• Title/Summary/Keyword: batch tests

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Black shale as an effective sorbent of Trichloroethylene (Black shale을 이용한 유기 오염물질인 TCE의 흡착 제거에 관한 연구)

  • 민지은;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.246-249
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    • 2002
  • Black shale that has relatively high organic carbon content was tested to determine its sorption phenomena and capacity for TCE. Conventional batch sorption tests were peformed at room temperature. The parameters that were thought to affect the TCE sorption were solution pH and dissolved organic matter. The effect of solution pH on TCE sorption was minimal, but the dissolved organic matter increased the amount of TCE sorbed on black shale. Thus, using black shale as sorbent for TCE in groundwater could save material costs by replacing high cost conventional activated organic carbon.

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Using Waste Foundry Sands as Reactive Media in Permeable Reactive Barriers

  • 이태윤;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.62-65
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    • 2002
  • Permeable reactive barriers (PRBs) are in-situ barriers constructed in a subsurface to treat contaminated groundwater using various reactive media. The common reactive medium used in PRB is zero-valent iron, which has been widely used to treat chlorinated solvents (i.e., PCE, TCE). A disadvantage of iron media is high cost. In this study, waste foundry sands were tested to determine the feasibility of their use as a low cost reactive medium. Batch and column tests were conducted with TCE to determine transport parameters and reactivity of the foundry sands. The reactivities of foundry sands for common groundwater contaminants are comparable to or slightly higher than those for Peerless iron, a common medium used in PRBs. In addition, the TOC and clay in foundry sands can significantly retard the movement of target contaminant, which may result in lower effluent concentration of contaminant due to biodegradation. In general, PRBs 1-m thick can be constructed with many foundry sands to treat TCE provided the zero-valent iron content in the foundry sand is higher than 1%.

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A Study on the Mechanical Property Evaluation of Carbon/Epoxy Composite Material for Aerospace Application (우주항공용 탄소/에폭시 복합재료의 기계적 특성 평가에 관한 고찰)

  • Lee, Ho-Sung;Min, Kyung-Ju
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.149-149
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    • 2003
  • This paper presents the work peformed in a program developing composite material which properties satisfy structural and thermal requirements for aircrafts and spacecrafts. In the aerospace vehicle structures, the specific strength of the materials is one of the important requirements and this is why polymer matrix composite material with reinforced carbon fiber is widely used. However, the mechanical properties of the composite material have been known to be dependent on processing and this difficulties in evaluation have caused a lot of mechanical tests for each batch.

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Study on the Long-term Change of nitrogen in the Tidal Area of River (하천 감조부에 있어서 질소의 장기변동에 관한 연구)

  • 김원규;강주복
    • Water for future
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    • v.25 no.2
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    • pp.67-78
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    • 1992
  • Several field surveys were conducted to investigate changes of water quality with time in a tidal river. Results indicated that nitrification process were dependent on the change of salinity and suspended solids concenttration. Therefore laboratory batch experiments were conducted, using suspended solids and sediment taken from a tidal river, to study the effect of salinity on nitrification and to estimate kinetic parameters of it in the tidal river. suspended solids and sediment were sampled at a point in the middle stream. Sediments were collect from the aerobic layer of mud. The change of nitrogen concentration with time was clearly explained with Monod groth model and kinetic parameters were obtained by curve fitting method. Changes in NH4-N, NO2-N, and NO3-N concentrations in the river ROKKAU with time were simulated well using Lagrangian reference frame and parameter values obtained in the laboratory tests. T도 mechanism of nitrification by suspended solids and sediment in a tidal river is shown to depend on tidal effects.

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Recycling of Casts as an Adsorbent for Phosphorous Removal (인제거를 위한 흡착제로써 분변토 재활용)

  • 손희정;김은호;이용희
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.76-81
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    • 1998
  • The technology of removing phosphorous, considered as one of the most important control nutrients causing eutrophication in various water bodies, have been investigated by many researchers. In this study, casts which can be obtained from the vermicomposting of mixing sewage sludge and cow manure, were used as an adsorbent, and their effects of several physical/chemical factors on the efficiencies of phosphorous adsorption were examined by batch tests. Generally, it could be showed that the efficiencies of phosphorous adsorption were very influenced by cast dosage, temperature and agitation speed. If we reflected the adsorption capacity(k) and adsorption intensity(1/n) of Freundlich isotherm, we couldn't consider casts as a good adsorbent for removing phosphorous. But, because casts were relatively excellent in cation exchange, in point of waste recycling, we could know that they were capable of removing phosphorous. The SEM observation revealed that the evident variations were hardly seen, but particle sizes of cast were relatively bigger and showed forms of smaller plate than before.

