• 제목/요약/키워드: binder component

검색결과 72건 처리시간 0.023초

알루미노실리케이트계 지오폴리머의 압축강도에 미치는 물유리의 영향 (Influence of Water Glass Content on the Compressive Strength of Aluminosilicate-Based Geopolymer)

  • 김진태;서동석;김갑중;이종국
    • 한국재료학회지
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    • 제20권9호
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    • pp.488-493
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    • 2010
  • Geopolymer is a term covering a class of synthetic aluminosilicate materials with potential use in a number of areas, but mainly as a replacement for Portland cement. In this study, geopolymers with fly ash and meta kaolin were prepared using KOH as an alkali activator and water glass. The effect of water glass on the microstructures and the compressive strength of the geopolymer was investigated. As the amount of water glass increased, the dissolved inorganic binder particles in the geopolymers increased due to polymerization, resulting in a dense microstructure. The meta kaolin-based geopolymer showed a better extent of polymerization and densification than that of the fly ash-based geopolymer. XRD data also suggested that polymerization in meta kaolin-based geopolymers should be active resulting in the formation of an amorphous phase with an increasing amount of water glass. The compressive strength of the geopolymer was also dependent on the amount of water glass. The compressive strength of the geopolymers from both fly ash and meta kaolin increased with an increasing amount of water glass because water glass improved the extent of polymerization of the inorganic binder and resulted in a dense microstructure. However, the addition of water glass to the geopolymer did not seem to be effective for the improvement of compressive strength because the meta kaolin-based geopolymer mainly consisted of a clay component. For this reason, the fly ash-based geopolymer showed a higher value of compressive strength than the meta-kaolin geopolymer.

Study and Application of the New Stick Make Up Product Using Clay Minerals as Binder & Buffer.

  • Kim, Sang-Je;Shin, Dong-Uk;Cho, Pan-Gu;Jung, Chul-Hee
    • 대한화장품학회지
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    • 제25권4호
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    • pp.97-110
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    • 1999
  • The new stick make-up product was studied by using a gel, which is a viscous complex formed with clay minerals, vitamins A and E and fluorinated liquid polymer with a 1500 molecular weight. The gel cannot be obtained with any random combination of clay minerals and the ingredients described above. It takes the sequential manufacturing method as follows to get this kind of gel. Firstly, clay minerals and liquid polymers have to be pre-mixed in order to saturate the liquid polymers with the clay minerals. Then the on-processed gel has to be finely crystallized. The clay minerals, which are the core elements for this gel, were used as a function of Binder & Buffer and liquid polymer was mixed together for the deterioration of the surface tension of each component and to form a functional film in the gel. This liquid polymer was combined with clay minerals because it is not miscible with most oils and solvents. Waxes have a function of keeping a solid status in the stick. We reduced the usage of waxes by putting clay minerals as buffer in the proportion of 0.5:1 with oil phase. Ceramide takes care of the skin when used regularly and maintains the skin's moisture. Vitamins A and E contribute to preventing skin aging by the activation of skin cells. We could get the stable viscous gel, which has about 80% oil phase using clay minerals and liquid polymer. The crystalline structures of gel were surface-chemically-analyzed using SEM and Image Analyzer and were thermodynamically analyzed using DSC. Surface tension test and softness were done by Rheometer. In the end, these characteristics were verified by consumer panel tests in Seoul, Daegeon and Pusan in Korea and Hokkaido, Osaka and Miyazaki in Japan with correlation to the climate.

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Study and Application of the New Stick Make Up Product Using Clay Minerals as Binder & Buffer.

  • Kim, Sang-Je;Shin, Dong-Uk;Cho, Pan-Gu;Jung, Chul-Hee
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 1999년도 IFSCC . ASCS 학술대회 발표 논문
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    • pp.97-110
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    • 1999
  • The new stick make-up product was studied by using a gel, which is a viscous complex formed with clay minerals, vitamins A and I and fluorinated liquid polymer with a 1500 molecular weight. The gel cannot be obtained with any random combination of clay minerals and the ingredients described above. It takes the sequential manufacturing method as follows to get this kind of gel. Firstly, clay minerals and liquid polymers have ·to be pre-mixed in order to saturate the liquid polymers with the clay minerals. Then tile on-processed gel has to be finely crystallized. The clay minerals, which are the core elements for this gel, were used as a function of Binder & Buffer and liquid polymer was mixed together for the deterioration of the surface tension of each component and to from a functional film in the gel. This liquid polymer was combined with clay minerals because it is not miscible with most oils and solvents. Waxes have a function of keeping a solid status in the stick. We reduced the usage of waxes by putting clay minerals as buffer in the proportion of 0.5 : 1 with oil phase. Ceramide takes care of the skin when used regularly and maintains the skin’s moisture. Vitamins A and I contribute to preventing skin’aging by the activation of skin cells. We could get the stable viscous gel, which has about 80% oil phase using clay minerals and liquid polymer, The crystal 1 me structures of gel were surface-chemical1y-analyzed using SEM and Image Analyzer and were thermodynamically analyzed using DSC, Surface tension test and softness were done by Rheometer. In the end, these characteristics were verified by consumer panel tests in Seoul, Baegeon and Pusan in Korea and Hokkaido, Oska and Miyazaki in Japan with correlation to the climate.

