• 제목/요약/키워드: binding strength

검색결과 242건 처리시간 0.026초

Performance of cement-stabilized sand subjected to freeze-thaw cycles

  • Jumassultan, Assel;Sagidullina, Nazerke;Kim, Jong;Ku, Taeseo;Moon, Sung-Woo
    • Geomechanics and Engineering
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    • 제25권1호
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    • pp.41-48
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    • 2021
  • In cold regions, the integrity of the infrastructures built on weak soils can be extensively damaged by weathering actions due to the cyclic freezing and thawing. This damage can be mitigated by exploiting soil stabilization techniques. Generally, ordinary Portland cement (OPC) is the most commonly used binding material for investigating the chemo-hydromechanical behavior. However, due to the environmental issue of OPC producing a significant amount of carbon dioxide emission, calcium sulfoaluminate (CSA) cement can be used as one of the eco-sustainable alternatives. Although recently several studies have examined the strength development of CSA treated sand, no research has been concerned about CSA cement-stabilized sand affected by cyclic freeze and thaw. This study aims to conduct a comprehensive laboratory work to assess the effect of the cyclic freeze-thaw action on strength and durability of CSA cement-treated sand. For this purpose, unconfined compressive strength (UCS) and ultrasonic pulse velocity (UPV) tests were performed on the stabilized soil specimens cured for 7 and 14 days which are subjected to 0, 1, 3, 5, and 7 freeze-thaw cycles. The test results show that the strength and durability index of the samples decrease with the increase of the freeze-thaw cycles. The loss of the strength and durability considerably decreases for all soil samples subjected to the freeze-thaw cycles. Overall, the use of CSA as a stabilizer for sandy soils would be an eco-friendly option to achieve sufficient strength and durability against the freeze-thaw action in cold regions.

순환잔골재 치환율에 따른 모르타르의 염화물이온확산계수 평가 (Evaluation on the Chloride Ion Diffusion Coefficient of Mortar Depending on Replacement Ratio of Recycled Fine Aggregate)

  • 이상윤;유재철;김규용;윤민호;남정수;최형길
    • 한국건축시공학회지
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    • 제16권6호
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    • pp.479-485
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    • 2016
  • 콘크리트용 천연골재의 공급이 어려워지고 건설폐기물은 발생량이 지속적으로 증가하고 있는 추세이다. 따라서 건설폐기물을 골재로 만든 순환골재 사용의 필요성이 대두되고 있다. 이에 순환골재를 사용한 콘크리트의 특성에 대한 많은 연구가 진행되고 있으나 대부분의 연구들이 부정적인 결과를 나타내고 있다. 하지만 최근 연구들을 중심으로 긍정적인 연구결과들이 보고되고 있으며 그 중 순환굵은골재의 부착 모르타르의 염화물고정효과에 관한 연구도 보고되고 있다. 따라서 본 연구에서는 순환굵은골재에 비해 모르타르 함량이 많아 염화물고정에 유리하다고 예상되는 순환잔골재를 사용한 모르타르의 역학적 특성과 염화물확산을 평가한 결과 순환잔골재의 염화물고정효과를 확인했다.

고온숙성에 의한 저급육의 연도개선과 그 이용 (Tenderness Improvement and Utilization of Low Quality Meat by High Temperature Aging)

  • 성삼경
    • 한국식품과학회지
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    • 제21권4호
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    • pp.549-555
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    • 1989
  • 저급육인 한우숫소의 앞다리고기를 도살직후 $16{\pm}2^{\circ}C$에서 고온숙성하여 연도개선 효과를 검토하였다. 또한 24시간 고온숙성한 후, 재구성육을 조제하여 결착성 개선방법을 모색하였다. 시료의 처리는 소금(0, 0.5, 1.0%), pyrophosphate(0, 0.3, 0.5%)와 이들의 혼용효과를 검토하였고, 소금(0.5%)과 pyrophosphate(0.3%)를 혼용한 원료에 succinic anhydride(0, 0.1, 0.2, 0.3%)를 첨가하여 석시닐산의 첨가효과를 검토하였다. 얻어진 결과는 다음과 같다. 1. 고온숙성은 저온숙성에 비하여 전단력이 낮았고, 근원섬유소편화지수가 높았으며, 연도개선의 효과가 뛰어났다. 전자현미경에 의한 형태학적 변화의 결과도 이들 결과 일치하였다. 2. 재구성육의 파단응력은 소금과 인산염의 첨가수준이 증가할수록 높아졌고, 소금과 인산염을 혼용할 경우, 현저히 증가하였다. 3. 조리수율은 소금과 인산염의 첨가수준이 증가할수록 낮아졌고, 소금과 인산염을 혼용할 경우, 현저하게 감소하였다. 4. TBA가는 소금 첨가수준에 비례하여 증가하였으며, 인산염 및 인산염과 소금혼용의 경우는 약간 증가하는 경향이었다. 5. 석신산은 재구성육의 결착력과 품질개선에 전혀 도움이 되지 않았다.

