• Title/Summary/Keyword: behavior diagram

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Investigations of the Phase Behavior of N-dodecanocyl-N-methyl amido polyol carboxyl alkyl ether/N-dodecanocyl-N-alkyl Glucamine/Water System (N-도데카노실-N-메틸 아미도 폴리올 카르복시 알킬 에테르/(N-도데카노실-N-알킬 글루카민)/물계에서의 상거동 관찰)

  • Kang, Yun-Seog;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.23-28
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    • 1997
  • The phase diagram for the surfactant mixture system of N-dodecanocyl-N-methyl amido polyolcarboxyl alkyl ether(DGC)/N-dodecanocyl-N-alkyl glucamine(DG)/water was studied usingpolarized microscopy, differential scanning calorimetry(DSC) and rheological measurements respectively. Using polarized microscopy, the textures of liquid crystal phases obtained at various surfactantconcentrations were investigated as a function of surfactant concentration and temperature, and phasetransitions between anisotropic liquid crystal phases and isotropic liquid phase were examined usingDSC measurements. Viscoelastic properties of surfactant solutions determined between hexagonal andlamellar liquid crystal phase by rheological measurements were approximately consistent with the resultsobtained by polarized microscopy and DSC. In the study for the phase of DGC/DG(5:5 mol ratio)/water system. It could be found that the hexagonal liquid crystal phase appeared at 25${\sim}$60wt% ofsurfactant, the cubic liquid crystal phase at 50${\sim}$65wt% and the lamellar crystal phase at above 70wt%.

Selective Extraction of Cobalt and Nickel in the Presence of Magnesium from Sulphate Solutions by Versatic Acid 10 (마그네슘이 함유된 황산용액에서 Versatic acid-10에 의한 코발트와 니켈의 선택적 추출)

  • Cho, Yeon chul;Ahn, Jae woo;Lee, Jae young
    • Resources Recycling
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    • v.29 no.4
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    • pp.51-57
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    • 2020
  • Separation of Co and Ni over Mg from the sulfuric acid solutions using Cyanex272, PC88A and Versatic acid 10 as an extractant was carried out. From the comparative studies about the extraction behavior of Co, Ni and Mg, Versatic acid 10 was superior to Cyanex272 and PC88A for the selective extraction of cobalt and nickel from the mixed solutions. About 98% of Ni and Co were extracted at equilibrium pH 7.0 and less than 5% of Mg was co-extracted by Versatic acid 10. McCabe-Thiele diagram indicated two stages requirement for Co and Ni extraction by 10% Versatic acid 10 at pH 7.0 and phase ratio (A/O) of 2.0. The loaded Co and Ni in organic phase was stripped effectively the sulfuric acid concentration above 70 g/L. 99.78% of cobalt and 98.42% of nickel were stripped.

Effect of bond slip on the performance of FRP reinforced concrete columns under eccentric loading

  • Zhu, Chunyang;Sun, Li;Wang, Ke;Yuan, Yue;Wei, Minghai
    • Computers and Concrete
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    • v.24 no.1
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    • pp.73-83
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    • 2019
  • Concrete reinforced with fiber reinforced polymer (FRP) bars (FRP-RC) has attracted a significant amount of research attention in the last three decades. A limited number of studies, however, have investigated the effect of bond slip on the performance of FRP-RC columns under eccentric loading. Based on previous experimental study, a finite-element model of eccentrically loaded FRP-RC columns was established in this study. The bondslip behavior was modeled by inserting spring elements between FRP bars and concrete. The improved Bertero-Popov-Eligehausen (BPE) bond slip model with the results of existing FRP-RC pullout tests was introduced. The effect of bond slip on the entire compression-bending process of FRP-RC columns was investigated parametrically. The results show that the initial stiffness of bond slip is the most sensitive parameter affecting the compression-bending performance of columns. The peak bond stress and the corresponding peak slip produce a small effect on the maximum loading capacity of columns. The bondslip softening has little effect on the compression-bending performance of columns. The sectional analysis revealed that, as the load eccentricity and the FRP bar diameter increase, the reducing effect of bond slip on the flexural capacity becomes more obvious. With regard to bond slip, the axial-force-bending-moment (P-M) interaction diagrams of columns with different FRP bar diameters show consistent trends. It can be concluded from this study that for columns reinforced with large diameter FRP bars, the flexural capacity of columns at low axial load levels will be seriously overestimated if the bond slip is not considered.

