• Title/Summary/Keyword: blend film

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Preparation and Electrochemical Behaviors of Polymer Electrolyte Based on PEO/PMMA Containing Li Ion (Li 이온 포함하는 PEO/PMMA 고분자 전해질의 제조 및 전기화학적 거동)

  • Han, A-Reum;Park, Soo-Jin;Shin, Jae-Sup;Kim, Seok
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.476-480
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    • 2009
  • A polymer composite electrolyte of a blend of poly(methyl methacrylate)(PMMA) and poly(ethylene oxide) (PEO) as a host polymer, the ethylene carbonate as a solvent, and $LiClO_4$ as a salt was studied. The crystallinity of the polymer electrolytes was evaluated using differential scanning calorimeter(DSC). The ionic conductivity of the polymer electrolytes was measured by frequency response analyzer(FRA) method. The effect of PEO/PMMA blend ratios on the ionic conduction in these electrolytes was investigated. The electrolyte films showed a phase separation due to immiscibility of the PMMA with the PEO. The PMMA-rich phase and the PEO-rich phase were produced during a film casting. The ionic conductivity of blend electrolyte was dependent on the content of PMMA and showed the highest value at 20 wt.%. However, when PMMA content exceeds 20 wt.%, the ionic conductivity was decreased due to the slow ionic transport through the PMMA-rich phase.

Gas and Lipid Permeabilities and Biodegradability of Poly(3-Hydroxybutyric Acid)/Chitosan Blend Film (Poly(3-Hydroxybutyric Acid)와 Chitosan 블렌드 필름의 기체 투과도, 유지 투과도 및 생분해도)

  • 김미라
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.7
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    • pp.1224-1229
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    • 2004
  • The blend films of poly(3-hydroxybutyric acid) (PHB) with chitosan were prepared and water vapor transmission rate, oxygen permeability and lipid permeability of the PHB/chitosan films were measured. Additionally, the biodegradability of the PHB/chitosan films was also evaluated. Water vapor transmission rate and oxygen permeability of the films decreased by the addition of chitosan. The addition of polyethylene glycol (PEG, plasticizer), however, increased the water vapor transmission rate and oxygen permeability of the films. In the evaluation of lipid permeability, all the films except PHB (the film made of only PHB) and PHB-P (the film made of PHB and PEG) did not permeate beef tallow for 24 hours. The consumed oxygen for PHB/chitosan films during incubation was greater than that for the control on the biodegradability determination of the films, which implies that PHB/chitosan films were degraded by the microorganisms. The higher PHB ratio of the films was, the faster biodegradation of the films occurred.

Barrier Property and Morphology of Biaxially Oriented PP/EVOH Blend Film (이축연신 PP/EVOH 블렌드 필름의 차단 성질 및 모폴로지)

  • 여종호;이종훈;박찬석;이기준;남재도
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.820-828
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    • 2000
  • In this study, biaxially oriented film process was used to improve barrier property of polypropylene (PP)/ethylene-vinyl alcohol copolymer (EVOH) blends by inducing a laminar morphology of the dispersed phase in the matrix phase. In order to examine the extent of deformation during melt extrusion process, the rheological properties of the resins were measured and the viscosity ratio of the dispersed phase to the continuous phase was determined. The effects of compatibilizer content, draw ratio, and draw temperature on the oxygen permeability and morphology of biaxially drawn blend films were studied. The laminar morphology of the EVOH phase with a larger area of thinner layer induced by biaxial orientation was found to result in a significant increase in oxygen barrier property of PP/EVOH (85/15) blends by about 10 times relative to the pure PP When both PP-g-MAH and ionomer were used as the compatibilizers, there existed an optimum level of compatibilizer content for obtaining improved barrier properties with a well developed laminar structure. In addition, higher draw ratio and draw temperature were found to be more favorable processing conditions in obtaining higher barrier blends.

