• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.3
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• pp.66-72
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• 2011

The annals of Joseon Dynasty is one of UNESCO's Memory of the World Register. For the safety preservation of the waxed annals of Joseon Dynasty, the acidic and alkaline aging mechanism of beeswax and beeswaxed Hanji has been investigated. The weight loss of beeswaxed Hanji by the acidic aging was higher than those of alkaline beeswax. The acid value and relative intensity of carbonyl groups in beeswax were slowly increased with aging time. The strength of dewaxed Hanji was decreased with aging time. The significant changes of crystallinity of dewaxed Hanji by acidic and alkaline aging were not observed.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.3
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• pp.73-79
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• 2011

The annals of Joseon Dynasty is one of the UNESCO's Memory of the World Register. For the safety preservation of wax applied volumes of the annals of Joseon Dynasty, the aging behavior of beeswax and beeswaxed Hanji with $CO_2$, $O_3$, $SO_2$ and $NO_2$ gas has been evaluated. The weight loss of beeswaxed Hanji after aging under ozone gas were increased because of strong acidity of ozone. The acid value and relative intensity of carbonyl groups in beeswax were stabilized with aging time. The physical strength of dewaxed Hanji after ozone aging were rapidly decreased by aging time. The crystallinity of dewaxed Hanji were stabilized at all aging times.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.3
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• pp.58-66
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• 2010

The Annals of beeswax applied-Joseon Dynasty have some serious damages such as cracks, brown, red or black spots, and discolorations by chemical and biological degradation, but others without any beeswax application have still been keeping good quality during over several hundred years. It would be convinced that the beeswax applied in the Annals resulted in these deteriorations. Therefore, in order to focus on the aging mechanism and conservation techniques for the beeswax-applied Annals of Joseon Dynasty, the beeswax applying and dewaxing techniques of Hanji were tried by auto bar coater with a hot plate, and by heat-pressure sensitive extracting treatments. The ageing behaviors of beeswaxed Hanji and dewaxed Hanji were investigated by measuring the changes of physical, optical, morphological, and chemical properties, through accelerated ageing treatment in dry oven at $150^{\circ}C$ during 48 hours. Consequently, the ageing actions of beeswaxed Hanji were even faster than that of Hanji. The optimum dewaxed amounts from beeswaxed Hanji was also obtained in pressure of $40\;kg_f$ under heating conditions.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.2
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• pp.46-52
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• 2010

The annals of Joseon Dynasty has been known as one of the UNESCO's Memory of the World Heritage. The annals of Joseon Dynasty composed with two kind of books, wax coated book and non coated book. Especially the waxed book have been severely damaged by various reason. For the safety preservation of the annals of Joseon Dynasty waxed book, the thermal ageing mechanism of beeswax coated Hanji paper has been evaluated. The weight loss of waxed Hanji were rapidly increased until 30 days in three temperatures(105, 120 & $150^{\circ}C$) and stabilized after 30 days. The acid value and relative intensity of carbonyl groups in beeswax were increased with strong conditions. This means that the deterioration of beeswax should be progressed with oxidizing reaction. The physical strength and the crystallinity of dewaxed Hanji were decreased with ageing time.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.04a
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• pp.207-215
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• 2011