• Title/Summary/Keyword: biotite granite

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Trace Elements and REE Characteristics of the Mesozoic Granites in the Wolchul Mt. Area (월출산 지역에 분포하는 중생대 화강암류에 대한 미량원소와 회토류원소의 특성)

  • Lee, Chang-Shin;Kim, Cheong-Bin
    • Economic and Environmental Geology
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    • v.29 no.3
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    • pp.293-304
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    • 1996
  • The Wolchul Mt. area is composed of a biotite granite and a pink feldspar granite. These granites are distinctly different in terms of their field occurrence, mineralogy, trace element and REE composition, as well as their isotope ages. The biotite granite has higher ferromagnesian elements and lower lithophile trace element abundances than the pink feldspar granite. The biotite granite has high Sr and Ba while the pink feldspar granite has high Rb. On the Rb-Sr-Ba diagram the biotite granite plots as a granodiorite while the pink feldspar granite belongs to a strongly differentiated granite. The ${\Sigma}$ LREE/ ${\Sigma}$ REE for the biotite granite is 0.95 and for the pink feldspar granite it is 0.88. The ratio shows a steep decrese in LREE while HREE is essentially constant. Based on the Eu/Sm, $[La/Lu]_{cN}$ and low Eu(-), the biotite granite has quartz diorite to granodiorite composition while the pink feldspar granite, with a relatively high Eu(-) anomaly, falls into the monzo- to syenogranite classification. The silica vs. trace element diagrams for the two granites indicate that the biotite granite could have formed near to a continental margin or volcanic island setting environment while the pink feldspar granite formed within a continental plate or as result of plate collision. The biotite granite has a U-Pb zircon age of 175 Ma, i.e. Middle Jurassic. The pink feldspar granite is younger, it has a K-Ar orthoclase age $93.6{\pm}1.5$ Ma which is Late Cretaceous age.

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Petrochemistry of Mesozoic Granites in Wolchulsan Area (월출산지역에 분포하는 중생대 화강암류에 대한 암석화학적 연구)

  • Kim, Cheong-Bin;Yoon, Chung-Han;Kim, Jeong-Taek;Park, Jay-Bong;Kang, Sang-Won;Kim, Dong-Ju
    • Economic and Environmental Geology
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    • v.27 no.4
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    • pp.375-385
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    • 1994
  • The studied area is composed of Precambrian gneiss complex, middle Jurassic biotite granite, late Cretaceour sediments, volcanics and pink feldspar granite. Characteristic minerals of the biotite granite is plagioclase and hornblende whereas the pink feldspar granite is pink feldspar (perthite) and quartz. Plagioclase compositions of the biotite granite and the pink feldspar granite are oligoclase to calcic andesine ($An_{18-44}$) and sodic albite ($An_{0.5-5.0}$), respectively. In the variation diagrams of the Harker and normative Q-Or-Pl diagram, the biotite granite belongs to the category from granodiorite to granite, the pink feldspar granite from nomal to late granite. The values of D.I. L.I. and alkalinity of the pink feldspar granite are higher than those of the biotite granite. While CaO is enriched in the biotite granite, $K_2O$ is enriched in the pink feldspar granite. The ratio of $K_2O/Na_2O$ which indicates the relative ratio of alkali is 1.06 in the pink feldspar granite, and 0.86 in the biotite granite. In A-M-F and N-C-K diagrams both these granites are plotted in peraluminus granite ($Al_2O_3$>$Na_2O+K_2O+CaO$) region, assigned to calc alkaline series and alkaline series respectively. Put into the form of A-C-F diagram, the biotite granite falls under I-type, and the pink feldspar granite S-type. On the base of whole rock ratios of $Fe^{+3}/Fe^{+2}+Fe^{+3}$ and $^{87}Sr/^{86}Sr$ for the granites in studied area, the biotite granite indicates ilmenite series (0.26) and S-type and/or contaminated I-type ($0.72020{\pm}0.00050$), the pink feldspar granite magnetite series (0.44) and I-type ($0.70826{\pm}0.00020$).