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Electrical Conduction Characteristics of XLPE Film According to Electrode Metals (전극금속재질에 따른 XLPE Film의 전기전도특성)

  • Lee, H.G.;Park, Y.G.;Shin, T.S.;Lim, K.J.;Kim, Y.J.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1419-1421
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    • 1998
  • Many kind of factors have influence on the electrical properties of polymer such as mechanical stress, impurity, additives, chemical blend, interfacial phenomena and so on. In this study, we lay emphasis on interfacial phenomena which is important part in insulating design of power cable. The electrical conduction characteristics of XLPE film are investigated as a function of different electrode materials in MIM Interfaces.

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Antimicrobial Activity of a Gelidium corneum - Gelatin Blend Film Containing Fermented Pollen Extract and Its Application in the Packaging of Pork Loins (화분발효물을 함유한 Gelidium corneum - 젤라틴 혼합필름의 항균활성과 돈육의 포장재 적용)

  • Hong, Yun-Hee;Lim, Geum-Ok;Song, Kyung-Bin
    • Food Science of Animal Resources
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    • v.29 no.3
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    • pp.391-395
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    • 2009
  • Gelidium corneum - gelatin (GCG) blend films containing fermented pollen extract (FPE) were prepared and used as a packaging material of pork loins. Water vapor permeability (WVP) of the film containing FPE was better than the control film, and the film's antimicrobial activity against Escherichia coli O157:H7 and Listeria monocytogenes increased with increasing FPE concentration. Addition of 0.15% FPE decreased the populations of Escherichia coli O157:H7 and Listeria monocytogenes by 2.98 and 3.68 Log CFU/g, respectively, compared to the control. Pork loin samples were inoculated with E. coli O157:H7 and L. monocytogenes and packed with the film. The samples packed with the GCG film containing 0.15% FPE had a decrease in the populations of E. coli O157:H7 and L. monocytogenes by 1.49 and 1.01 Log CFU/g after 4 d of storage, respectively, compared to the control. The results suggested that shelf life of the pork loins could be extended by packaging with the GCG film containing 0.15% FPE.

Blend Films of Poly(acrylic acid-co-maleic acid) with Poly(vinyl alcohol) (I) : Thermo-mechanical Properties and Gas Permeability (폴리(비닐 알코올)과 폴리(아크릴산-말레산) 공중합체의 블렌드 필름 (I) : 열적-기계적 성질 및 가스 투과도)

  • Ham Shin-Kyun;Jung Min-Hye;Chang Jin-Hae
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.298-304
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    • 2006
  • Blends of poly (acrylic acid-co-maleic acid)(PAM) with poly (vinyl alcohol)(PVA) were obtained by solution blending. The blends were solvent-on to a film to examine thermo-mechanical properties and gas permeability. The transition temperatures $(T_g\;and\;T_m)$ of the blends remained constant regardless of PAM contents. However, the values of enthalpy changes corresponding to melting transition $({\Delta}H_m)$ and initial degradation temperature $({T_D}^i)$ were decreased with increasing PAM content. The values of ultimate strength and initial modulus gave the maximum value at the 12 wt% PAM then decreased with further increase of PAM content up to 15 wt%. To measure the gas permeability of the PVA/PAM blend films, the PVA blend solutions were coated onto both biaxially oriented propylene (BOPP) and poly (ethylene terephthalate)(PET) films. The oxygen transmission rate $(O_2\;TR)$ permeability values mono- tonically decreased with increasing PAM content. However, moisture vapor transmission rate was not affected by PAM content.