Photoelectrochemical Behavior of Cu2O and Its Passivation Effect (산화구리의 광전기화학적 거동 특성)

  • Yun, Hongkwan;Hong, Soonhyun;Kim, Dojin;Kim, Chunjoong
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.1-6
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    • 2019
  • Recent industrialization has led to a high demand for the use of fossil fuels. Therefore, the need for producing hydrogen and its utilization is essential for a sustainable society. For an eco-friendly future technology, photoelectrochemical water splitting using solar energy has proven promising amongst many other candidates. With this technique, semiconductors can be used as photocatalysts to generate electrons by light absorption, resulting in the reduction of hydrogen ions. The photocatalysts must be chemically stable, economically inexpensive and be able to utilize a wide range of light. From this perspective, cuprous oxide($Cu_2O$) is a promising p-type semiconductor because of its appropriate band gap. However, a major hindrance to the use of $Cu_2O$ is its instability at the potential in which hydrogen ion is reduced. In this study, gold is used as a bottom electrode during electrodeposition to obtain a preferential growth along the (111) plane of $Cu_2O$ while imperfections of the $Cu_2O$ thin films are removed. This study investigates the photoelectrochemical properties of $Cu_2O$. However, severe photo-induced corrosion impedes the use of $Cu_2O$ as a photoelectrode. Two candidates, $TiO_2$ and $SnO_2$, are selected for the passivation layer on $Cu_2O$ by by considering the Pourbaix-diagram. $TiO_2$ and $SnO_2$ passivation layers are deposited by atomic layer deposition(ALD) and a sputtering process, respectively. The investigation of the photoelectrochemical properties confirmed that $SnO_2$ is a good passivation layer for $Cu_2O$.

Effect of flexural and shear stresses simultaneously for optimized design of butterfly-shaped dampers: Computational study

  • Farzampour, Alireza;Eatherton, Matthew R.;Mansouri, Iman;Hu, Jong Wan
    • Smart Structures and Systems
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    • v.23 no.4
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    • pp.329-335
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    • 2019
  • Structural fuses are made up from oriented steel plates to be used to resist seismic force with shear loading resistance capabilities. The damage and excessive inelastic deformations are concentrated in structural fuses to avoid any issues for the rest of the surrounding elements. Recently developed fuse plates are designed with engineered cutouts leaving flexural or shear links with controlled yielding features. A promising type of link is proposed to align better bending strength along the length of the link with the demand moment diagram is a butterfly-shaped link. Previously, the design methodologies are purely based on the flexural stresses, or shear stresses only, which overestimate the dampers capability for resisting against the applied loadings. This study is specifically focused on the optimized design methodologies for commonly used butterfly-shaped dampers. Numerous studies have shown that the stresses are not uniformly distributed along the length of the dampers; hence, the design methodology and the effective implementation of the steel need revisions and improvements. In this study, the effect of shear and flexural stresses on the behavior of butterfly-shaped links are computationally investigated. The mathematical models based on von-Mises yielding criteria are initially developed and the optimized design methodology is proposed based on the yielding criterion. The optimized design is refined and investigated with the aid of computational investigations in the next step. The proposed design methodology meets the needs of optimized design concepts for butterfly-shaped dampers considering the uniform stress distribution and efficient use of steel.

Response Characteristics of Forced Vibration of High Damping Vehicle Passing the Bumped Barrier (둔턱을 진행하는 고감쇠 차량의 강제진동 응답특성)

  • Kim, Jong-Do;Yoon, Moon-Chul
    • Journal of Convergence for Information Technology
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    • v.11 no.3
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    • pp.132-139
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    • 2021
  • The response characteristics of the forced vibration generated when the high-damped vehicle pass the bumped barrier was studied, and in particular, the response behavior of displacement, velocity and acceleration was analyzed for the forced vibration model. In addition, in order to obtain responses such as displacement, velocity, and acceleration, a numerical analysis technique of the Runge-Kutta-Gill method was performed in time domain. The response was successfully obtained in detail under several high damping conditions. As a numerical analysis result, the response of the vehicle was obtained by considering the vehicle body to which the impulse impact was applied. Also, the analysis result was compared with the experimental result in order to verify the validity of vehicle model. The amplitude and natural frequency of the vehicle were considered and analyzed. The Nyquist diagram of the vehicle model was also obtained and the relationship could be analyzed. And the vibration response was analyzed on different mass, damping and stiffness.

Simulation study on the mechanical properties and failure characteristics of rocks with double holes and fractures

