• Title/Summary/Keyword: basis conversion

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Enantiospecific separation in biphasic Membrane Reactors

  • Giorno, Lidietta
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.15-18
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    • 1998
  • Membrane reactors are systems which combine a chemical reactor with a membrane separation process allowing to carry out simultaneously conversion and product separation. The catalyst can be immobilized on the membrane or simply compartmentalized in a reaction space by the membrane. Membrane reactors are today investigated to produce optically pure isomers and/or resolve racemic mixture of enantiomers. The interest towards these systems is due to the increasing demand of enantiomerically pure compounds to be used in the pharmaceutical, food, and agrochemical industries. In fact, enantiomers can have different biological activities, which often influence the efficacy or toxicity of the compound. On the basis of current literature there are basically two schemes on the use of membrane technology to produce enantiomers. In one case, the membrane itseft is intrinsically enantioselective: the membrane is the chiral system which selectively separates the wanted isomer on the basis of its conformation. In the other, a kinetic resolution using an enantiospecific biocatalyst is combined with a membrane separation process; the membrane separates the product from the substrate on the basis of their relative chemical properties (i.e. solubility). This kind of configuration is widely used to carry out kinetic resolutions of low water soluble substrams in biphasic membrane reactors [Giomo, 1995, 1997; Lopez, 1997]. These are systems where enzyme-loaded membranes promote reactions between two separate phases thanks to the properties of enzymes, such as lipases, to catalyse reactions at the org ic/aqueous interface; the two phases are maintained in contact and separated at the membrane level by operating at appropriate transmembrane pressure. A schematic representation of biphasic membrane reactor is shown in figure 1, while an example of enantiospecific reaction and product separation carried out with these systems is reported in figure 2.

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Nitrogen Conversion Factors and in vitro Protein Digestibility of some Seaweeds (수종해조의 단백계수와 in vitro Digestibility)

  • Ryu Hong-Soo;SATTERLEE Lowell D.;LEE Kang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.4
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    • pp.263-270
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    • 1982
  • In an attempt to evaluate the nutritional quality of seaweed protein, the effects of heat treatment on the in vitro digestibility and trypsin inhibitor content in seaweed were determined. In this study, the nitrogen-to-protein conversion factors were also calculated on the basis of quantitative amino acid data. The results are as follows : 1. The in vitro protein digestbilty of red seaweeds (P. teoera anc P. suborbiculata) were ranged from 78.5 to 82.2, and green seawerd (E. linza) and brown seaweeds showed value under 80 in vitro digestibility. In general, trypsin inhibitor contents in brown seaweed were higher (0.33-0.54 mg/g) than those of red seaweeds (0.26-0.39 mg/g). And it is noted that the lowest trypsin inhibitor content was shown in green seaweed (E. linza) in spite of lowest in spite digestibility (78.5). 2. The in vitro protein digestibility of sun dried laver (P. tenera) was increased with cooling time (microwave heating), but it was not significant. Hot plate cooking raised the in vitro digestibility from 81. 1 to 84.5. The influence pot cooking time on trypsin inhibitor content was inversely proportional to in vitro digestibility. 3. Computed nitrogen factor, based on amino acid content (Factor method) and Kjeldahl nitrogen content (Kjeldahl mettled), were 5.83 (H. fusiforme)- 6.52 (P. tencra) as Factor method and 5.40 (U. pinnatifida)-6.29 (P. tenera) as Kjeldahl method. Individual value for each nitrogen conversion factor differed by species, especially in brown seaweeds. The best estimate of the protein content of seaweed can be calculated, from multiplying the summed amino acid content by conversion factor (Factor method).