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구아검 및 바질검 첨가 Gluten-free 생면의 제조 및 품질 특성 비교 (A Comparison of the Manufacturing and Quality Characteristics of Gluten-free Noodles using Guar Gum and Basil (Ocimum basilicum L.) Seed Gum)

  • 송가영;오현빈;정기영;신소연;김영순
    • 한국조리학회지
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    • 제23권4호
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    • pp.116-124
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    • 2017
  • This study was investigated quality characteristics of gluten-free noodles added guar gum and basil seed gum (BSG). Gluten-free noodles were prepared using corn flour and corn starch and added 1% and 2% of guar gum and basil seed gum. Water binding capacity was measured by centrifuge, and moisture content was obtained by moisture analyzer. Color of noodles was measured from the midsection of noodles. Water absorption of noodles was calculated by weight of uncooked and cooked noodles. pH of noodles was measured by pH meter. Texture and tensile strength were obtained by rheometer. SPSS 12.0 program was used for significant differences by Duncan's multiple range test. Water binding capacity of noodles was the highest in 2% basil seed gum but 1% guar gum was the lowest. Moisture content was not different in uncooked noodles, but 1% guar had the highest moisture content in cooked noodles. Water absorption of noodles was high in basil seed gum group. pH of noodles was more increased in guar gum additions than basil seed gum additions. For hardness, control had the lowest as 16.09 N, but 2% guar gum showed the highest as 28.40 N. Tensile strength of noodles was increased by adding gums. These results suggested that 1% basil seed gum could be good materials for manufacturing gluten-free noodles in order to improve quality characteristics.

지시약 적정법 및 분광광도법에 의한 양이온 고분자 전해질의 전해밀도 정량 (Charge Determination of Cationic Polyelectrolytes by Visual Titrimetry and Spectrophotometry)

  • 이민규;김상규
    • 한국환경과학회지
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    • 제14권6호
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    • pp.525-532
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    • 2005
  • Polyelectrolyte titration, which was called colloid titration is based on the stoichiometric reaction between oppositely charged polyelectrolytes, This can be used, for instance, to determine the charge density of a cationic polyelectrolyte, using an anionic polyelectrolyte of known charge density, such as potassium polyvinyl sulfate (PPVS). The technique requires a suitable method of end-point detection and there are several possibilities. In this work, two methods have been investigated: visual titrimetry based on the color change of a cationic dye (o-toluidine blue, o-Tb) and spectrophotometry based on the absorbance change corresponding to the color change of the same dye. These have been applied to several cationic polyelectrolytes with different charge density and molecular weight. In all cases, the cationic charge was due to quaternary nitrogen groups. In the case of cationic dye, it was shown that the sharpness depends on the charge density of cationic polyelectrolyte. With the polyelectrolytes of lower charge density, the binding to PPVS is weaker and binding of the dye to PPVS can occur before all of the polyelectrolyte charge has been neutralized. However, by carrying out titrations at several polyelectrolyte concentrations, good linear relationships were found, from which reliable charge density values could be derived. Effects of pH and ionic strength were also briefly investigated. For cationic polyelectrolytes (copolymers of acrylamide and dimethylaminoethy] acrylate), there was some loss of charge at higher pH values, probably as a result of hydrolysis. Increasing ionic strength causes a less distinct color change of o-Tb, as a result of weaker electrostatic interactions.