  • Pan, Haiyang;Jiang, Ning;Gao, Zhiyou;Liang, Xiao;Yin, Dawei
    • Geomechanics and Engineering
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    • v.30 no.1
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    • pp.93-105
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    • 2022
  • With the exploitation of natural resources in China, underground resource extraction and underground space development, as well as other engineering activities are increasing, resulting in the creation of many defective rocks. In this paper, uniaxial compression tests were performed on rocks with double holes and fractures at different angles using particle flow code (PFC2D) numerical simulations and laboratory experiments. The failure behavior and mechanical properties of rock samples with holes and fractures at different angles were analyzed. The failure modes of rock with defects at different angles were identified. The fracture propagation and stress evolution characteristics of rock with fractures at different angles were determined. The results reveal that compared to intact rocks, the peak stress, elastic modulus, peak strain, initiation stress, and damage stress of fractured rocks with different fracture angles around holes are lower. As the fracture angle increases, the gap in mechanical properties between the defective rock and the intact rock gradually decreased. In the force chain diagram, the compressive stress concentration range of the combined defect of cracks and holes starts to decrease, and the model is gradually destroyed as the tensile stress range gradually increases. When the peak stress is reached, the acoustic emission energy is highest and the rock undergoes brittle damage. Through a comparative study using laboratory tests, the results of laboratory real rocks and numerical simulation experiments were verified and the macroscopic failure characteristics of the real and simulated rocks were determined to be similar. This study can help us correctly understand the mechanical properties of rocks with defects and provide theoretical guidance for practical rock engineering.

Growth and characterization of a Bi-Sr-Ca-Cu-O phase by crystal pulling method (Crystal pulling법에 의한 Bi-Sr-Ca-Cu-O계의 결정 성장과 특성 평가)

  • Yoon, D.H.;Sato, N.;Yoshimoto, N.;Yoshizawa, M.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.1-5
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    • 1997
  • The $Bi_2Sr_2Ca_{n-1}Cu_nOy$(BSCCO) phase is well known to be a superconductor having a strong anisotropic behavior. It can be seen that it is difficult to control the growth direction. In this study, we try to grow a Bi-Sr-Ca-Cu-O phase crystal by the crystal pulling method with a seed crystal and crucibel rotation. Relatively large crystals of the order of $5{\times}5{\times}5{\textrm}{mm}^3$ dimensions can be obtained. We also discuss the possible crystallization field of the $BiO_{1.5}$-(Sr, Ca)O-CuO ternary phase diagram, and present some results of the characterization and magnetic measurements on the grown crystal.

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Numerical analysis and eccentric bearing capacity of steel reinforced recycled concrete filled circular steel tube columns

  • Ma, Hui;Liu, Fangda;Wu, Yanan;Cui, Hang;Zhao, Yanli
    • Advances in concrete construction
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    • v.13 no.2
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    • pp.163-181
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    • 2022
  • To study the mechanical properties of steel reinforced recycled concrete (SRRC) filled circular steel tube columns under eccentric compression loads, this study presents a finite element model which can simulate the eccentrically compressed columns using ABAQUS software. The analytical model was established by selecting the reasonable nonlinear analysis theory and the constitutive relationship of materials in the columns. The influences of design parameters on the eccentric compressive performance of columns were also considered in detail, such as the diameter-thickness ratio of circular steel tube, replacement percentage of recycled coarse aggregate (RCA), slenderness ratio, eccentricity, recycled aggregate concrete (RAC) strength and steel strength and so on. The deformation diagram, stress nephogram and load-displacement curves of the eccentrically compressed columns were obtained and compared with the test results of specimens. The results show that although there is a certain error between the calculation results and the test results, the error is small, which shows the rationality on the numerical model of eccentrically compressed columns. The failure of the columns is mainly due to the symmetrical bending of the columns towards the middle compression zone, which is a typical compression bending failure. The eccentric bearing capacity and deformation capacity of columns increase with the increase of the strength of steel tube and profile steel respectively. Compared with profile steel, the strength of steel tube has a greater influence on the eccentric compressive performance of columns. Improving the strength of RAC is beneficial to the eccentric bearing capacity of columns. In addition, the eccentric bearing capacity and deformation capacity of columns decrease with the increase of replacement percentage of RCA. The section form of profile steel has little influence on the eccentric compression performance of columns. On this basis, the calculation formulas on the nominal eccentric bearing capacity of columns were also put forward and the results calculated by the proposed formulas are in good agreement with the test values.

A Study on Prediction of Overriding Behavior Leading Vehicle in Train Collision (철도차량 충돌시 선두차량의 타고오름량 예측 연구)

  • Kim, Jun Woo;Koo, Jeong Seo;Kim, Geo Young;Park, Jeong Pil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.8
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    • pp.711-719
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    • 2016
  • In this study, we derived an theoretical equation, using a simplified spring-mass model for the rolling stock, to obtain the overriding behavior of a leading vehicle, which is considered as the main factor in train accidents. To verify the derived equation, we created a simple 2D model based on the theoretical model, and a simple 3D model considering the characteristics of the power bogie. We then compared the theoretical results with the simulation results obtained using LS-DYNA. The maximum relative derivations in the vertical displacements at the first end-buffer, which is the most important point in overriding, were 3.5 [%] and 1.7 [%] between the two results. Further, we evaluated collision-induced overriding displacements using the theoretical equation for a rubber draft gear, a hydraulic buffer under various collision conditions. We have suggested a theoretical approach for the realization of overriding collision accidents or the energy absorption design of the front end of trains.