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Evaluation of 3D concrete printing performance from a rheological perspective

  • Lee, Keon-Woo;Lee, Ho-Jae;Choi, Myoung-Sung
    • Advances in concrete construction
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    • 제8권2호
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    • pp.155-163
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    • 2019
  • The objective of this study was to derive a cementitious material for three-dimensional (3D) concrete printing that fulfills key performance functions, extrudability, buildability and bondability for 3D concrete printing. For this purpose, the rheological properties shown by different compositions of cement paste, the most fundamental component of concrete, were assessed, and the correlation between the rheological properties and key performance functions was analyzed. The results of the experiments indicated that the overall properties of a binder have a greater influence on the yield stress than the plastic viscosity. When the performance of a cementitious material for 3D printing was considered in relation with the properties of a binder, a mixture with FA or SF was thought to be more appropriate; however, a mixture containing GGBS was found to be inappropriate as it failed to meet the required function especially, buildability and extrudability. For a simple quantitative evaluation, the correlation between the rheological parameters of cementitious materials and simplified flow performance test results-time taken to reach T-150 and the number of hits required to reach T-150-in consideration of the flow of cementitious materials was compared. The result of the analysis showed a high reliability for the correlation between the rheological parameters and the time taken to reach T-150, but a low reliability for the number of hits needed for the fluid to reach T-150. In conclusion, among several performance functions, extrudability and buildability were mainly assessed based on the results obtained from various formulations from a rheological perspective, and the suitable formulations of composite materials for 3D printing was derived.

고성능 저발열 자기충전 콘크리트의 최적 배합설계 (Optimal Mix Design of High-Performance, Low-Heat Self-Compacting Concrete)

  • 김영봉;이준해;박동천
    • 한국건축시공학회지
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    • 제22권4호
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    • pp.337-345
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    • 2022
  • 해안지역 초고층 콘크리트 건축물 매트기초는 상하층 응력발생으로 인한 결함예방과 원활한 공정관리를 위해 일반적으로 일체타설이 요구되지만 일체타설의 경우 수화열에 의한 온도응력 균열 발생의 우려가 있으며 다짐에 대한 시공성을 확보하기 위해 높은 수준의 자기충전성의 콘크리트 배합이 필요하다. 본 연구에서는 이러한 요구성능을 만족할 수 있도록 고성능 분사제와 혼화재의 사용량을 실험변수로 배합 실험을 통해 최적량을 도출하고자 하였다. 배합 변수별 결과분석을 통해 단위수량은 155kg/m3, 결합재에서 시멘트 비율 18% 일 때 굳지 않은 콘크리트 물성 및 강도발현 목표값을 만족하는 것으로 나타났다. 4성분계(시멘트 18%, 슬래그미분말 50%, 플라이애시 27%, 실리카흄 5%)가 사용되었다.

부순모래를 사용한 초고강도 콘크리트의 레미콘 제조성능에 관한 실험적 연구 (An Experimental Study on the Ready-Mixed Concrete Manufacture Performance of Ultra-High Strength Concrete using the Crushed Sand)

  • 노형남;임현응;최세진;이성연;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2007년도 춘계학술논문 발표대회
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    • pp.25-28
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    • 2007
  • In this study we measured the changes according to time respectively on the basis of 0, 30, 60 and 90 minutes, taking into consideration the decline in fluidity of concrete according to elapsed time to analyze manufacturing capability of batcher plant according to elapsed time of ready-mixed concrete manufactured in batcher plant, and offer basic data for mixture design of ultra-high strength concrete. The proportion of water-binder was 23.55, water content was 160kg/m3, proportion of replacement of crushed sand was 0, 20 and 40% at 3 level, and we applied to the same condition of triaxial component using blast furnace slag powder and silica fume as admixture. And to meet the demand of certain fluidity, we measured respectively on property before and after hardening of ultra-high strength concrete using superplasticizer. As a result of experiment, before hardening of ultra-high strength concrete showed the best fluidity in conditions of crushed sand replacement rates of 20% and superplasticizer composition of 1.95%, but it appeared that fluidity drops as time goes by in the same composition condition. And it appeared that when it comes to hardened, the changes of compression strength according to elapsed time by crushed sand replacement rates were within 1MPa. Therefore, it turned out that the difference of strength according to elapsed time was low and compression strength of 280dys in composition mentioned above appeared highly as 88MPa.

