• Bulletin of the Korean Chemical Society
• /
• 제34권2호
• /
• pp.609-614
• /
• 2013

Extended H$\ddot{u}$ckel tight-binding band structure calculations are used to address the chemical bonding and elastic properties of $Zr_2AC$ (A=Al, Si, P, and S). Elastic properties are interpreted by analyzing the density of states and the crystal orbital overlap population for the respective phases. Our results show that the bulk modulus of these ternary compounds is determined by the strength of Zr-A bonds.

• 한국생물물리학회:학술대회논문집
• /
• 한국생물물리학회 1999년도 학술발표회 진행표 및 논문초록
• /
• pp.45-45
• /
• 1999

Cytochrome c (cyt c) binds to acidic membranes at low ionic strength. Replacement of Lys-72 or Lys-87 by Glu reduced the binding affinity of cyt c toward large unilamellar vesicles (LUV) in liquid crystalline phase. The differences were smaller for LUV in gel phase. A fraction of bound cyt c was non-electrostatically associated.(omitted)

• 콘크리트학회논문집
• /
• 제25권3호
• /
• pp.261-269
• /
• 2013

이 연구에서는 산업부산물인 고로슬래그 미분말과 알칼리 활성화제(물유리, 수산화나트륨)를 사용하였다. 또한, 이를 활용하여 철근콘크리트 보에 적용하여 휨성능 평가를 하였다. 주요변수는 W/B, 알칼리 활성화제의 혼입비율, 혼화재의 종류 및 혼입유무로서 총 8개의 실험체를 제작하였으며, 재료 및 구조성능 평가를 위한 실험을 수행한 결과 다음과 같은 결론을 얻었다. 친환경 무기결합재 콘크리트는 초기 경화속도가 빠르며, 고강도 콘크리트의 가능성을 보였다. 또한, 이를 활용한 철근콘크리트 보는 기존 시멘트를 사용한 철근콘크리트 보와 유사한 거동과 파괴양상을 보였다. 친환경 무기결합재 콘크리트가 시멘트 콘크리트를 대체할 수 있는 기초연구로서 향후 건설소재 및 재료분야에 활용할 수 있을 것으로 사료되며, 이러한 특성을 바탕으로 콘크리트 2차 제품 생산과 구조부재를 PC화하여 활용할 경우 생산성 향상, 공기단축 등 효율이 상승될 것으로 보인다.

• 한국광물학회:학술대회논문집
• /
• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
• /
• pp.40-40
• /
• 2001

The sorption behavior of Cs(I), Sr(II), and U(VI) on representative single minerals(oxide and clay) and rocks were comparatively studied by using batch type sorption experiment. The effects of pH, ionic strength and the sorption mechanism were also discussed. It was found that mineral structure played as a main factor governing the sorption characteristics of Cs(I), Sr(II). The sorption of Cs(I) and Sr(II) on minerals showed ionic strength-dependency, which is a indirect sign of weak binding between metal cation and mineral surfaces. However, the sorption behavior of U(VI) was quite different compared with that of Cs(I), and Sr(II). Fe-oxide minerals showed strong tendency for U(VI) sorption, dominating the sorption in the composite/mixture systems. The surface characteristics which arise from mineral structure, and the affinity of metal ions to the sorption sites of minerals are the key to understand the role of minerals in the radionuclide sorption.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2008년도 추계 학술논문 발표대회
• /
• pp.117-120
• /
• 2008

The Purpose of this is properties of CFT filled with expansion concrete. CFT(concrete filled steel tube) is the structure that circle shape steel column filled with concrete. 3 kinds of expansive additives and variation of replacement rate. we changed expansive additive from 0%, 10%, 20%, 30% of ratio of addition rate are selected for this experiment. Merits of CFT are concrete internal force rising influenced by steel shape restriction, reinforcing the local buckling, excellent resistance to transformation. Generally, High rise building using CFT utilize the high strength and fluidity concrete for packing the tube inside. As the result a steel tube charged expensive concrete has stiffness 1.5times more than a steel tube not charged concrete. Increase of resisting power about compressive stress by binding expansion of expansive concrete affects strength increase and softness.