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Performance analysis of an organic Rankine cycle for ocean thermal energy conversion system according to pinch point temperature difference (핀치포인트온도차에 따른 해양온도차발전용 유기랭킨사이클의 성능분석)

  • Kim, Jun-Seong;Kim, Do-Yeop;Kang, Ho-Keun;Kim, You-Taek
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.6
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    • pp.476-483
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    • 2016
  • An organic Rankine cycle for ocean thermal energy conversion system is a generating cycle using the temperature difference between surface water and deep water of the ocean. The working fluid is an important factor in the thermodynamic performance of an organic Rankine cycle. There is pinch point analysis as thermodynamic analysis of an organic Rankine cycle. This study performed a thermodynamic performance analysis according to variation in the pinch point temperature difference in heat exchangers and variation of outlet temperature of heat source and heat sink. It analyzed the thermodynamic performance by applying seven types of simple working fluids in a simple Rankine cycle for ocean thermal energy conversion that was designed according to pinch point analysis. As a result of the performance analysis, cycle irreversibility and total exergy destruction factor more decreased, and second law efficiency more increased in the lower pinch point temperature difference and temperature variation of heat source and heat sink in heat exchangers. In addition, the irreversibility changed greatly at a point that occurred in the thermodynamic variation. Among the selected working fluids, RE245fa2 showed the best thermodynamic performance, and the performance of all working fluids was observed to be similar. It needs a strict theoretical basis about diverse factors with thermodynamic performances in selecting heat exchangers and working fluids.

An analysis on the change rate of housing rent price index (월세가격동향조사 통계의 가격지수 변동률 분석)

  • Yeon, Kyu Pil
    • Journal of the Korean Data and Information Science Society
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    • v.25 no.6
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    • pp.1361-1369
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    • 2014
  • This research is for analyzing the change rate of housing rent price index produced by KAB (Korea Appraisal Board) in the monthly periodical, Survey on Housing Monthly Rent. The index is a very important and useful indicator to understand and diagnose the house rental market. However, the index is criticized in that it tends to decline when the price level of Jeonse (i.e., a typical type of dwellings in Korea, generally leased on a deposit basis for 1 or 2 years) is highly going up, which is inconsistent with the actual economic sentiment of tenants. We verify the reason why such phenomenon occurs and suggest a simple but novel method to analyze properly the change rate of the index. The main findings are as follows. The key factor to trigger the problem is the use of the conversion rate for Jeonse-to-monthly rent for constructing the rent price indexes. We separate the effect of the conversion rate out of the change rate of the index and quantify the adjusted real change rate showing an increase of the rent price level which is masked by the conversion rate before.

The Characteristics of Typically Perceived Situations (TPSs) and Critical Examples: Focusing on Secondary Students' Ideas of Force and Mechanical Energy Conversion (전형적 인식 상황과 결정적 예의 특징: 힘과 역학적 에너지 전환에 대한 중등학생의 생각을 중심으로)

  • Kang, Tae-Wook;Joung, Yong-Jae;Song, Jin-Woong
    • Journal of The Korean Association For Science Education
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    • v.28 no.6
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    • pp.579-591
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    • 2008
  • Recently, there have been studies about Typically- Perceived-Situations (TPSs) and about critical examples as a way to understand students' preconceptions with context. TPS is a situation arising immediately in one's mind when he or she thinks about the concept, while a critical example is an example that becomes the most helpful in learning the concept. We might explore how the context is involved in the process of students' conceptual understanding by examining TPSs and critical examples together. This study analyzed, through questionnaires and interviews, the characteristics of TPSs and those of critical examples that secondary students hold about 'force' and 'mechanical energy conversion.' Students' TPSs and critical examples showed different characteristics according to the concept. In a case of force that is related to everyday life, there were various situations as TPSs and critical examples. Unlike force, there were a few situations as TPSs and critical examples such as a falling ball in the case of mechanical energy conversion. Students tended to regard situations that are usually experienced and understood easily as TPSs or critical examples. On the basis of the results of this study, it is concluded that it would be a good strategy to teach science concepts for teachers to start with the TPS of a concept, to introduce the concept, and then to expose the attributes of the concept with critical examples.

