• 대한환경공학회지
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• 제37권4호
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• pp.228-233
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• 2015

본 연구에서는 회분식 실험 및 $A^2/O$ 공법의 연속식 실험으로 아연이 생분해, 산소 소모율, 질산화 및 탈질에 미치는 영향을 검토하였다. 본 연구의 결과를 요약하면 다음과 같다. 아연 영향 실험 결과 유기물 분해는 회분식 실험의 경우 아연 농도 12 mg/L까지 영향을 미치지 않았으며, 연속식 실험의 경우 아연 농도 3.0 mg/L 이상일 때 생분해성이 낮아졌다. 질산화 및 질소 제거의 경우 회분식은 아연 농도 6.0 mg/L 이상일 때 질산화율이 낮아졌으며, 연속식의 경우 아연 농도 3.0 mg/L 이상일 때는 질소 제거율이 낮아졌다. 인 제거의 경우 회분식은 아연 농도 6.0 mg/L, 연속식은 아연 농도 3.0 mg/L 이상일때 인 제거율이 낮아지는 것으로 나타났다. 산소 소모율의 경우 연속식의 아연 농도가 3.0 mg/L 이상이면 미생물 활성에 영향을 주어 산소 소모율이 낮아졌다.

• 상하수도학회지
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• 제8권3호
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• pp.1-8
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• 1994

In the general process of design for aerobic digestion, the design for field plant of which inflow pattern is continuous inflow is performed using the results from lab scale batch reactor. However, the recent researchers reported that the general designs were performed as over-estimated, Therefore, in this study, laboratory batch experiments were carried out at $20^{\circ}C$ and pH 7.5 on the aerobic digestion of waste activated sludge at different solid levels. This treatise could consider the negligence about effective digestion periods the usage of VSS as solid concentration, and the effect of initial solid concentration of solid degration rate coefficient($k_d$) as reasons of the overestimated design, and showed the scheme of how to design for aerobic digestion from batch experiment.

• Biotechnology and Bioprocess Engineering:BBE
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• 제8권5호
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• pp.291-293
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• 2003

Batch reactors were employed to investigate the kinetics of cellulose hydrolysis under extremely low acid (ELA) and high temperature condition. The sawdust was pretreated by Auto-hydrolysis prior to the batch reaction. The maximum yield of glucose obtained from the batch reactor experiment was about 70% for the pretreated sawdust, this occurred at 210 and 22$0^{\circ}C$. The maximum glucose yield from the untreated sawdust was much lower at these temperatures, about 55%. The maximum yields of glucose from the lignocellulosics were obtained between 15th and 20th minutes after which gradual decrease was observed.

• 한국물환경학회지
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• 제18권2호
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• pp.169-187
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• 2002

The effects of important parameters such as reaction time and pH on the Fenton's process were evaluated using a batch reactor. It was proven that organic materials and heavy metals in leachate could be successfully removed by Fenton's reagent. Favorable operation conditions were investigated. It was observed that the reaction between ferrous iron and hydrogen peroxide with the production of hydroxyl radical was almost complete in 10 minutes. That is, the oxidation of organic materials by Fenton's reagent was so fast that it was complete in 30 minutes with batch experiments. With the formation of carbonic acid, pH of the batch reactor decreased to favorable acidic conditions without acid addition. The oxidation of organic materials in the leachate showed a pH dependence and was most efficient in the pH range of 2-3.

• 산업기술연구
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• 제21권B호
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• pp.141-147
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• 2001

For the preparation of calcium carbonate particles from aqueous $Ca(OH)_2$ slurry, carbonation reaction of aqueous $Ca(OH)_2$ slurry was carried out by batch method the $CO_2$ into reactor filled with aqueous slurry of $Ca(OH)_2$. The concentration of $Ca(OH)_2$ varies from 1.00 to 7.00wt%, reactor temperature at 20 and $40^{\circ}C$, and reactor pressure from atmospheric pressure to $6.0kg_f/cm^2$. Crystal structure of calcium carbonate was of calcite, the particle size were about $0.05{\sim}2.0{\mu}m$, and the particle shape was cubic and spindle. When reactor temperature was higher, particle size of calcium carbonate was bigger and particle shape was varied, but reaction rate was increased. When reactor pressure was higher, particle size of calcium carbonate was smaller, particle shape was cubic, and reaction rate was increased.

• Transactions on Control, Automation and Systems Engineering
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• 제4권1호
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• pp.62-74
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• 2002

The tracking of a reference temperature trajectory in a polymerization batch reactor is a common problem and has critical importance because the quality control of a batch reactor is usually achieved by implementing the trajectory precisely. In this study, only energy balances around a reactor are considered as a design model for control synthesis, and material balances describing concentration variations of involved components are treated as unknown disturbances, of which the effects appear as time-varying parameters in the design model. For the synthesis of a tracking controller, a method combining the input-output linearization of a time-variant system with the parameter estimation is proposed. The parameter estimation method provides parameter estimates such that the estimated outputs asymptotically follow the measured outputs in a specified way. Since other unknown external disturbances or uncertainties can be lumped into existing parameters or considered as another separate parameters, the method is useful in practices exposed to diverse uncertainties and disturbances, and the designed controller becomes robust. And the design procedure and setting of tuning parameters are simple and clear due to the resulted linear design equations. The performances and the effectiveness of the proposed method are demonstrated via simulation studies.