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동결융해와 황산염의 복합작용을 받는 부순모래 모르타르의 기초 특성 평가 (Evaluation on Basic Properties of Crushed Sand Mortar in Freezing-Thawing and Sulfate Attack)

  • 김명식;백동일;최강석
    • 한국해양공학회지
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    • 제23권5호
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    • pp.54-60
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    • 2009
  • Exposed to various environments, concrete confronts degradation by a lot of physical and chemical reaction. Though so many experiments and theorizations on the single condition of concrete degradation have been carried out by constant studies, the truth for now is that there are few studies on the compound phenomenon of degradation related with marine environments. Accordingly, this study measured the degree of degradation in the change of external shape, the change of unit weight and compressive strength, ultrasonic velocity test, and the change of length, etc. after exposing the specimen of cement mortar to the environment between 0 cycle and the maximum of 300 cycles under the condition of aquatic curing, freezing and thawing, and compound degradation, using mineral admixture effective for concrete degradation as a binder. The result indicated that the case of adding mineral admixture showed greater resistance than that of using OPC only, and specifically, the specimen with the additive of slag powder and three component system showed very excellent resistance to freezing and thawing, and compound degradation.

자수기용 로터리 훅 개발을 위한 금속분말 사출성형해석 (Metal Injection Molding Analysis for Developing Embroidering Machine Rotary Hooks)

  • 김상윤;박보규;정재옥;조규상;정일섭
    • 한국기계가공학회지
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    • 제17권4호
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    • pp.160-168
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    • 2018
  • Among the components of rotary hooks, a core component of an embroidery sewing system, a study was conducted to apply metal injection molding to the manufacture of a hook body and a housing that was very difficult to mechanical working. The correlation of feedstock, a mixture of binder and SCM 415 metal powder, and properties of the pressure-volume-temperature interrelationship, viscosity, specific heat, and thermal conductivity were measured. Injection molds for the hook body and the housing were developed through injection molding analysis using these properties and conducted injection tests. Optimal injection gate position and number, injection pressure, and injection time were obtained through a comparison of analysis results with the experiment results.

A Study on the High-Flowing Concrete with Low Unit Weight of Cement

  • Si Woo Lee;Hong Shik Choi;Sang Chel Kim;Gweon Heo
    • The Korean Journal of Ceramics
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    • 제6권3호
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    • pp.318-321
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    • 2000
  • Most compressive strengths commonly used in the construction field are in a range of 240 to 300 kgf/$\textrm{cm}^2$ at 28 days. To get this rage of strengths, however, high-flowing concrete requires cementitious binders more than 400 to 450 kg/$\textrm{cm}^2$ for preventing segregation and sedimentation of aggregates. This amount of cementitious binder generates a large emission of excessive hydration heat, which may consequently induce harmful cracks in concrete structure. In order to reduce excessive hydration heat, thus, this paper aims at fabricating a high-flowing concrete under the condition that cement content is kept as low as 350kg/$\textrm{cm}^3$ by using viscose agents. In a parametric study, effects of cement types such as a ternary blended cement and Type V on he physical characteristics of high-flowing concrete were evaluated. In addition, the influence of viscosity was also investigated by applying two different viscose agents, one in a range of 6,000 to 10,000 cps and the others of 10,000 to 14,000 cps. In terms of chemical admixtures used in concrete mixture, the superplasticizer was Sulfonated Melamine-Formaldehyde Condensate with about 30,000 of molecular weight, and main component of viscose agent was HPMC (Hydroxy Propyl Methyl Cellulose). Slump flow was fixed at 50cm with different dosages of superplasticizer in weight.

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LabRAM Mixer를 이용한 ZPP 입자 제조 (Manufacture of ZPP Granule Using the LabRAM Mixer)

  • 정혜흔;김준형;고승원;류병태
    • 한국추진공학회지
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    • 제21권4호
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    • pp.63-70
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    • 2017
  • ZPP (Zirconium-Potassium Perchlorate)는 PMD (Pyrotechnic Mechanical Device)에 사용하는 1차 점화장약의 일종이다. 용매에 녹아있는 바인더 성분을 석출시켜 부유해 있는 입자들을 유동상태에서 과립형태로 만들어 제조하는데 LabRAM Mixer를 이용하여 기계적 접촉을 하는 블레이드형 장비와 달리 공진현상을 이용하여 에너지를 전달시켜 입자를 제조한다. 본 연구를 통해 LabRAM Mixer의 조건 변화에 따라 제조한 입자의 특성을 평가하고 그 특성을 고찰하였다.