• 한국분말재료학회지
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• 제13권1호
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• pp.62-67
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• 2006

Friction welding of $Al_2O_3$ particulate reinforced aluminum composites was performed and the following conclusions were drawn from the study of interfacial bonding characteristics and the relationship between experimental parameters of friction welding and interfacial bond strength. Highest bonded joint efficiency (HBJE) approaching $100\%$ was obtained from the post-brake timing, indicating that the bonding strength of the joint is close to that of the base material. For the pre-brake timing, HBJE was $65\%$. Most region of the bonded interface obtained from post-brake timing exhibited similar microstructure with the matrix or with very thin, fine-grained $Al_2O_3$ layer. This was attributed to the fact that the fine-grained $Al_2O_3$ layer forming at the bonding interface was drawn out circumferentially in this process. Joint efficiency of post-brake timing was always higher than that of pre-brake timing regardless of rotation speed employed. In order to guarantee the performance of friction welded joint similar to the efficiency of matrix, it is necessary to push out the fine-grained $Al_2O_3$ layer forming at the bonding interface circumferentially. As a result, microstructure of the bonded joint similar to that of the matrix with very thin, fine-grained $Al_2O_3$ layer can be obtained.

• 한국주조공학회지
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• 제27권5호
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• pp.203-208
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• 2007

The high temperature properties of vanadium and molybdenum added high silicon ductile iron, so called V-Mo-Si ductile iron, were investigated. The (V,Mo) complex carbides and Mo carbides precipitated at the cellular boundaries of the as-cast specimens. The microhardness of the (V,Mo) carbides were in the range of 553-619, while that of the Mo carbides in the range of 341-390. The thermo-mechanical tests were carried out with a Gleeble system at 700 and $800^{\circ}C$ under vacuum condition. The tensile strengths of the specimen tested at $700^{\circ}C$ with the dynamic deformation rate of 50 mm/sec and those with the static deformation rate of 0.15 mm/sec were 235.7 and 115.3 MPa, while the reduction in area were 23.7 and 22.4%, respectively. At the high dynamic deformation rates, the tensile strength was steeply increased due to promoting the brittle fracture of pearlite in the matrix of the specimens. But the changes of the reduction in area with the deformation rates on the same specimens were negligible. The weight gain of the V-Mo-Si specimens oxidized in the air atmosphere for 6 hours at 800 and $900^{\circ}C$ were 1.1 and 4.1.%, respectively. The cross-sectional microstructure of oxidized specimens consisted of the porous external scale layer grown outside from the original surface, the dense internal scale layer grown into the original surface, the decarburized ferrite layer between the internal scale and the matrix of base metal. The (V,Mo) carbides and Mo carbides formed in the matrix of as-cast specimen did not decompose during oxidation at 900 for 24 hours in air atmosphere.

• 한국결정성장학회지
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• 제23권2호
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• pp.114-118
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• 2013

최근 금속자원 재활용과 환경보호에 대한 기술적 필요성에 의해 구리(Cu)를 주성분으로 하는 동합금으로부터 니켈, 주석 등의 유가금속 분리/회수에 대한 관심이 높아지고 있다. 본 연구에서는 동합금에 포함된 유가금속들을 분리/회수하는 기초연구중 하나로서, 킬레이트 수지를 이용하여 동합금 제련시 발생하는 부산물에 포함되어 있는 대표적인 유가금속인 니켈(Ni)을 분리/추출할 수 있는 농축 공정의 가능성에 대해 검토하였다. 킬레이트 수지는 원자량이 높은 $Cu^{2+}$ 이온을 $Ni^{2+}$ 이온보다 선택적으로 흡수하였으며, 이러한 과정을 수차례 반복함으로써 실제 동합금 부산물 샘플의 $Ni^{2+}$ 및 $Cu^{2+}$ 이온을 농축할 수 있었으며, XRF 분석을 통하여 각각 70 % 및 99 %의 농도로 분리할 수 있음을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제31권6호
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• pp.1615-1620
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• 2010

