• Title/Summary/Keyword: bio-sulfur

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Effects of different sulfur ion concentration in nutrient solution and light source on glucosinolate contents in kale sprouts (Brassica oleracea var. acephala)

  • Park, Ye-Jin;Chun, Jin-Hyuk;Woo, Hyunnyung;Maruyama-Nakashita, Akiko;Kim, Sun-Ju
    • Korean Journal of Agricultural Science
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    • v.44 no.2
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    • pp.261-271
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    • 2017
  • The aim of this study was to investigate the amount of glucosinolates (GSLs) in kale sprouts (Brassica oleracea L. var. acephala) ('TBC') according to different concentrations of sulfur ions in sprout's nutrient solutions (0.0, 0.5, 1.0, and 2.0 mM) and to different light sources [Fluorescent lamp, Red, Blue, and Mix (R+B) LED]. Kale sprouts were cultivated in a growth chamber for 13 days in sulfur solutions. Kale sprouts were treated with fluorescent lamp and LED light sources for 5 days, from eight days after sowing to harvest. Amount of seven types of GSLs (progoitrin, sinigrin, 4-hydroxyglucobrassicin, glucobrassicin, 4-methoxyglucobrassicin, gluconasturtiin, and neoglucobrassicin) were measured in kale sprouts after harvest. The total GSL content was influenced by different sulfur solution concentration, and it was the highest at S 0.5 mM ($172.54{\mu}mol{\cdot}g^{-1}DW$) and the lowest at S 2.0 mM ($163.09{\mu}mol{\cdot}g^{-1}DW$). The GSL content was influenced by different light source, and it was the highest with Red LED ($159.23{\mu}mol{\cdot}g^{-1}DW$) and the lowest with Blue LED ($147.57{\mu}mol{\cdot}g^{-1}DW$). As the sulfur solution concentration increased under all light source, progoitrin and sinigrin contents tended to decrease while glucobrassicin content showed an upward tendency for all of the light sources. The content of glucobrassicin was higher than that of progitrin when treated with sulfur solutions for all LED light sources. Sinigrin, which has excellent anti-cancer effects, showed the highest rate (92.2%) among all the GSLs, under all of the light sources.

Study on Performance and An Exhaust Emission by Bio-Diesel Deterioration and Engine Load Rate at Heavy-Duty Diesel Engine (대형디젤기관에서 바이오디젤 열화와 엔진부하에 따른 배출가스특성 및 성능에 관한 연구)

  • Park, Man-Jae;Kim, Mi-Soo
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.3
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    • pp.56-63
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    • 2007
  • Modern diesel vehicle has to comply with the EURO IV, V regulation with low level of particulate matter and smoke emission Moreover, emission standards of each countries are becoming stringent in advanced countries such as USA and Europe. Because Bio-diesel is similar to diesel fuel, it is essential to judge the environmental and health effects deriving from the use of Bio-diesel in diesel engine. The deterioration characteristics of emission in accordance with aging vehicles must be regulated for Bio-diesel. Therefore, under 1200 driving hours, 220,000km driving distance condition and full load, the deterioration characteristics of emission were estimated. We could reduce sulfur contents of fuel, particulate matter and smoke emission by using Bio-diesel and conform the influence of engine performance, emission, and fuel consumption by Bio-diesel deterioration

Effects of Sulfur Substitution on Chemical Bonding Nature and Electrochemical Performance of Layered LiMn0.9Cr0.1O2-xSx

  • Lim, Seung-Tae;Park, Dae-Hoon;Lee, Sun-Hee;Hwang, Seong-Ju;Yoon, Young-Soo;Kang, Seong-Gu
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1310-1314
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    • 2006
  • Sulfur-substituted $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$ $(0\;\leq\;x\;\leq\;0.1)$ layered oxides have been prepared by solid state reaction under inert atmosphere. From powder X-ray diffraction analyses, all the present lithium manganates were found to be crystallized with monoclinic-layered structure. Electrochemical measurements clearly demonstrated that, in comparison with the pristine $LiMn_{0.9}Cr_{0.1}O_2$, the sulfur-substituted derivatives exhibit smaller discharge capacities for the entire cycle range but the recovery of discharge capacity after the initial several cycles becomes faster upon sulfur substitution. The effect of the sulfur substitution on the chemical bonding nature of $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$has been investigated using X-ray absorption spectroscopic (XAS) analyses at Mn and Cr K-edges. According to Mn K-edge XAS results, the trivalent oxidation state of manganese ion remains unchanged before and after the substitution whereas the local structure around manganese ions becomes more distorted with increasing the substitution rate of sulfur. On the other hand, the replacement of oxygen with sulfur has negligible influence on the local atomic arrangement around chromium ions, which is surely due to the high octahedral stabilization energy of $Cr^{+III} $ ions. Based on the present experimental findings, we have suggested that the decrease of discharge capacity upon sulfur substitution is ascribable to the enhanced structural distortion of $MnO_6$ octahedra and/or to the formation of covalent Li-S bonds, and the accompanying improvement of cyclability would be related to the depression of Mn migration and/or to the pillaring effect of larger sulfur anion.