• 한국세라믹학회지
• /
• 제31권6호
• /
• pp.678-684
• /
• 1994

The surface of alumina is capable of acquiring a change when it is in an aqueous solution. This surface change will have a strong influence on the surrounding ions, particularly those of opposite change known as the counter ions. A site-binding model of the {{{{ gamma }}-alumina/KCl(aq) interface was used to calculated theoretical surface ionization constants and P.Z.C.(Point of zero change) of {{{{ gamma }}-alumina. This paper was carried out to investigate the effect of calcination temperature on the acidic and electrical properties of pure {{{{ gamma }}-alumina prepared by the precipitation method from the Al(NO3)3.9H2O and NH4OH. From the experimental data it was shown that {{{{ gamma }}-alumina have a mainly Br nsted acid site. However, the acidity of {{{{ gamma }}-alumina decreased with increasing calcination temperature at strength Ho +9.3. The surface charge density of {{{{ gamma }}-alumina was increased with electrolyte ionic strength and calcination temperature.

• Advances in nano research
• /
• 제3권1호
• /
• pp.13-27
• /
• 2015

Size dependent emission properties and the interband optical transition energies in group-III nitride based quantum dots are investigated taking into account the geometrical confinement. Exciton binding energy and the optical transition energy in $Ga_{0.9}In_{0.1}N$/GaN and $Al_{0.395}In_{0.605}N$/AlN quantum dots are studied. The largest intersubband transition energies of electron and heavy hole with the consideration of geometrical confinement are brought out. The interband optical transition energies in the quantum dots are studied. The exciton oscillator strength as a function of dot radius in the quantum dots is computed. The interband optical absorption coefficients in GaInN/GaN and AlInN/AlN quantum dots, for the constant radius, are investigated. The result shows that the largest intersubband energy of 41% (10%) enhancement has been observed when the size of the dot radius is reduced from $50{\AA}$ to $25{\AA}$ of $Ga_{0.9}In_{0.1}N$/GaN ($Al_{0.395}In_{0.605}N$/AlN) quantum dot.

• Biotechnology and Bioprocess Engineering:BBE
• /
• 제11권1호
• /
• pp.84-87
• /
• 2006

Batch binding experiments were performed to assess the recovery performance of glyceraldehyde 3-phosphate dehydrogenase (G3PDH) bound to the unshielded and polymer (polyvinyl pyrrolidone. PVP)-shielded dye-ligand (Cibacron Blue 3GA) adsorbent. The adoption of a polymer-shielded, dye-ligand technique facilitated the elution efficiency of bound G3PDH. It was demonstrated that the recovery of G3PDH using polymer-shielded dye-ligand adsorption yielded higher elution efficiency, at 60.5% and a specific activity of 42.3 IU/mg, after a low ionic strength elution (0.15 M NaCl). The unshielded dye-ligand yielded lower elution efficiency. at 6.5% and a specific activity of 10.2 IU/mg.

• 한국지반신소재학회논문집
• /
• 제12권3호
• /
• pp.23-29
• /
• 2013

동결토는 물과 얼음의 상변화에 따라 일반적인 흙과는 다른 거동을 보이며, 동결토의 강도는 온도, 함수비, 시간, 토질 특성 등 다양한 인자에 의해 영향을 받는다. 특히 지반이 동결되는 경우, 얼음과 흙 입자의 결합력에 의해 높은 강도 특성을 보이며, 이때의 전단강도는 흙의 구조적 결합에 영향을 미치는 얼음과 세립분의 함량에 따라 달라지며, 이로 인해 점착력이 동결토의 전단강도에 미치는 영향은 증가한다. 본 논문에서는 동결조건에서 직접전단시험과 일축압축강도시험을 실시하여 온도에 따른 흙의 강도 특성을 확인하였으며, 점착력과 일축압축강도와의 상관관계를 확인하였다.

• 한국지반공학회논문집
• /
• 제29권12호
• /
• pp.95-104
• /
• 2013

최근 시멘트혼합토(CSG)가 많은 설계 시공에 적용되어지고 있다. CSG재료는 경화 초기엔 흙과 같은 역학적 특성을 보이지만 시간이 경과함에 따라 점차 콘크리트 재료적 특성을 발현하게 된다. 경화된 시멘트혼합토는 작은 변형률에서 최대강도가 발현되고 이 후 급격한 취성파괴에 도달하는 탄성적인 성질을 띠게 된다. 본 연구에서는 이러한 CSG재료의 취성거동특성을 완화하고 상대적으로 취약한 인장성능을 개선하고자 PVA 섬유보강재를 적용하였다. 섬유보강 CSG재료는 재하시 하상시료와 섬유사이의 결합력으로 섬유에 인장력이 발생하여 혼합시료의 인장강도 증가와 급작스런 취성파괴발생을 방지할 수 있다. 실험결과 섬유보강만으로도 CSG재료의 응력-변형특성을 취성파괴에서 연성파괴로 유도할 수 있으며, 섬유보강에 의한 잔류강도 증가효과를 확인 할 수 있었다.