Bis-[dipyrido[3,2-$\alpha$:2',3'-c]phenazine)$_2$(1,10-phenanthroline)$_2Ru_2$]$^{2+}$ complexes (bis-Ru(II) complexes) tethered by linkers of various lengths were synthesized and their binding properties to DNA investigated by normal absorption and linear dichroism spectra, and fluorescence techniques in this study. Upon binding to DNA, the bis-Ru(II) complex with the longest linker (1,3-bis-(4-pyridyl)-propane), exhibited a negative $LD^r$ signal whose intensity was as large as that in the DNA absorption region, followed by a complicate $LD^r$ signal in the metal-to-ligand charge transfer region. The luminescence intensity of this bis-Ru(II) complex was enhanced. The observed $LD^r$ and luminescence results resembled that of the [Ru(1,10-phenanthroline)$_2$ dipyrido[3,2-$\alpha$:2',3'-c]phenazine]$^{2+}$ complex, whose dipyrido[3,2-$\alpha$:2',3'-c]phenazine (dppz) ligand has been known to intercalate between DNA bases. Hence, it is conclusive that both dppz ligands of the bis-Ru(II) complex intercalate. The binding stoichiometry, however, was a single intercalated dppz per ~ 2.3 bases, which violates the "nearest binding site exclusion" model for intercalation. The length between the two Ru(II) complexes may be barely long enough to accommodate one DNA base between the two dppz ligands, but not for two DNA bases. When the linker was shorter (4,4'-bipyridine or 1,2-bis-(4-pyridyl)-ethane), the magnitude of the LD in the dppz absorption region, as well as the luminescence intensity of both bis-Ru(II) complexes, was half that of the bis-Ru(II) complex bearing a long linker. This observation can be elucidated by a model whereby one of the dppz ligands intercalates while the other is exposed to the aqueous environment.

• Journal of Welding and Joining
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• 제34권6호
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• pp.28-34
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• 2016

Galvannealed(GA) steels are now generally used in car body manufacturing for corrosion resistance. In this study, the weldability and joint mechanical behavior of a newly developed 1.2GPa grade GA ultra high strength TRIP(transformation induced plasticity) steel was investigated for three joining processes, such as adhesive bonding, resistance spot welding and weldbonding. Under both shear and peel stress conditions, the failure mode of the adhesive joints were the mixture of the adhesive cohesive failure, adhesive interface failure and coating layer failure. It means that the adhesion strength of GA coating onto the base metal was similar to that of adhesive bonding onto the GA coating. Under the shear stress condition, the weldbonding exerted to expand the optimal spot welding condition of 1.2GPa GA TRIP steel because the strength of adhesive bond overwhelmed that of the resistance spot weld. Under the peel stress condition, the weldbonding also exerted to expand the optimal spot welding condition of 1.2GPa GA TRIP steel by inducing the tear fracture mode rather than the partial plug fracture mode.

• 한국지진공학회논문집
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• 제8권3호
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• pp.87-96
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• 2004

최근에 수행된 보 플랜지 절취형 (Reduced Beam Section, RBS) 내진 철골모멘트접합부의 실험 결과에 의하면, 보 웨브를 볼트 접합한 시험체는 보 웨브를 용접 접합한 시험체에 비해서 조기에 스캘럽을 가로지르는 취성파단이 발생하는 열등한 내진성능을 보였다. 실험결과에 의할 때, 이러한 접합부 취성파괴가 발생하는 주요 원인은 웨브 볼트의 슬립과 고전 휨이론에 의한 예측과는 전혀 다른 응력 전달메카니즘에 의한 스캘럽 부근의 응력집중 때문으로 사료된다. 이는 고전 휨이론에 기초한 전통적 보 웨브 볼트접합부의 설계법을 재검토할 필요가 있음을 시사하는 것이다. 본 연구를 통하여 고전 휨이론에 기초한 현행의 보 웨브 설계법에 문제가 있음을 지적하였다. 실험 및 해석결과를 바탕으로 RBS 접합부의 실제 응력전달경로에 부합되는 새로운 보 웨브 볼트접합 설계법을 제안하였다.

• Structural Engineering and Mechanics
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• 제63권5호
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• pp.617-628
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• 2017

In order to study the failure mode and seismic behavior of the interior-joint in steel traditional-style buildings, a single beam-column joint and a double beam-column joint were produced according to the relevant building criterion of ancient architectural buildings and the engineering instances, and the dynamic horizontal loading test was conducted by controlling the displacement of the column top and the peak acceleration of the actuator. The failure process of the specimens was observed, the bearing capacity, ductility, energy dissipation capacity, strength and stiffness degradation of the specimens were analyzed by the load-displacement hysteresis curve and backbone curve. The results show that the beam end plastic hinge area deformed obviously during the loading process, and tearing fracture of the base metal at top and bottom flange of beam occurred. The hysteresis curves of the specimens are both spindle-shaped and plump. The ultimate loads of the single beam-column joint and double beam-column joint are 48.65 kN and 70.60 kN respectively, and the equivalent viscous damping coefficients are more than 0.2 when destroyed, which shows the two specimens have great energy dissipation capacity. In addition, the stiffness, bearing capacity and energy dissipation capacity of the double beam-column joint are significantly better than that of the single beam-column joint. The ductility coefficients of the single beam-column joint and double beam-column joint are 1.81 and 1.92, respectively. The cracks grow fast when subjected to dynamic loading, and the strength and stiffness degradation is also degenerated quickly.