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A Study on Prediction of Early-Age Concrete Strength by Maturity Concept(II) (콘크리트 조기강도 예측을 위한 합리적인 기법 연구(II))

  • 오병환;채성태;이명규;김광수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.124-128
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    • 1995
  • It is the "maturity rule" that concrete of the same mix, at the same maturity, has the same strength. In this study, the Nurse-Saul function which was proposed to account for the effects of temperature and time on strength development is used in computing maturity. After existing various functions to relate concrete strength to the maturity value are considered, new strenth-maturity function is proposed. Tests are conducted in order to compare prediction value with measured concrete strength. The constants in proposed prediction equation are determined by standard specimens(cylinders) test, and the equation is adopted to predict strength of slab. The slab was cast in the laboratory from the same batch of mole, and cores are cut from slab in order to estimate the actual strength. Tehese values are used to compare with proposed equation. equation.

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Reductive Dechlorination of Chlorinated Oraganic Compounds Using Zero-Valent Iron (0가 철분을 이용한 유기염소화합물의 환원적 탈염소화)

  • Lee, Chang-soo;Bae, Woo-keun
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.4
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    • pp.427-432
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    • 2001
  • The purpose of study is to examine the sensitivity of the rate of degradation to initial TCE concentration and iron concentration in the solution. The batch tests were executed to assess the degradation rate at varying initial conditions. First order rate constants($k_a$) were more rapid with the lower initial TCE concentration, Howere the correleation was not always linear between $k_a$ and initial TCE concentration. $k_a$ was proportionally increased as the increasing surface area. It implied that the effective reactive surface area acted as the limiting factor on the reductive dechlorination of TCE by iron.

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Solubilization of Sewage Sludge by Microwave Pretreatment and Elutriated Acid Fermentation (Microwave를 이용한 하수슬러지의 전처리 특성 및 회분식 세정산발효를 이용한 슬러지 가용화)

  • Lee, Won-Sic;Hong, Seung-Mo;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.1130-1136
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    • 2006
  • This work elucidates the effects of pretreatment of the sewage sludge from wastewater treatment plant by microwave irradiation on elutriated acid fermentation. These experiments typically fell into two process; pretreatment as microwave irradiation and elutriated acid fermentation for hydrolysis and acidification as main process of primary sludge. The results of maximum solubilization rate of B, D primary and secondary sludge were 0.042, 0.086 and 0.15 gSCODprod./gICODin and the optimum irradiation time of microwave on 2,450 MHz and 900 W were 5 min. for primary sludge and 7 min. for secondary sludge. From batch tests on elutriated acid fermentation that was used the pretreated primary sludge as microwave, the optimum pH and HRT (hydraulic retention time) were 7 and 5 days at $35^{\circ}C$ condition.

The Effect of Phosphate Desorption Solution on LDH (Layered Double Hydroxide) Desorption (탈착 용액의 조성변화가 층상이중수산화물에 흡착된 인 탈착에 미치는 영향)

  • Jung, Yong-Jun
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.670-675
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    • 2008
  • Batch type adsorption and desorption tests were performed with different types (Powder, Granule) of Layered double hydroxides (LDHs) saturated with phosphate. The adsorption isotherm was approximated as a modified Langmuir type equation. The maximum adsorption capacity was 55 mg-P/g-LDH for powder type LDH, and 46 mg-P/g-LDH for granule type LDH. The highest phosphate desorption (79.6%) was obtained with 20% NaOH solution, whereas the desorption degrees were 4.8, 22.2% and 46.7% in the solutions of acidic condition (pH 4), 30% NaCl, and 3% NaOH, respectively. It was suggested that the optimal condition for the phosphate desorption from LDH was 30% NaCl + 3~6% NaOH solutions. The desorption characteristics of LDH was little influenced by adsorbent type.

복합오염물질 처리를 위한 Hybrid PRB System

  • 김상태;강완협;문희선;민지은;조종수;박주양;김재영;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.129-132
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    • 2004
  • A hybrid permeable reactive barriers(hybrid PRBs) composed of Fe(II) PRB, biological PRB and sorptive PRB was investigated to treat groundwater with multiple contaminations. We performed batch, column and pilot tests to determine removal rates and design parameters of each PRB media, and operated two hybrid PRB systems with pilot-scale barriers in series. The pilot test of the hybrid PRB system with the combination of Fe(II), biological media and black shale showed multiple contaminations could be removed in ground water. Nitrate could be treated below 20 mg/L and Cr(VI) was treated down to 0.05 mg/L. TCE was degraded below 0.001 mg/L in system. The hybrid PRB system with a proper combination of PRBs could remediate ground water with multiple contaminations.

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