BMG) composite was fabricated by consolidation of milled metallic glass composite powders. The metallic glass composite powder was synthesized by a controlled milling process using the Cu-based metallic glass powder blended with 30 vol% Zr-based metallic glass powders. The milled composite powders showed a layered structure with three metallic phases, which is formed as a result of mechanical milling. By spark plasma sintering of milled metallic glass powders in the supercooled liquid region, a fully dense BMG composite was successfully synthesized.

매스콘크리트에서 최적의 타설 단면 결정을 위한 해석적 연구 (Analysis Study for the Determination of Optimized Block Size in Mass Concrete)

  • 김진근;김상철;이두재;김국한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1997년도 봄 학술발표회 논문집
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    • pp.422-429
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    • 1997
  • Thermal stress induced by hydration heat may produce cracks in mass concrete structure, which can result in structural problems as well as bad appearance. To minimize crack occurrence in massive structural, thus, the study put an emphasis on the determination of optimized lift height and block size. In the parametric study different sizes and lift heights were used to measure the magnitudes of hydration heat and thermal stresses for 3 different types of concrete fabricated with 1 pure cement and 2 blended Portland cements. As a result of analysis. it was found that magnitude of hydration heat and the occurrence of thermal cracks depend on the restriction conditions and material characteristics, especially adiabatic material parameters. It was also found that optimized lift height and block size can be determined from an appropriate combination of the degree of inner and outer structural restrictions.

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Hydration properties of cement pastes containing high-volume mineral admixtures

  • Tang, Chao-Wei
    • Computers and Concrete
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    • 제7권1호
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    • pp.17-38
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    • 2010
  • This research aimed to investigate the influence of high-volume mineral admixtures (MAs), i.e., fly ash and slag, on the hydration characteristics and microstructures of cement pastes. Degree of cement hydration was quantified by the loss-on-ignition technique and degree of pozzolanic reaction was determined by a selective dissolution method. The influence of MAs on the pore structure of paste was measured by mercury intrusion porosimetry. The results showed that the hydration properties of the blended pastes were a function of water to binder ratio, cement replacement level by MAs, and curing age. Pastes containing fly ash exhibited strongly reduced early strength, especially for mix with 45% fly ash. Moreover, at a similar cement replacement level, slag incorporated cement paste showed higher degrees of cement hydration and pozzolanic reaction than that of fly ash incorporated cement paste. Thus, the present study demonstrates that high substitution rates of slag for cement result in better effects on the short- and long-term hydration properties of cement pastes.

Marmatite 鑛의 直接酸浸出에 關한 硏究 (第2報) ${\beta}$-ZnS Autoclave Leaching의 反應機構에 關한 硏究 (Direct acid Leaching of zinc from Marmatite ores 2 Kinetics of Autoclave Leaching of Synthetic ${\beta}$-ZnS)

  • 김재원
    • 대한화학회지
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    • 제11권1호
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    • pp.33-37
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    • 1967
  • The influence of impurities contained in Marmatite ores on leaching of zinc was investigated. The zinc sulfide having the same crystal structure of natural Sphalerite was prepared by heating the zinc sulfide chemically precipitated, at $650^{\circ}C$ in nitrogen atmosphere. The activation energy of the sample was 25.8 kcal per mole in the leach test when oxygen partial pressure was 5 atm. and the value was exceedingly high compared to that obtained in Marmatite ores. Synthetic zinc sulfides added with small amount of each impurities were treated in same procedure. As a result, it was found that the leaching velocity was accelerated sharply when about 1 percent of $Cu^{++}$ was blended to the sample. Larger amount of iron has also same effect but the effect was minor compared to the copper. The other impurities indicated no appreciable catalytic action.

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Rolling Contact Fatigue of Hot-forged Steels out of Prealloyed Powders and Powder Blend

  • Dorofeyev, Vladimir;Sviridova, Anna
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.559-560
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    • 2006
  • Powder forging is used for heavy-loaded parts (rings of rolling-contact bearings, gears etc.) production. Rolling contact fatigue is material property values of which characterize possibility of practical utilization of such parts. Rolling contact fatigue of some steels obtained out of prealloyed powders Astaloy CrM, Atomet 4601, Atomet 4901 and powder blends iron-carbon-nickel by hot forging is studied in the present paper. Effect of various kinds of heat and thermomechanical treatment on rolling contact fatigue is determined. Thermomechanical treatment provides optimal values of rolling contact fatigue. In this case steel structure contains up to 40% of retained metastable austenite which is transformed to martensite on trials. Thus typically crack is generated on residual pores and non-metallic inclusions instead of martensite zones in wrought steels.

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폴리우레탄-폴리에칠렌옥사이드-폴리프로필렌옥사이드-디바이스로부터의 헤파린 방출 (Heparin Release from Polyurethane-Polyethylene Oxide-Polypropylene Oxide Device)

  • 유재권;전성주;김성호
    • Journal of Pharmaceutical Investigation
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    • 제18권4호
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    • pp.169-174
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    • 1988
  • The release of heparin from monolithic devices composed of different ratios of polyethylene oxide-polypropylene oxide (PEO-PPO) and hydrophobic polyurethane was investigated. The release rate of heparin could be controlled by varying the PEO-PPO content. The heparin release rate from the devices increased as the content of PEO-PPO in the devices increased. The release mechanism may be associated with creation of micro-channels and pores through the devices following the change in the physical structure of the polymer network. Hydrophobic polyurethane containing PEO-PPO can provide an antithrombogenic material for prolonged release of heparin from a heparin blended system.

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HDPE/EVA혼합수지의 공간 전하 분포에 관한 연구 (A Study on Space Charge Distribution of HDPE Mixed with EVA)

  • 정의환;허준;윤재훈;임기조;이흥규
    • 전기학회논문지
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    • 제58권11호
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    • pp.2229-2235
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    • 2009
  • In this paper, each specimen blended at weight proportions of 80% HDPE to 20% EVA, 70% HDPE to 30% EVA, 60% HDPE to 40% EVA, and 50% HDPE to 50% EVA was manufactured respectively. The insulation performances of the proposed insulator were compared with conventional XLPE, main insulating material of CV cable on the basis of the investigation results of DC insulation performances. From the space charge density, electric field and potential profiles with raising DC voltage and time variation in HE82, distortion of electric field distribution was improved. As EVA mixed into the bulks acts as nucleation in crystallization process of HDPE, the size of spherulites became decreased and finally formed continuous network structure. Ultimately, it resulted from extinction of space charge in the interfacial region of spherulites.

지역사회기반학습 수업 운영 사례와 효과 연구 (A Case Study of Community-based Service Learning Outcomes)

  • 이주성
    • 공학교육연구
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    • 제26권4호
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    • pp.36-46
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    • 2023
  • This paper presents a case study and online-offline (hybrid) course structure for project-oriented community-based service learning in order to solve real-world problems for society. It examines social issues and conduct student projects to develop solutions that can generate sustainable value. This course helps students to use their major knowledge to assess and solve the problems faced by the local community. The outcomes of this course conducted via online lectures and offline project activities are discussed. The operation of this blended type of social problem-solving course is also stated.