• Polymer(Korea)
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• v.24 no.3
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• pp.358-365
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• 2000

Miscibility itnd thermal behavior of blends of synthetic biodegradable aliphatic polyester (Bionolle) with poly(epichlorohydrin) (PECH) were investigated by a differential scanning calorimetry (DSC), a dynamic mechanical thermal analyzer (DMTA) and a rotational rheometer. Observed both single glass transition temperatures from the DSC in agreement with the Fox equation and single T$_{g}$ changes as a function of composition from the DMTA indicate that these blend mixtures are miscible. In addition, the miscibility of this blend system was also observed from the single curve of the Cole-Cole Plot of log G′($\omega$) vs. log C"($\omega$) from the dynamic test using a rotational rheometer. This was further verified from the cryogenically fractured surface of BDP/PECH blends by scanning electron microscopy.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.377-385
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• 1992

• Clean Technology
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• v.8 no.4
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• pp.223-228
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• 2002

The biodegradable Properties of various polyester resins with different chemical structures have been studied by applying the controlled compost test and soil burial test. Celluose was taken as a fully biodegradable reference resin while PVC and PE were empolyed as non-biodegradable reference chains or ester group were rather easily degraded by hydrolase, meanwhile copolymer type polyesters which contain aromatic rings showed relatively low biodegradability. According to the results from controlled compost test, cellulose(the positive reference) showed 70.6% degradation after 45 days, whereas synthetic poly(butylene adipate-co-succinate), poly(butylene succinate), poly(butylene adipate-co-succinate-co-terephthalate) showed 44.0%, 32.0% and 23.4% degradation respectively. In this regard, it was concluded that biodegradable properties of polymers are largely dependant on the chemical structures constituting the polymers.

• Polymer Science and Technology
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• v.5 no.1
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• pp.13-18
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• 1994

• Proceedings of the Korean Fiber Society Conference
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• 2001.04a
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• pp.27-29
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• 2001

• KSBB Journal
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• v.27 no.1
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• pp.51-56
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• 2012

This research was to investigate the polyester preparation using waste ethylene glycol (EG) generated from the wastepaper pretreatment process. Waste EG was obtained from using EG five times repeatedly in the pretreatment of wastepaper. The hydroxyl value of the waste EG was 441 mg KOH/g and its composition was 0.68% cellulose, 6.5% hemicellulose, 6.1% lignin, and 86.7% EG. Maleic acid was used as carboxylic acid. The effect of reaction temperature and time except carboxyl group/hydroxyl group ratio on the crosslinkage of the prepared polyester was marginal. Citric acid, lithium hydroxide and dicumyl peroxide were used as additive or catalyst to enhance the crosslinkage of polyester. Among them, 10% of citric acid was found to be most effective. The crosslinkage was 86% when the polyester was prepared at an optimum condition such as $130^{\circ}C$ and 15 minutes, 1.5 of C/H ratio, and 10% of citric acid, and its insoluble percentage in boiling water for 6 hours was 47%. The weight loss of the prepared polyester was approximately 40% when it was buried in damp soil for 5 months, indicating that it is readily biodegradable. This results can provide some information for future development of wastepaper pretreatment by organic solvent.

• Korean Journal of Food Science and Technology
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• v.47 no.2
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• pp.224-232
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• 2015

The effects of cold plasma (CP) treatments on the physicochemical and biodegradable properties of a corn biomass-containing polyester (CBPE) film were studied. The CBPE film was treated with CP generated by $N_2$, $O_2$, He, Ar, or dry air at 400-900 W and 667 Pa for 10-40 min. The glass transition temperature of the CBPE film ($-30.2--28.6^{\circ}C$) was not affected by the CP treatment, while the elastic modulus and water vapor permeability decreased (p<0.05). The ink printability was improved by the treatment and the improved printability was maintained during storage for 56 days at room temperature. Roughness of the film increased after treatments and the level of roughness appeared to increase during storage. Heat and microbial biodegradability of the CBPE film was improved by the air-CP treatment (p<0.05). These results have demonstrated the potential of applying CP treatments to improve the flexibility, printability, and biodegradability of CBPE films.

• Proceedings of the Korean Fiber Society Conference
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• 1997.04a
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• pp.328-332
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• 1997

Hot stretching focused on the improvement of properties of poly(L-lactic acid) fiber. Some aliphatic polyesters are biodegradable under microbial attack and the new unique applications are expected. Generally, these materials have a somewhat low melting temperature and low mechanical properties compared with the aromatic polyesters. In this study, melt-spinning of poly(L-lactic acid) was conducted. We investigated effects of the stretching and the molecular orientation of aliphatic polyester fibers on the change of fine-structure. Glass transition temperature, molecular orientation and crystallinity increased according to the increase of stretching ratio.

• Journal of the Society of Disaster Information
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• v.3 no.2
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• pp.23-35
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• 2007

Recently, for places with poor vegetating environment, such as slopes made of weathered soil or rocks, erosion tranquilizers, coverings and composite fertilizers have been mixed with seeds and sprinkled onto soil. Also, these plant revegetations have been mixed with nets and used to strengthen cohesion. However, this technique often obstructed plant growth and caused pollution because of not decomposing nets. This study has tested influence on plant revegetation B for slope of weathered soil and rocks and decomposition of naturally decomposing polyester filament yarn. In result, it was showed that plant revegetation B does not harm environment in case of applying it to soil slope and enhance protection capacity of slopes as time goes by. Also, naturally decomposing polyester filament yam was analyzed its physical properties with the passage of time and was known that naturally decomposing polyester filament yarn transformed into a structure easy to decompose by hardening. Thus it is considered that the revegetation method used this study was very effective method for plant establishment and stability of slope.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.48 no.1
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• pp.1-7
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• 2003

In spite water direct seeding cultivation of rice has advantages in terms of laborsaving and cost-down, it demonstrates uneven seedling establishment and difficult weed management. To select an applicable mat for mulching system of water seeded rice, weed occurrence, growth and yield performances of rice, and soil temperature were evaluated in several kinds of biodegradable mulching material. Field studies were conducted at the experimental farm of National Crop Experiment Station in 1999 and 2000. Among the mats tested in 1999, Safer-mat had the greatest effect on inhibiting weed occurrence and Lawn-mat demonstrated the least efficacy of weed control (EWC) value. In Safer-mat treatment, Ludwigia prostrata was the dominant weed species but Echinochloa crus-galli was not observed. Different kinds of mulching material from the mats studied in 1999 were tested in 2000. Biodegradable polyester (PES) coated on the recycled paper for newspaper press (RP) treatments showed similar or higher EWC values than non-mulched broadcast seed rice with 2 times of herbicide application (BC-herbicide) and Safer-mat that was the most effective mat on preventing weed appearance in 1999. Immediately after mat mulching on the surface of paddy soil, five pregerminated rice seeds were manually sown in each 3cm-hole formerly punctured at 30${\times}$14 cm spacing in 2000. All the 3 kinds of mulching material tested in 2000 had better seedling stand than BC-herbicide treatment. Rice yield in PES coated with 10 thickness on RP (PES10 $\mu\textrm{m}$＋RP) was a little higher than in BC-herbicide treatment but the former produced less panicles in unit land area than the latter. PES10 $\mu\textrm{m}$＋RP demonstrated a great effect on raising soil surface temperature than non-mulching treatment throughout the period of seedling establishment.