A Study on Performance and Exhaust Emission with Bio-Diesel and ULSD at Heavy-Duty Diesel Engine (대형디젤기관에서 바이오디젤과 초저유황경유 사용에 의한 성능 및 배출가스에 미치는 영향에 관한 연구)

  • 박만재
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.12 no.6
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    • pp.97-103
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    • 2003
  • Currently, due to serious increase of pollution scones, lots of technology has been involved to reduce exhaust gas in diesel engine. But the amounts of exhaust gas can not be decreased somehow due to the increase of diesel vehicles. Moreover, emission standards of each counties are being stringent in advanced countries such as USA and Europe. In the near future, sulfur contents in fuel must be essentially reduced f3r health and environment because sulfur can basically reduce exhaust gas. Therefore, when will be applied to Bio-diesel and ULSD, they could reduce sulfur contents of fuel without aftertreatment and might conform the influence of engine performance, emission, smoke and fuel consumption.

Age-Related Changes in Sulfur Amino Acid Metabolism in Male C57BL/6 Mice

  • Jeon, Jang Su;Oh, Jeong-Ja;Kwak, Hui Chan;Yun, Hwi-yeol;Kim, Hyoung Chin;Kim, Young-Mi;Oh, Soo Jin;Kim, Sang Kyum
    • Biomolecules & Therapeutics
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    • v.26 no.2
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    • pp.167-174
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    • 2018
  • Alterations in sulfur amino acid metabolism are associated with an increased risk of a number of common late-life diseases, which raises the possibility that metabolism of sulfur amino acids may change with age. The present study was conducted to understand the age-related changes in hepatic metabolism of sulfur amino acids in 2-, 6-, 18- and 30-month-old male C57BL/6 mice. For this purpose, metabolite profiling of sulfur amino acids from methionine to taurine or glutathione (GSH) was performed. The levels of sulfur amino acids and their metabolites were not significantly different among 2-, 6- and 18-month-old mice, except for plasma GSH and hepatic homocysteine. Plasma total GSH and hepatic total homocysteine levels were significantly higher in 2-month-old mice than those in the other age groups. In contrast, 30-month-old mice exhibited increased hepatic methionine and cysteine, compared with all other groups, but decreased hepatic S-adenosylmethionine (SAM), S-adenosylhomocysteine and homocysteine, relative to 2-month-old mice. No differences in hepatic reduced GSH, GSH disulfide, or taurine were observed. The hepatic changes in homocysteine and cysteine may be attributed to upregulation of cystathionine ${\beta}-synthase$ and down-regulation of ${\gamma}-glutamylcysteine$ ligase in the aged mice. The elevation of hepatic cysteine levels may be involved in the maintenance of hepatic GSH levels. The opposite changes of methionine and SAM suggest that the regulatory role of SAM in hepatic sulfur amino acid metabolism may be impaired in 30-month-old mice.

MATHEMATICAL MODEL OF SULFUR UTILIZING AUTOTROPHIC DENITRIFICATION IN AN UP-FLOW PACKED-BED REACTOR BASED ON BIOMASS DISTRIBUTION

  • Park, Woo-Shin;Ahn, Yoeng-Hee;Jung, Kyung-Ja;Tatavarty, Rameshwar;Kim, In-S.
    • Environmental Engineering Research
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    • v.10 no.4
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    • pp.191-198
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    • 2005
  • A novel technology for the removal of nitrogen from wastewater, an autotrophic denitrification process with sulfur particles, has been developed. A respirometer was employed to monitor the nitrogen gas produced in the reactor, while 4',6-diamidino-2-phenylindole staining was employed to investigate the biomass distribution in terms of cell number according to the reactor height. From the respirometric monitoring, the denitrification reaction was defined as a first order reaction. The reactor was divided into 7 sections and biomass was analyzed in each section where cell number was ranged from $4.8\;{\times}\;10^6\;to\;8.7\;{\times}\;10^7$ cells/g dry weight of sulfur. Cells placed mostly in the lower layer ( < 10 cm of height). A function for biomass distribution was obtained with non-linear regression. Then a mathematical model has been developed by combining a plug-flow model with the biomass distribution function. The model could make a vertical profile of the up-flow packed-bed reactor resulting in a reasonable comparison with measured nitrate concentration with 5% of error range.