Characterizations of Lyocell and Its Blended Nanocomposite Film: Morphology and Mechanical Property (라이오셀 및 라이오셀 블렌드 나노복합체 필름의 특성 연구 : 모폴로지 및 기계적 성질)

  • Jang, Seo-Won;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.221-227
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    • 2007
  • The mechanical properties and morphologies of lyocell and its blend we compared. Poly (vinyl alcohol) (PVA) was used as a filler in blends with lyocell produced through solution blending. The variations of their properties with polymer matrix filler content are discussed. The ultimate tensile strength of the PVA/lyocell blend is highest for a blend lyocell content of 30 wt%, and decreases as the lyocell content is increased up to 40 wt%. The variations in the initial moduli of the blends with filler content are similar. Lyocell and its blended hybrid films were prepared by the solution intercalation method, using dodecyltriphenylphosphonium-mica ($C_{12}PPh$-Mica) as the organoclay. The variations of the mechanical tensile properties of the hybrids with the organoclay content were examined. These properties were found to be optimal for an organoclay content of up to 5 wt%. However, the mechanical tensile properties of the PVA/Lyocell (w/w=30/70) blended hybrid films were found to decrease linearly with increases in organoclay content from 1 to 5 wt%.

Analysis on Color Shaping the Space of Animated Film Coco (애니메이션영화 <코코> 색상이 공간의 모델링 분석)

  • Yue, Xiao Ling
    • Journal of Korea Entertainment Industry Association
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    • v.13 no.3
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    • pp.343-350
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    • 2019
  • As an important visual element, color in animated films can not only depicts the reality, but also conveys emotion and meanings, which play an important role in shaping the space of animated films. As one of the most outstanding animated films, Coco uses bold and unique color language to shape the film space. It uses the national color to blend the Mexican culture into the story space making it full of Mexican regional and cultural connotation, uses color contrast to shape the physical space, highlighting the three-dimensional and deep sense of the physical space. And also uses color association to create the psychological space, leading audience into the spiritual world of the film. Based on the analysis of the Coco, we an see that when shape the film space of animation, the film maker should give full play to the characteristics and function of color, and apply different color language to shape different space according to the role of the film space, so as to expand and deepen the connotation and expressiveness of film space.

Breakdown Characteristics of LLDPE/EVA mixture film under DC field (직류 전계하 LLDPE/EVA혼합필름의 절연파괴특성)

  • 고시현;김형주;이종필;신현택;이충호;홍진웅
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.65-68
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    • 2000
  • Polyethylene, has long history and is widely used, was researched due to good electrical properties by many authors. But PE under stress has the critical defects of space charge accumulation and tree growth, so various methods such as catalyst, additives and blend to improve these problems have been execute, of which we selected blending method. As in our previous papers we investigated electrical conduction, dielectric and AC dielectric breakdown characteristics, we did DC dielectric breakdown characteristics in this paper. We selected pure LLDPE, pure EVA and LLDPE films mixed with EVA as specimens, which were mixed with the weight percentages of 50, 60, 70 and 80[wt%] to be thin film. DC applying voltage speed was 500[V/sec]. The relation between dielectric breakdown characteristics and the variations of super structure due to mixing was investigated, and especially trap level at amorphous region, threshold energy increment of conductive electron at free volume were considered.

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Strain hardening behavior of linear polymer melts

  • Hong Joung Sook;Ahn Kyung Hyun;Lee Seung Jong
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.213-218
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    • 2004
  • Linear high-density polyethylene (PE) was controlled to induce strain-hardening behavior by introducing a small amount of second component with an anisotropic structure. In order to form an anisotropic structure in the PE matrix, the polymer was extruded through a twin-screw extruder, and the structure was controlled by varying the extrusion conditions. Depending on conditions, the second component formed a film, thread and droplet structure. If the second component was kept rigid, the morphology evolution could be delayed and the second component could maintain its film or thread structure without further relaxation. In par­ticular, the second component of the thread structure made a physical network and gave rise to remarkable strain hardening behavior under high extension. This study suggests a new method that induces strain hard­ening behavior by introducing a physically networked second component into the linear polymer melt. This result is anticipated to improve the processibility of linear polymers especially when extensional flow is dominant, and to contribute to our understanding of strain hardening behavior.