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Geochronology and Petrochemistry of Foliated Granites between Damyang and Jinan (담양(潭陽)-진안(鎭安)사이에 분포(分布)하는 엽리상화강암류(葉理狀花崗岩類)에 대(對)한 지질시대(地質時代)와 성인(成因)에 관(關)한 연구(硏究))

  • Kim, Cheong Bin;Kim, Yong Jun
    • Economic and Environmental Geology
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    • v.23 no.2
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    • pp.233-244
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    • 1990
  • Plutons of Damyang-Jinan area consist of gray feldspar granite gneiss, biotite granite gneiss, foliated granites, Namweon granites, gabbro, biotite granite and Ogangri granite in term of mineralogical, texture and field evidence. From Isotope data of study area, chronological order of the Plutons are the Pre-cambrian gray feldspar granite gneiss(Ar39-Ar40, hornblende, $1998.4{\pm}8.3Ma$), middle to late Triassic Daegang foliated granite(Rb/Sr, whole rock, $288{\pm}4Ma$), foliated hornblende biotite granodiorite(K/Ar, hornblende, $198.7{\pm}9.9Ma$), Sunchang foliated granodiorite(Rb/Sr, whole rock, $222{\pm}4Ma$), foliated two mica granite, Samori foliated granite and Namweon granite(Rb/Sr, whole rock, $211{\pm}3Ma$: K/Ar, hornblende, $203{\pm}10.2Ma$), middle Jurassic Gabbro(K/Ar, hornblende, $180.7{\pm}9MA$) and biotite granite, and Cretaceous Ogangri granite. According to variations diagrams of $Al_2O_3$ versus normative PI(100 An)/(Ab+An), Daegang foliated granite is plotted on tholeiitic series, and other foliated granites on calc alkaline rock series which are consider to be formed by magmatism at continental margin and island arc region. And alkalinity versus $SiO_2$ shows that Daegang folited granite and Samori foliated granite are correspond to alkaline region, foliated hornblende biotite granodiorite and Sunchang foliated granodiorite to calc alkaline region, and foliated two mica granite to both regions. According to ACF diagrams, Daegang and Samori foliated granites are plotted on S-type. Foliated hornblende biotite granodiorite and Sunchang foliated granodiorite on I-type, and foliated two mica granite on both type. Foliated granites are a series of differentiated products from cogenetic magma, and effected under ductile sheared zone. Characteristic foliation of foliated granites are considered to be generated by dextral strike slip faulting and ductile shearing.

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Contrasting TiO$_2$/MgO ratios in the Namwon granitic complex

  • Kwon, S.T.;Hong, S.S.
    • The Journal of the Petrological Society of Korea
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    • v.2 no.1
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    • pp.41-52
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    • 1993
  • We report adventages of employing MgO as a differentiation index for the Namwon granitic complex. It is shown to be much more sensitive than the usual Harker index. The complex can be divided into two groups on the basis of $TiO_2$/MgO ratio. The low $TiO_2$/MgO group consists of hornblende biotite tonalite-granodiorite, porphyritic hornblende biotite granodiorite (PHBGd) and part of biotite granite (loBG). PHBGd shows its own distinct variation in the low group. This group is characterized in most cases by the presence of hornblende, even if it occurs as a trace amount. The high $TiO_2$/MgO group consists of part of biotite granite (hiBG) and two mica granite. The major element differences between rock types are also apparent in biotite chemistry. These chemical data indicate that at least two distinct origins of magma are rquired for the complex. Two kinds of biotite granite revealed in this study show distinct geographic distribution, suggesting that a new geologic map should be made.