• 대한화학회지
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• 제29권3호
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• pp.257-264
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• 1985

메탄올 용액에서 3-메톡시살리실알데히드와 몰리브덴산암모늄으로 부터 디옥소비스메톡시살리실알데히다토 몰리브데늄(VI) 착물을 합성하고 이를 일차아민과 반응시켜 MoO$_2$(CH$_3$O-sal-N-R)$_2$, (R;일차아민)형의 시프-염기착물을 합성하였다. 이들에 대한 원소분석, 스펙트라의 해석 그리고 전기전도도의 측정으로 부터 착물의 성질과 그 구조를 추정하였다. 적외선 스펙트라에서 Mo=O 신축진동에 기인한 두 개의 흡수띠가 900cm$^{-1}$부근에서 관찰되었으며 이는 Mo(VI) 착물이 cis-MoO$_2$형으로 되어있음을 나타낸다. 또한 MoO$_2$와 배위자 사이의 결합비가 1:2임을 알 수 있었다. 이들 착물의 전자스펙트라에서 배위자로부터 금속으로 전하이동전이가 일어났다. 이들 착물은 노란색 혹은 오렌지색깔을 띠며 비극성물질로서 알코올이나 디클로로메탄, 클로로포름 및 디메틸프름 아마이드에 약간 녹인다.

• Nuclear Engineering and Technology
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• 제36권1호
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• pp.112-120
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• 2004

The purpose of this paper is to analyze the piping failure frequency for the main feedwater system in domestic nuclear power plants(NPPs) for the application to an in-service inspection(ISI), leak before break(LBB) concept, aging management program(AMP), and probabilistic safety analysis(PSA). First, a database was developed for piping failure events in domestic NPPs, and 23 domestic piping failure events were collected. Among the 23 events, 12 locations of wall thinning due to flow accelerated corrosion(FAC) were identified in the main feedwater system in 4 domestic WH 3-loop NPPs. Two types of the piping failure frequency such as the damage frequency and rupture frequency were considered in this study. The damage frequency was calculated from both the plant population data and damage(s) including crack, wall thinning, leak, and/or rupture, while the rupture frequency was estimated by using both the well-known Jeffreys method and a new method considering the degradation due to FAC. The results showed that the damage frequencies based on the number of the base metal piping susceptible to FAC ranged from $1.26{\times}10^{-3}/cr.yr\;to\;3.91{\times}10^{-3}/cr.yr$ for the main feedwater system of domestic WH 3-loop NPPs. The rupture frequencies obtained from the Jeffreys method for the main feedwater system were $1.01{\times}10^{-2}/cr.yr\;and\;4.54{\times}10^{-3}/cr.yr$ for the domestic WH 3-loop NPPs and all the other domestic PWR NPPs respectively, while those from the new method considering the degradation were higher than those from the Jeffreys method by about an order of one.

• 대한조선학회논문집
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• 제48권1호
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• pp.76-83
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• 2011

FCAW(Flux Cored Arc Welding) is a widely used welding method in shipbuilding. It also conducts WPS(Welding Procedure Specification) requested by the classification variations of the factors which affect the quality on the welded area such as thickness of base metal, type of welding wire and shielding gas etc. which has to be satisfied. CO2 is commonly used as a shielding gas for FCAW due to the economic point of view. The amount of shielding gas is stated when classification certify WPS. However, the shielding gas is unnecessarily used at the shipyard leaning only on the welder's experience as there are classification standards for using the shielding gas. It causes production cost to rise. Also recently, CO2 is a main contributor for global warming, and large amounts of CO2 are discharged into the atmosphere during shipbuilding processes without any filtration. Therefore it was confirmed by the security of the welded area as a result of conducting the destructive and non-destructive tests with setting up the factors and the standards by using the Taguchi method. Then the FCAW shielding gas's amounts were calculated precisely when assembling a ship. It will be applied to cost reduction and prevention of environmental pollution at the shipyard.