금속의 두께가 도재의 파절강도에 미치는 영향 (A study on the difference of Ceramic fracture strength according to the metal depth)

  • 신무학;최운재;김용원
    • 대한치과기공학회지
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    • 제27권1호
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    • pp.89-95
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    • 2005
  • In the manufacture of ceramo-metal crown, difference of fracture strength according to the metal depth has been known to be an important influence on enough intensity and internal stress to endure an occlusion-pressure as well as aesthetics of rehabilitating similar colour such as natural teeth. Depth of ceramic material could be determined by that of metal in three groups: first case of thin depth, second case of thick depth, and third case of constant depth. For the enhancement of the fracture strength between metal and ceramic materials and aesthetic satisfaction, a study on the bonding force, fracture strength, and aesthetics have been required more. In this study, therefore metal coping were made in three groups of A, B and C by using both ceramic powder of Norithe and metal of Columbium, which have been used primarily in the market. A group was made in $0.2mm\times10mm\times10mm$, B group was made in $0.4mm\times10mm\times10mm$, and, C group was made in $0.8mm\times10mm\times10mm$, respectively. The number of metal coping in each group was 10, and total sample numbers used in this study were 30 metal copings. After these metal coping tissue were in the process of build-up in 1.5mm constant depth of porcelain, firing, and glazing, the fracture strength about each metal coping tissue was investigated using oil press. It was found that the average values of durable occlusion pressure for separation of ceramic material in the porcelain fused to metal crown (PFM) in the each group showed the increasing order of A group (30 bar), B group (42 bar), and C group (44 bar), respectively. Proper depth of metal coping in the PFM was considered to be 0.4mm in the B group because this metal size showed higher durable property to the occlusion pressure and better coupling strength in the ceramo-metal crown.

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Repairing Damaged Hair Using Pentapeptides of Various Amino Acid Sequences with Crosslinking Reaction

  • Choi, Wonkyung;Son, Seongkil;Song, Sang-Hun;Kang, Nae Gyu;Park, Sun-gyoo
    • Korea Journal of Cosmetic Science
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    • 제2권1호
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    • pp.11-19
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    • 2020
  • The aim of this study is to investigate the effect of various pentapeptides on hair repair depending on the characteristics of comprising amino acids using crosslinking agents in hair. Total ten peptides were synthesized with two kinds of amino acids respectively, of which were previously categorized according to R group of the amino acids contributing to the characteristic of each peptide: STTSS (Ser-Thr-Thr-Ser-Ser), LIILL (Leu-Ile-Ile-Leu-Leu), CMMCC (Cys-Met-Met-Cys-Cys), DEEDD (Asp-Glu-Glu-Asp-Asp), RKKRR (Arg-Lys-Lys-Arg-Arg), TAMRA-STTSS, TAMRA-LIILL, TAMRA-CMMCC, TAMRA-DEEDD, and TAMRA-RKKRR. Pentapeptide alone, or pentapeptides with crosslinking agents such as polymeric carbodiimide (PCI) and 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC) were treated to chemically damaged hair. Hair diameter and break strength (N = 40/case) were measured to calculate tensile strength of hair for computing hair repair ratio, and fluorescence yields (N = 20/case) were collected for hair treated with TAMRA-peptides. The tensile strength of hair treated with pentapeptides alone, or pentapeptides with cross-linking agents is consistent with the fluorescence yield from the microscope images of the cross-sectioned hair in vision and in numerical values. Pentapeptides consisting of hydrophobic amino acids (LIILL), amino acids with sulfur (CMMCC), and basic amino acids (RKKRR) increased the tensile strength in perm-damaged hair. Pentapeptides with no extra carboxyl/amine groups in R group of amino acids resulted in no significant differences in hair strength and fluorescence yield among hairs treated with alone and with crosslinkers. Pentapeptides with extra carboxyl groups or amine groups enabled further strengthening of hair due to increased bonds within the hair after carbodiimide coupling reaction. The hair repairs of pentapeptides with various amino acid sequences were studied using crosslinking. Depending on the physical characteristics of comprising amino acids, the restoration of damaged hair was observed with tensile strength of hair and fluorescence signals upon cross-sectioned hair in parallel to possibly understand the binding tendency of each pentapeptide within the hair.

