• Macromolecular Research
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• v.11 no.5
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• pp.303-310
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• 2003

The phase behavior of binary blends of dimethylpolycarbonate-tetramethyl polycarbonate (DMPCTMPC) copolycarbonates and styrene-acrylonitrile (SAN) copolymers has been examined and then compared with that of DMPC/TMPC/SAN ternary blends having the same chemical components and compositions except that the DMPC and TMPC were present in the form of homopolymers. Both binary and ternary blends were miscible at certain blends compositions, and the miscible blends showed the LCST-type phase behavior or did not phase separated until thermal degradation temperature. The miscible region of binary blends is wider than that of the corresponding ternary blends. Furthermore, the phase-separation temperatures of miscible binary blends are higher than those of miscible ternary blends at the same chemical compositions. To explain the destabilization of polymer mixture with the increase of the number of component, interaction energies of binary pairs involved in these blends were calculated from the phase separation temperatures using lattice-fluid theory and then the phase stability conditions for the polymer mixture was analyzed with volume fluctuation thermodynamics.

• Computers and Concrete
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• v.21 no.2
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• pp.149-156
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• 2018

This paper investigated the influence of binary and ternary blends of mineral admixtures in self-compacted mortar (SCM) on the fresh, mechanical and durability properties. For this purpose, 25 mortar mixtures were prepared having a total binder content of $640kg/cm^3$ and water/binder ratio between 0.41 and 0.50. All the mixtures consisted of Portland cement (PC), fly ash (FA) and silica fume (SF) as binary and ternary blends and air-entrained admixture wasn't used while control mixture contained only PC. The compressive and tensile strength tests were conducted for 28 and 91 days as well as slump-flow and V-funnel time tests whilst freeze-thaw (F-T) resistance and capillary water absorption tests were made for 91-day. Finally, in general, the use of SF with FA as ternary blends improved the tensile strength of mortars at 28- and 91-day while the use of SF15 with FA increased the compressive strength of the mortars compared to binary blends of FA. SCM mixtures with ternary blends had lower the sorptivity values than that of the mortars with binary blends of FA and the control mixture due to the beneficial properties of SF while the use of FA with SF as ternary blends induced the F-T resistance enhancement.

• Proceedings of the Korean Fiber Society Conference
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• 2003.10a
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• pp.101-101
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• 2003

TLCP/Polyester binary blends were prepared by melt blending. Rheological, morphological, and thermal properties of of TLCP/polyester blends were investigated with viscosity ratio. Diameter of TLCP fibrils decreased with viscosity ratio. More and smaller TLCP fibrils were obtained at higher shear rate. Lower viscosity ratio was necessary for the fibrillation of TLCP in the binary blends.

• Elastomers and Composites
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• v.38 no.3
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• pp.262-272
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• 2003

Maleic anhydride-grafted-polypropylene(PP-g-MA) were used as a blend component and a compatibilizer, respectively, for two reactive blends of polyamide 66(PA 66)PP-g-MA binary blends and PA 66/polypropylene(PP)/PP-g-MA ternary blends. The goal of this work was to investigate the property differences between binary and ternary blends. Tensile strength, flexural modulus, heat deflection temperature, impact strength, melt flow index, and the dependence of melt viscosity on the shear rate were examined. The impact strengths of binary blends were higher than those of ternary blends at all compositions, since the in situ synthesis of PP-g-PA 66 copolymer through the imide formation between the amine end group of PA 66 and the anhydride group of PP-g-MA gave the increase of molecular weight and was more popular in binary blends than in ternary blends. In case of ternary blends, most of the properties were superior to those of binary blends, owing to the better properties of PP compared with PP-g-MA. The toughened binary blends with 70/30(PA 66/PP-g-MA) and 80/20 ratios were not commercially applicable due to their poor processibility. So, the ternary blends which showed lower melt viscosities were recommended for the commercial applications.

• Elastomers and Composites
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• v.25 no.3
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• pp.203-210
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• 1990

The structure and properties of blends of ethylene-propylene-diene terpolymer(EPDM) and polyolefin blends have been investigated. The rheology and tensile properties of the EPDM/HDPE(high density polyethylene), EPDM/PP(polypropylene) binary and EPDM/PP/HDPE ternary blends were studied along with morphological analyses. Those properties were affected by preferential interaction of EPDM on HDPE, compared to that of EPDM on PP, for the binary blends. The preferetial interaction may stem from the molecular characteristics of EPDM to possess more ethylene units than propylene units in the elastomer. The EPDM played a role as compatibilizer for HDPE and PP in the EPDM/PP/HDPE ternary blends.

