• Journal of Korean Society of Environmental Engineers
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• v.39 no.8
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• pp.489-493
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• 2017

Microbial fuel cells (MFC) are bio-electrochemical processes that can convert various organic materials present in wastewater into electrical energy. For scaling-up and practical application of MFC, it is necessary to investigate the effect of anode size, electrode distance, and total area of anode on substrate degradation. Spaced electrode assembly (SPA) type microbial fuel cell with multiple anodes treating domestic wastewater was used for simulation. According to computer simulation results, the shorter the distance between electrodes than the size of single electrode, the faster the substrate degradation rate. Particularly, when the total area of the anode is large, the substrate decomposition is the fastest. In this study, it was found that the size of the anode and the distance between the electrodes as well as the cathode electrode, which is known as the rate-limiting step in the design of the microbial fuel cell process, are also important factors influencing the substrate degradation rate.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.297-301
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• 2012

Microbial fuel cell (MFC) is the major of bio-electrochemical system which can convert biomass spontaneously into electricity through the metabolic activity of the microorganisms. In this study, we used an activated sludge as a microbial inoculum and then investigated the feasibility of using dairy wastewater as a possible substrate for generating electricity in MFC. To examine the performance of MFC as power generator, the characteristics on cell potentials, power density, cyclic voltammetric analysis and sustainable power estimation were evaluated for dairy wastewater. The maximum power density of $40\;mW/m^2$was achieved when the dairy wastewater containing 2650 mg/L COD was used, leading to the removal of 88% of the COD. The results from this study demonstrate the feasibility of using MFC technology to generate electricity while simultaneously treating dairy wastewater effectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.117-117
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• 2008

In MIM capacitor, poly-Si bottom electrode is replaced with metal bottom electrode. Noble metals can be used as bottom electrodes of capacitors because they have high work function and remain conductive in highly oxidizing conditions. In addition, they are chemically very stable. Among novel metals, Ru (ruthenium) has been suggested as an alternative bottom electrode due to its excellent electrical performance, including a low leakage of current and compatibility to high dielectric constant materials. Chemical mechanical planarization (CMP) process has been suggested to planarize and isolate the bottom electrode. Even though there is a great need for development of Ru CMP slurry, few studies have been carried out due to noble properties of Ru against chemicals. In the organic chemistry literature, periodate ion ($IO_4^-$) is a well-known oxidant. It has been reported that sodium periodate ($NaIO_4$) can form $RuO_4$ from hydrated ruthenic oxide ($RuO_2{\cdot}nH_2O$). $NaIO_4$ exist as various species in an aqueous solution as a function of pH. Also, the removal mechanism of Ru depends on solution of pH. In this research, the static etch rate, passivation film thickness and wettability were measured as a function of slurry pH. The electrochemical analysis was investigated as a function of pH. To evaluate the effect of pH on polishing behavior, removal rate was investigated as a function of pH by using patterned and unpatterned wafers.

• Applied Chemistry for Engineering
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• v.34 no.1
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• pp.9-14
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• 2023

In this work, we developed a Nafion polymer-coated impedance sensor with two gold electrode configurations to measure the ion concentration in solution samples. The gold electrodes were fabricated through the sputtering process, followed by surface modification using Nafion polymer. The resulting sensors enable the prevention of the polarization phenomenon on the electrode surface, resulting in stable measurement of electrochemical signals. Spectroscopy and scanning electron microscopy measurements revealed that the thin film of Nafion was coated uniformly onto the surface of the gold electrode. The Nafion-coated sensor exhibited more stable impedance signals than the conventional gold electrode. It showed a highly reliable calibration curve (R² = 0.983) of the impedance sensor using a standard sodium chloride solution. In addition, a comparison experiment between the impedance sensor and a commercial conductivity sensor was performed to measure the ion concentration of artificial tears, showing similar results for the two sensors.

• Journal of Environmental Science International
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• v.24 no.11
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• pp.1485-1491
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• 2015

There are two treatment processes that are currently applied to ships are the biological treatment process using the activated sludge and the electrochemical treatment. However, neither of them are able to remove both nitrogen and phosphorus due to their limited ability to remove organic matters, which are main causes of the red tide. This study was conducted to identify the characteristics of nitrogen removal factors from manure wastewater by replacing the final settling tank in SBR (Sequencing Batch Reactor) process and applying immersion type hollow fiber membrane. SBR process is known to have an advantage of the least land requirement in special environment such as in ship and the immersion type hollow fiber membrane is more stable in water quality change. As the result, the average in the cases of DO (Dissolved Oxygen) is 2.9(0. 6~3.9) mg/L which was determined to be the denitrifying microorganism activity in anaerobic conditions. The average in the cases of ORP (Oxidation Reduction Potential) is 98.4~237.3 mV which was determined to be the termination of nitrification since the inflection point was formed on the ORP curve due to decrease in the stirring treatment after the aeration, same as in the cases of DO. Little or no variation in the pH was determined to have positive effect on the nitrification. T-N (Total Nitrigen) removal efficiencies of the finally treated water were 71.4%, 72.3% and 66.5% in relatively average figures, thus was not a distinct prominence. In being applied in ships in the future, the operating conditions and structure improvements are deemed necessary since the MEPC (Marine Environment Protection Committee). 227(64) ship sewage nitrogen is less than the standard of 20 Qi/Qe mg/L or the removal rate of 70%.