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Petrology of Granitic Complex Distributed in the Woosanbong area, northwestern part of Yuseong (유성(儒城) 서북부(西北部) 우산봉(雨傘峰) 일대(一帶)에 분포(分布)하는 화강암(花崗巖) 복합체(複合體)의 암석학적(岩石學的) 연구(硏究))

  • Kim, Seungho;Lee, Dai Sung
    • Economic and Environmental Geology
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    • v.14 no.3
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    • pp.123-142
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    • 1981
  • Granitic complex in the Woosanbong area is composed of schistose granite, two-mica granite, biotite granite, porphyritic granite and pink feldspar granite in order of intrusion. In their boundary aspects, the gradational change between porphyritic granite and pink feldspar granite is observed in field relations. All the granites of the complex are classified to quartz monzonite by the modal compositions following Bateman's classification (1961) with the exception of pink feldspar granite which belongs to granite according to the petrographical classification. The first three granites are characterized by highly development of vein and/or lens-like pegmatites in their bodies, and two others contain green hornblende uniquely. These leucocratic two-mica granite shows an unusual character in ratio of muscovite to biotite 1: 0.7 to 1:13, and contains dominantly microcline. The content of muscovite varies in places in the field. Under the polarizing microscope it is revealed that the muscovite flakes occur as the products altered from biotite partly or completely, and it usually associates with chlorite flakes nearby. These features, therefore, suggests that biotite probably has been altered to muscovite and chlorite by hydration during deuteric processes. At the same stage, sericitization of plagioclase by the hydrolytic decomposition, and transformation of orthoclase to microcline may be taken place. Accordingly, it is obviously permissible to consider the two-mica granite as a kind of 'apo-granite' by deuteric alterations during the consolidation of magma.

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Mineralogical Characteristics and Formation Environment of Kaolin Minerals in the Weathering of Granitoids: Weathering of Biotite in Palgongsan Granite (팔공산 화강암내 흑운모의 풍화과정에서 생성되는 고령토광물들의 광물학적 특성 및 생성 환경)

  • 정기영
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.97-105
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    • 1998
  • Weathering of biotite in Palgonsan granite was studied by using X-ray diffraction, optical microscopy, scanning electron microscopy, and electron probe micro analysis. Biotite altered to biotite/vermiculite regular mixed layer mineral (B/V) in the early stage of weathering. Although partially replaced by kaolinite with the progress of weathering. B/V is the major weathering product of biotite throughout the profile. During the formation of B/V, Mg, Fe and K are removed from a biotite layer to form a vermiculite layer by about 28%, 44% and 88%, respectively, whereas the Ti content is not changed. Considerable volume increase after the kaolinitization of B/V suggests that Al and Si are largely introduced from the external weathering solution. The silicate lattice templet of a weathering biotite facilitated the nucleation and growth of kaolinite. In the Palgongsan granite weathering profile, plagioclase weathered mostly into halloysite whereas biotite greatly contributes to the kaolinite crystallization though its small content in fresh rock.

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Characterization of Weathering Process in Biotite Gneiss and Granite, Ganghwa Island (강화도 선두리 지역 흑운모 편마암과 화강암에 대한 풍화 특성)

  • Jang Yun-Deuk;Kim Jeong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.1 s.47
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    • pp.39-48
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    • 2006
  • X-ray diffaction and chemical analysis were used for mineralogical characteristics of weathering grade of granite and biotite gneiss. Granite is composed mainly of quartz, albite, and minor K-feldspar and biotite gneiss is biotite, quartz, albite. Illite and kaolinite increased in granite, and vermiculite and halloysite in biotite gneiss as increasing weathering process. The percentages of $Al{2}O_{3}$ increase but that of CaO, $Na_{2}O,\;K_{2}O$ decrease as the weathering process. $Fe_{2}O_{3}$ different from granite and biotite gneiss.

선캠브리아 홍제사 화강암의 진화과정(한국 북동부지역의 원생대의 화성활동과 변성작용)

  • 김정민;조문섭
    • The Journal of the Petrological Society of Korea
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    • v.3 no.1
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    • pp.76-93
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    • 1994
  • The Precambrian Hongjesa granite is lithologically zoned from biotite granite in central part to biotite-muscovite granite towards the margin. The X_{Fe}$ (=Fe/(Fe+Mg)) value and the aluminum saturation index of biotite systematically vary as a function of mineral assemblage, and are positively related with those of bulk rock. This relationship as well as the lithological zoning are attributed to the fractional crystallization of the Hongjesa granitic magma. The trace element data corroborate that biotite-muscovite granite is more fractionated than biotite granite. The evolution of the Hongjesa granite is elucidated by using the AFM liquidus topology, where A=$Al_2O_3-CaO-Na_2O-K_2O$; F=FeO+MnO; and M=MgO. At an early magmatic stage where biotite is the only ferromagnesian mineral to crystallize, the X_{Fe}$ value and the alumina content of granitic magma continuously increase.. Muscovite subsequently crystallizes with biotite along the biotitemuscovite cotectic curve where biotite-muscovite granite forms. Local enrichments in Mn and B further crystallize garnet and tourmaline, respectively. The unique zonal pattern characterized by the occurrence of the evolved biotite-muscovite granite at the margin may be accounted for by the passive stoping during the emplacement of the Hongjesa granite. This emplacement may have occurred in continental collision environment, according to the tectonic discrimination diagram using major element chemistry.