• Elastomers and Composites
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• v.34 no.1
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• pp.20-30
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• 1999

In this study, binary polyamide 6,6(PA 6,6)/ethylene-propylene rubber(EPM) or EPM-g-maleic anhydride(EPM-g-MA) blends and ternary PA 6,6/EPM/EPM-g-MA blends with various elastomer content were prepared in order to investigate the degree of influence of elastomer content and average particle size, morphology, and distribution of dispersed elastomer on mechanical and thermal properties of blends. According to the results, notched Izod impact strength and relative crystallinity of binary blends modified with EPM-g-MA as well as average particle size and distribution of dispersed elastomer in such blends were more improved than those of binary blends modified with EPM. Notched Izod impact strength of blend whose composition ratio(wt % ) was 70:30(PA 6,6 : EPM-g-MA) was the highest among the binary PA 6,6/EPM-g-MA blends. The impact strength was increased by 25 times and its relative crystallinity was increased by 7 times when compared with those of polyamide 6,6. In the case of ternary PA 6,6/EPM/EPM-g-MA blend of which composition ratio was 70:15:15(PA 6,6:EPM:EPM-g-MA), the elastomer was finely distributed with the average particle size of $0.56{\mu}m$. The Izod impact strength of this blend was the highest of all blends prepared with different elastomer content.

• Computers and Concrete
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• v.30 no.2
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• pp.99-111
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• 2022

In this study, deep learning and k-Nearest Neighbor (kNN) models were used to estimate the sorptivity and freeze-thaw resistance of self-compacting mortars (SCMs) having binary and ternary blends of mineral admixtures. Twenty-five environment-friendly SCMs were designed as binary and ternary blends of fly ash (FA) and silica fume (SF) except for control mixture with only Portland cement (PC). The capillary water absorption and freeze-thaw resistance tests were conducted for 91 days. It was found that the use of SF with FA as ternary blends reduced sorptivity coefficient values compared to the use of FA as binary blends while the presence of FA with SF improved freeze-thaw resistance of SCMs with ternary blends. The input variables used the models for the estimation of sorptivity were defined as PC content, SF content, FA content, sand content, HRWRA, water/cementitious materials (W/C) and freeze-thaw cycles. The input variables used the models for the estimation of sorptivity were selected as PC content, SF content, FA content, sand content, HRWRA, W/C and predefined intervals of the sample in water. The deep learning and k-NN models estimated the durability factor of SCM with 94.43% and 92.55% accuracy and the sorptivity of SCM was estimated with 97.87% and 86.14% accuracy, respectively. This study found that deep learning model estimated the sorptivity and durability factor of SCMs having binary and ternary blends of mineral admixtures higher accuracy than k-NN model.

• Polymer(Korea)
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• v.24 no.5
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• pp.682-689
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• 2000

The information related to the interaction energy between repeat units is essential for the production of useful polymer blends via molecular structure design. Based on the interaction energies obtained here, a method for the fabrication of miscible blend was suggested. An investigation related to the equilibrium phase behavior of polymer blends of various polycarbonates with various polymethacrylates was performed and then based on the obtained interaction information miscible polymer blends were produced by controling molecular structure of polymer. Binary interaction energies between repeat units were calculated from the lower critical solution temperature-type phase boundary using an equation of state combined with binary interaction model.

• Polymer(Korea)
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• v.26 no.6
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• pp.737-744
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• 2002

Thermodynamic miscibility of the binary blends composed of semi-crystalline poly (butylene 2,6-naphthalate) (PBN) and amorphous poly (4-vinylphenol) (PVPh) was investigated using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. DSC scan results showed that there was a single glass transition temperature (T$\_$g/) for each blend. Crystalline melting temperature (T$\_$m/) depression of the PBN in the blends was also observed with the increase of PVPh content. Both results of the single T$\_$g/ and the depression of T$\_$m/ for the PBN/PVPh blends indicate that the blends are thermodynamically miscible at the molecular level. FTIR spectroscopic analysis confirmed that strong intermolecular hydrogen bonding interactions between the ester carbonyl groups of the PBN and the hydroxyl groups of the PVPh are occurred.

• Korea-Australia Rheology Journal
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• v.17 no.2
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• pp.71-77
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• 2005

We investigated thermal, rheological, morphological and mechanical properties of a binary blend of poly(lactic acid) (PLA) and poly(butylene succinate adipate) (PBSA). The blends were extruded and their molded properties were examined. DSC thermograms of blends indicated that the thermal properties of PLA did not change noticeably with the amount of PBSA, but thermogravimetric analysis showed that thermal stability of the blends was lower than that of pure PLA and PBSA. Immiscibility was checked with thermal data. The rheological properties of the blends changed remarkably with composition. The tensile strength and modulus of blends decreased with PBSA content. Interestingly, however, the impact strength of PLA/PBSA (80/20) blend was seriously increased higher than the rule of mixture. Morphology of the blends showed a typical sea and island structure of immiscible blend. The effect of the blend composition on the biodegradation was also investigated. In the early stage of the degradation test, the highest rate was observed for the blend containing $80wt\%$ PBSA.