• 상하수도학회지
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• 제22권5호
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• pp.581-587
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• 2008

In this study, we investigated the buffering effect with different COD, $NH_4{^+}-N$ and TP shock loads on the performance of lab-scale Sequencing Batch Reactor(SBR) using synthetic wastewater. This study was operated under the following conditions : HRT, 12 hrs : MLSS, 2,000 mg/L : F/M ratio, $0.2kgCOD/kgMLSS{\cdot}d$ : SRT, 20days, and was increased by a factor, COD : ranging from 200-2000 mg/L, $NH_4{^+}-N$ : ranging from 30-300 mg/L, T-P : ranging from 5-50 mg/L in the reactor. As results, COD removal rate at different shock loads was decreased until 42.1%(stable state : 95%) and concentration with effluent was higher than 695 mg/L(at Run 6). In case of $NH_4{^+}-N$ removal rate was decreased until 35.8% from 97.0% and also T-P removal rate was decreased until 5.0%. Effluent concentrations of COD, $NH_4{^+}-N$ and T-P were rapidly increased according to shock loads and needed 3, 4 and 6 additional cycle times for recovering the stable condition.

• 한국환경과학회지
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• 제9권6호
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• pp.463-468
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• 2000

Ther effect of UV on the mortality rate of toxic dinoflagellate Amphidinium Carterae causing a red tide in the coastal area of korea was investigated in the batch and continuous-scale reactor equipped with ultraviolet irradiation-apparatus. Degussa P(sub)25 titanium oxide, a photocatalyst proved to be effective of the mortality of Amphidinium Carterae supplied with photocatalyst and UV radiation were greater than 95% in 2 minutes of UV radiation and the rate were higher than that by UV-radiation without titanium dioxide in the batch and continuous-flow scale reactor, The mortality time of Amphidinium Carterae increased with the cell density under UV-illumination in the batch scale reactor. The mortality rate in the density of $5.0$\times$10^4$ cell/mL at the same experimental condition was more than 90% in 4 minutes in the continuous flow scale reactor. The percentage of 99.9$\pm$0.1% of Amphidinium Carterae in the density of $0.5$\times$10^4$ cells/mL was died in 20 minutes when the phytoplankton was illuminated with UV-radiation without photocatalyst.

• Environmental Engineering Research
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• 제13권4호
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• pp.177-183
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• 2008

Ex-situ reductive dechlorination of carbon tetrachloride (CT) by iron sulfide in a batch reactor was characterized in this study. Reactor scaled-up by 3.5 L was used to investigate the effect of reductant concentration on removal efficiency and process optimization for ex-situ degradation. The experiment was conducted by using both liquid-phase and gas-phase volume at pH 8.5 in anaerobic condition. For 1 mM of initial CT concentration, the removal of the target compound was 98.9% at 6.0 g/L iron sulfide. Process optimization for ex-situ treatment was performed by checking the effect of transition metal and mixing time on synthesizing iron sulfide solution, and by determining of the regeneration time. The effect of Co(II) as transition metal was shown that the reaction rate was slightly improved but the improvement was not that outstanding. The result of determination on the regeneration time indicated that regenerating reductant capacity after $1^{st}$ treatment of target compound was needed. Due to the high removal rates of CT, ex-situ reductive dechlorination in batch reactor can be used for basic treatment for the chlorinated compounds.

• 한국환경과학회지
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• 제1권2호
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• pp.125-136
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• 1992

Digestion of a municipal wastewater sludge by the anaerobic sequencing batch reactor (ASBR) was investigated to evaluate the performance of the ASBR process at a critical condition of high-solids-content fined. The reactors were operated at an HRT of 10 days with an equivalent loading rate of 0.8-1.5 gVS/L/d at 35$^{\circ}C$ The main conclusions drawn from this study were as follows: 1. Digestion of a municipal wastewater sludge was possible using the ASBR in spite of high concentration of settleable solids in the sludge. The ASBRS with 3- and 4-day cycle period showed almost identical high digestion performances. 2. No adverse effect on digestion stability was observed In the ASBRS in spite of withdrawal and replenishment of 30% or 40% of liquid contents. A conventional anaerobic digester could be easily converted to the ASBR without any stability problem. 3. Flotation thickening occurred in thicken step of the ASBRS throughout steady state, and floating bed volume at the end of thicken period occupied about 70% of the working volume of the reactor Efficiency of flotation thickening in the ASBRS could be comparable to that of additional gravity thickening of a completely mixed digester. 4. Solids were accumulated rapidly in the ASBR during start-up period. Solids concentrations in the ASBRS were 2.6 times higher than that in the completely mixed control reactor at steady state. Dehydrogenase activity had a strong correlation with the solids concentration. Dehydrogenase activity of the digested flu형e in the ASBR was 2.9 times higher than that of the flu형e in the control reactor, and about 25 times higher than that of the subnatant in the ASBR. 5. Remarkable increase in equivalent gas production of 52% was observed at the ASBRS compared with the control reactor in spite of similar quality of clarified effluent from the ASBRS and control reactor. The increase in gas production from the ASBRS was believed to be combined results of accumulation of microorganisms, higher driving force applied, and additional long-term degradation of organics continuously accumulated.