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Petrochemical Study of Igneous Rocks Occurring in the Northwestern Part of Keumsan Area, Chungnam-do (충남 금산군 서북부에 분포하는 화성암류에 대한 암석화학적 연구)

  • Kim, Won-Sa;Min, Kyoung-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.99-109
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    • 2006
  • Igneous rocks occurring in the northwesern part of Keumsan area, Chungcheongnam-do were studied petrogeochemically. The geology of this area is composed mainly of the Precambrian biotite gneiss, age-unknown Ogchon supergroup, Jurassic biotite granite, and Cretaceous volcanic rocks, pink feldspar granite and quartz porphyry. The biotite granite is gradually changes to leucocratic nature by going from center to periphery of the rock mass. It shows variation, with distance from the center, in chemical components: $SiO_2,\;Na_2O\;and\;K_2O$ increase, whereas $Fe_2O_3,\;CaO,\;P_2O_5,\;MgO,\;and\;TiO_2$ decrease. Based on geochemical data, the biotite granite and quartz porphyry belong to subalkaline series and I-type. They show calc-alkaline differentiation trend. The biotite granite shows little negative Eu-anomaly pattern, whereas quartz porphyry show marked negative Eu-anomaly pattern, indicating that quartz porphyry was evolved further, when compared with biotite granite.

Geochemical Study on Foliated Granites in the Damyang-Jinan area (담양(潭陽)-진안(鎭安)사이에 분포(分布)하는 엽리상화강암류(葉理狀花崗岩類)에 대(對)한 암석화학적(岩石化學的) 연구(硏究))

  • Kim, Cheong-Bin;Kim, Yong-Jun;Hong, Sei-Sun
    • Economic and Environmental Geology
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    • v.23 no.1
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    • pp.87-104
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    • 1990
  • Foliated granites between Damyang and Jinan are subdivided into Daegang foliated granite, Foliated hornblende biotite granodiorite, Sunchang foliated granodiorite, Foliated two mica granite and Samori foliated granite by mineral and texture. From EPMA data of the foliated granites following results are achieved. Composition of plagioclase are correspond to andesine, oligoclase and albite in Foliated hornblende biotite granodiorite, Sunchang foliated granodiorite and other foliated granites, respectively. And amphiboles are calcic hornblende in Foliated hornblende biotite granodiorite, and riebeckite in Daegang foliated granite. In differentiation index(D. I.) and Larsen index(L. I.), Daegang foliated granite, Foliated two mica granite and Samori foliated granite which belong to granite are 83.12-95.54 and 25.86-29.05 and Foliated hornblende biotite granodiorite and Sunchang foliated granodiorite of diorite to granodiorite are 54.99-78.54(D. I.) and 6.48-21.01(L. I.). Harker and AMF diagrams plotted from foliated granites show that the granites are product of calc alkali rock series orignated from co-magma. Characteristic foliation of foliated granites fromed by ductile deformation at deep zone of dextral strike slip fault. Foliated granites are considered as a series of differentiated product of Triassic Igneous activity of Songrim disturbance. According to REE, (La/Lu) and Eu/Sm, Foliated hornblende biotite granodiorite and Sunchang foliated granodiorite are correspond to granodiorite, and other foliated granites are monzo-and syeno-granite. Foliated granites having 0.20-0.01 of Em/Sm ratio are plutons emplaced by the tectonic setting in continents and continental margin.

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