• Title/Summary/Keyword: bis(dithiobenzil)

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Synthesis of Bis(dithiobenzil) Metal Complex and Its Photostability (Bis(dithiobenzil) 금속 화합물의 합성 및 광안정성)

  • Lee, Gun-Dae;Park, Na Yi;Jeon, Seung Yup;Heo, Jin;Son, Dae Hee;Hwang, Tae Kyung;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.433-437
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    • 2007
  • Bis(dithiobenzil) metal complex, used as functional NIR absorbing dye and photostabilizer, was synthesized using bezoin and anisoin as intermediate compounds. And squarylium, a charge generation material, was synthesized to find its photostability effect. The structure of the product was determined by $^1H-NMR$ and FT-IR and the thermal property was analyzed by DSC and TGA. Optical property and photostability were determined by UV-Vis-NIR spectroscopy. High absorbance was obtained in the NIR range and maximum absorbing wavelength was shifted depending on the nature and position of substituent in the bis(dithiobenzil) metal complex. The photofading effect of squarylium decreased by the addition of bis(dithiobenzil) metal complex.