A Study on the Relationship Between Oral Malodor and Periodontal Disease (구취와 치주질환의 상관성에 관한 연구)

  • Kwon, Jin-Hee;Chang, Moon-Taek;Ryu, Sung-Hoon;Kim, Hyung-Seop
    • Journal of Periodontal and Implant Science
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    • v.30 no.1
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    • pp.203-212
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    • 2000
  • Putrefactive activity within the oral cavity is the principal cause of halitosis. The most common intraoral sites of oral malodor production are tongue, interdental and subgingival areas. The other foci may include faulty restorations, sites of food impaction and abscesses. Periodontal disease frequently involves pathological oral malodor, which is caused mainly by volatile sulfur compounds(VSC), such as hydrogen sulfide, methyl mercaptan, and dimethyl sulfide. The purpose of this study is to evaluate the association between oral malodor and periodontal status. Volatile sulfur compounds in mouth air were estimated by portable sulfide monitor($Halimeter^{TM}$). The results were as follows : 1. The levels of volatile sulfur compounds were significantly greater in a periodontitis group than in a control group(P<0.01). The amounts of VSC in mouth air from patients with periodontal involvement were four times greater than those of the control group. 2. The significant positive correlation was found between VSC concentrations and the number of pocket depth above 4mm(P<0.01), but correlation between VSC concentrations and plaque score was not statistically significant(P>0.05). 3. In the periodontitis group, VSC concentrations of pre-treatment significantly decreased after scaling and root planing(P<0.01). 4. No statistically significant correlation was found between VSC concentrations and sex / age in the periodontitis group. The above results indicate that periodontal disease may play a role as an important factor of oral malodor and deep periodontal pockets are a source of volatile sulfur compounds.

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Dietary Sulfur Amino Acids Can Spare Taurine in Rock Bream Oplegnathus fasciatus

  • Ferreira, Fernando Magalhaes;Yun, Hyeonho;Park, Youngjin;Lee, Seunghan;Park, Gunhyun;Bai, Sungchul C.
    • Fisheries and Aquatic Sciences
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    • v.18 no.3
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    • pp.249-255
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    • 2015
  • An 8 week feeding trial was conducted to evaluate whether methionine and cysteine would effectively spare taurine supplementation on growth performance in juvenile rock bream Oplegnathus fasciatus. Triplicate groups of 25 fish averaging $2.74{\pm}0.04g$ ($mean{\pm}SD$) were fed one of the experimental diets. Five experimental diets including a fish meal based control diet were prepared by adding sulfur amino acid at fixed level of 1.0% and taurine at graded levels of 0%, 0.25%, 0.5% and 1.0% ($S+Tau_0$, $S+Tau_{0.25}$, $S+Tau_{0.5}$ and $S+Tau_{1.0}$, respectively). After the feeding trial, growth performance of fish fed the $S+Tau_{0.25}$, $S+Tau_{0.5}$ and $S+Tau_{1.0}$ diets were significantly higher (P < 0.05) than those of fish fed the Control diet. ANOVA test suggested that when sulfur amino acid were supplemented to the diets, the optimum taurine supplementation level could be 0.25% in the diet, and broken line analysis of weight gain indicated a level of 0.33%, for positive effects on growth and feed utilization. Fish whole-body protein content and taurine concentration steadily increased with the increase of dietary level in the presence of sulfur amino acid in the diets. On the other hand, whole-body lipid content significantly decreased with the incremental levels of dietary taurine. In conclusion, the results of the present study clearly indicated that dietary supplementation of methionine and cysteine at a level of 1% could spare 0.25 to 0.33% of taurine in juvenile O. fasciatus diets.

Multiple Applications of Lime Sulfur for Fruit Thinning of 'Fuji' and 'Hongro' Apple Trees (석회유황합제의 다중처리에 따른 '후지' 및 '홍로' 사과의 적과 효과)

  • Chun, Ik-Jo;Zheng, Wei-Wei;Choi, Cheol;Song, Yang-Yik;Kwang, In-Kye;Hirst, Peter
    • Journal of Bio-Environment Control
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    • v.21 no.4
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    • pp.445-451
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    • 2012
  • The thinning effects of lime sulfur either alone or combined with fish oil on two apple cultivars 'Fuji'/M.9 and 'Hongro'/M.9 were investigated during two consecutive seasons. Either 1% or 2% lime sulfur at full bloom decreased the amounts of both terminal and axillary fruits compared with unsprayed 'Fuji' control trees in the first year. However, 1% or 2% lime sulfur did not decrease terminal fruit set in the second year. Only, triple applications of 1% lime sulfur significantly reduced the number of terminal and axillary fruits in both years. Multiple application of 1% lime sulfur was the most effective in thinning of 'Hongro'. In the first year, double or triple applications of 1% lime sulfur was effective in thinning terminal or axillary fruit, but one time applications of 1% or 2% lime sulfur was not reduced axillary fruit in 'Hongro' apple trees. In the second season, all treatments reduced terminal or axillary fruit in 'Hongro' clusters, except single application of 1% lime sulfur. Fish oil did not always improve the thinning effects of lime sulfur in 'Fuji' or 'Hongro' apple trees. None of treatments caused significant russeting in the harvested fruits. Most of thinning treatments had little effect on 'Fuji' or 'Hongro' fruit quality in terms of fruit weight, firmness, soluble solids concentration or titratable acidity.