A stepwised catalytic combustion of ammonia with $H_2$ and CO on supported Pt, Pd and Rh catalysts (Pt, Pd와 Rh가 담지된 촉매상에서 암모니아와 수소/일산화탄소의 단계별 촉매연소에 관한 연구)

  • Hwang, J.Y.;Ryu, I.S.;Lee, K.C.;Lee, S.J.;Noh, D.S.;Rhee, K.S.;Kang, S.K.
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.20-26
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    • 2006
  • This study investigated on the conversion of nitrogen component in ammonia gas to control fuel-NOx. Control conditions were found to suppress the production of NOx in the catalytic combustion of the gasified fuels. Also, the results would provide the basis of the theoretical study on fuel-NOx generation mechanism.

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Development of Digital map Ver.2.0 representation conversion system for 1/5,000 Topographic mapping (1/5,000 지형도제작을 위한 수치지도 Ver.2.0 자료변환 시스템 개발)

  • 황창섭;이재기
    • Proceedings of the Korean Society of Surveying, Geodesy, Photogrammetry, and Cartography Conference
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    • 2004.04a
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    • pp.321-328
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    • 2004
  • Since National Geographic Information System was started, topographic maps have been made with computer aided editing of digital map, instead of etching map-size negative film. topographic mapping system's necessity is growing more and more, because digital map has changed into Ver.2.0 which include attributes of feature. On the basis of the previous study for analyzing correlation between the digital map feature code and the 1/5,000 topographic map specifications and trying to develop fundamental modules which will play a core role in topographic mapping system, in this study, we apply some 1/5,000 digital maps Ver.2.0 to topographic mapping system have implemented and try to analyze the result.

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Role of Bypass Protein in Feeding Ruminants on Crop Residue Based Diet - Review -

  • Garg, Manget Ram
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.2
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    • pp.107-116
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    • 1998
  • Measurement of DCP is considered inadequate and unsatisfactory means of assessing the protein value of the diet as no distinction is made between the digestion in ferestomach and in the small intestine. Protein meals should be classified on the basis of rumen degradable protein (RDP) and rumen undegradable protein (UDP). Usually, protein meals naturally available with high level of UDP or bypass protein value should be preferred for incorporation in the diet of lactating and growing animals. However, if such resources are non-available or are expensive, protein meals having high degradability can be carefully subjected to heat or formaldehyde treatment to achieve desired level of rumen bypassability. Various studies conducted the world over have revealed that bypass protein feeding to ruminants, especially when animals are fed on crop residue based basal diet, help increasing feed conversion efficiency in growing and lactating ruminants.

Real time GPS position correction using a camera and the vanishing point when a vehicle runs (카메라와 무한원점을 이용한 주행중 실시간 GPS 위치 보정)

  • Kim, Bo-Sung;Jeong, Jun-Ik;Rho, Do-Whan
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.508-510
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    • 2004
  • In this paper, we proposed the GPS position data correction method for autonomous land navigation using vanishing point property and a monocular vision system. Simulations are carried out over driving distances of approximately 60 km on the basis of realistic road data. In straight road, the proposed method reduces GPS position error to minimum more than 63% and positioning errors within less than 0.5m are observed. However, the average accuracy of the method is not presented. because it is difficult to estimate it in curve road or other road environments.

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High-Frequency Soft-Switching PWM DC-DC Power Converter for Low Voltage Large Current Applications

  • Muraoka Hidekazu;Sakamoto Kenya;Nakaoka Mutsuo
    • Proceedings of the KIPE Conference
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    • 2001.10a
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    • pp.198-202
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    • 2001
  • This paper presents a novel prototype version of ZCS-PWM forward DC-DC power converter using power MOSFETs which is designed for application specific low voltage large current conversion operation. The soft-switching forward power converter with a high frequency isolated transformer link which can efficiency operate over wide load ranges under two conditions of ZCS as well as active voltage clamped switching is evaluated and discussed on the basis of the simulation and experimental results.

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