Alkaline induced-cation crosslinking biopolymer soil treatment and field implementation for slope surface protection

  • Minhyeong Lee;Ilhan Chang;Seok-Jun Kang;Dong-Hyuk Lee;Gye-Chun Cho
    • Geomechanics and Engineering
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    • 제33권1호
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    • pp.29-40
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    • 2023
  • Xanthan gum and starch compound biopolymer (XS), an environmentally friendly soil-binding material produced from natural resources, has been suggested as a slope protection material to enhance soil strength and erosion resistance. Insufficient wet strength and the consequent durability concerns remain, despite XS biopolymer-soil treatment showing high strength and erosion resistance in the dried state, even with a small dosage of soil mass. These concerns need to be solved to improve the field applicability and post-stability of this treatment. This study explored the utilization of an alkaline-based cation crosslinking method using calcium hydroxide and sodium hydroxide to induce non-thermal gelation, resulting in the enhancement of the wet strength and durability of biopolymer-treated soil. Laboratory experiments were conducted to assess the unconfined compressive strength and cyclic wetting-drying durability performance of the treated soil using a selected recipe based on a preliminary gel formation test. The results demonstrated that the uniformity of the gel structure and gelling time varied depending on the ratio of crosslinkers to biopolymer; consequently, the strength of the soil was affected. Subsequently, site soil treated with the recipe, which showed the best performance in indoor assessment, was implemented on the field slope at the bridge abutment via compaction and pressurized spraying methods to assess feasibility in field implementation. Moreover, the variation in surface soil hardness was monitored periodically for one year. Both slopes implemented by the two construction methods showed sufficient stability against detachment and scouring, with a higher soil hardness index than the natural slope for a year.

Kevlar-29 섬유강화 복합재료의 기계적 계면 특성 연구 (Studies on Mechanical Interfacial Properties of Kevlar-29 Fibers Reinforced Composites)

  • Park, Soo-Jin;Seo, Min-Kang;Ma, Tae-Jun;Lee, Jae-Rock
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.158-162
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    • 2001
  • The effects of chemical treatment on Kevlar-29 fibers have been studied in a composite system. The surface characteristics of the Kevlar-29 fibers were characterized by pH, acid-base value and X-ray photoelectron spectroscopy (XPS). The mechanical interfacial properties of final composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). Also, the impact properties of the composites were investigated in the differentiating studies between initiation and propagation energies, and ductile index (DI) along with maximum farce and total energy. It was found that the chemical treatment with phosphoric acid ($H_3PO_4$) solution significantly affected the degree of adhesion at interfaces between fibers and resin matrix, resulting in improving the mechanical interfacial strength of the composites. This was probably due to the presence of chemical polar groups on Kevlar surfaces, leading to an increment of interfacial binding force in a composite system.

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Lyocell 섬유를 함유한 종이의 제조 및 적용에 관한 연구( I ) (A study on the application and manufacture of paper sheet containing lyocell fiber( I ))

  • 김종열;류운형;유성종;김정열;신창호;김영호
    • 한국연초학회지
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    • 제22권1호
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    • pp.99-106
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    • 2000
  • In order to investigate the applicability of lyocell fiber to filter paper, papper sheets were manufactured with the addition of lyocell fibers in various length(1.5 denier: 2, 3, 4mm) and content(10, 30, 50%) and their physical characters, such as fibrilation rate, adsorption efficiency of methylene blue(MB), paper formation, and crimping ability, etc, were tested. The level of main fibrilation from lyocell fiber was higher in wet beating process than that in free beating because of the higher strength of lyocell fiber compared with wood fiber. Fibrilation could be observed at the degree of beating over 30$^{\circ}$ SR in wet beating with Valley beater. The air permeability and tear factor of the paper increased and the paper formation index decreased according to the increase of fiber length. The weak binding force of lyocell fiber in spite of its higher fiber strength, might be a limitng factor in addition of lyocell fiber to the natural wood pulp in manufacturing the paper having the needed physical properties. High contents of wood pulp decreased air permeability, the breaking length, tear factor, the bursting strength, and paper formation index in paper sheets. As the contents of lyocell increased from 10% to 100%, the adsorption efficiency of MB was elevated to 1.7-7.9 times compared with that in 100% wood pulp. But the length of lyocell fiber did not affect the MB adsorption.

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