• Title/Summary/Keyword: base polymer

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Membrane Strip형 전기전도도 면역센서 신호발생원으로써 전도성고분자 합성

  • O, Gyu-Ha;Baek, Se-Hwan
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.707-708
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    • 2000
  • Colloidal gold with a conducting polymer (e.g., polyaniline) bound on the metal surfaces has been used for the generation of conductimetric signal in a membrane strip immunosensor. Since polyaniline itself at a low pH range revealed a low conductivity, an approach of doping the polymer with a lithium salt was used. As an alternative method, a self-doped (i.e., pH-independent) sustance such as leucoemeraldine base sulfonated polyaniline (LEB-SPAN) can be used as signal generator. It was also highly soluble in water and, thus, such a selected polymer was expected to support a satisfactory property as a label of the immunosensor.

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Development of sulfonated polysulfone composite membranes for ammonium rejection

  • Bastos, Edna T.R.;Barbosa, Celina C.R.;Silva, Jaciara C.;Queiroz, Vanessa B.C.;Vaitsman, Delmo S.
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.83-93
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    • 2013
  • In the present investigation, were synthesized composite membranes prepared by simultaneous casting of two polymer solutions using the technique of phase inversion by immersion / precipitation. The support layer was prepared using polyethersulfone and polysulfone as base polymer and for the top layer was used sulfonated polysulfone (SPSU) with 50% sulfonation degree. The morphology of the resulting membranes were characterized by scanning electron microscopy (SEM). The final results showed that it is possible to prepare composite membranes by simultaneous casting of two polymer solutions with adherence between the two layers. Regarding the permeation tests, the developed membranes presented values of hydraulic permeability within the range of commercial nanofiltration (NF) membranes. Values rejection of 80% ammonium ions can be increased by using a SPSU with a greater degree of sulfonation.

Patterning Barrier Ribs of PDP by Transparent Soft Mold

  • Paek, Sin-Hye;Choi, Hyung-Suk;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.639-642
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    • 2002
  • A new PDP barrier rib formation technique was investigated utilizing transparent soft maid made of silicon resin. Transparent soft mold was fabricated by pouring a silicone resin into the base mold made with photosensitive glass. The photosensitive barrier rib paste was coated on the glass substrate and dried in a 90 $^{\circ}C$ convection oven for 20min. The transparent soft mold was pressed on top of the semi-dry barrier rib layer and then irradiated with a UV lamp to a total dose of $900{\sim}1000mJ/cm^2$ The soft maid was then removed from the pressed barrier rib by winding up and fine pattern of barrier rib was obtained. The photosensitive barrier rib paste makes the demolding easy due to reduced interfacial forces and shrinking of paste materials.

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Preparation and Characteristics of High Voltage Liquid Silicone Rubber by Modified Cross-linking Agent

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.1
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    • pp.9-15
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    • 2009
  • There is a growing demand for a high voltage silicone rubber composite with high mechanical property and high electrical property. The effect of modified cross-linking agent on the mechanical, electrical properties, and short-circuit test performance of silicone rubber insulators have been investigated. To use base polymer, the various silicone polymers were prepared by the equilibrium polymerization. Aluminum trihydrate surface was treated by vinyl silane. Liquid silicone rubber nanocomposite was prepared from the compounding of VPMPS, HPDMS, catalyst, and alumina trihydrate modified with 1,3,5-trivinyl-l,3,5-trimethylcyclotrisiloxane. The mechanical property and electrical property for insulation materials were measured, indicating the high tensile strength and the good short-circuit property.

Rheological Properties of EPM end EPDM Rubbers (EPM 및 EPDM 고무의 유변학적 특성)

  • Kim, Byung-Kyu;Kim, Chang-Kee;Park, Chan-Young
    • Elastomers and Composites
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    • v.25 no.2
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    • pp.97-102
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    • 1990
  • Linear viscoelastic properties of 11 types of EPDM and 1 type of EPM rubbers have been measured at $210^{\circ}C$, using a RDS(Rheometrics dynamic spectrometer). The data base, i.e., complex viscosity, storage modulus, loss modulus, loss tangent and relaxation spectrum of the sample should be useful for rubber blending and compounding.

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Electrical Properties of Silicone Rubber Filled with Surface Treated Alumina Trihydrate

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.3
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    • pp.134-140
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    • 2006
  • The effect of surface treatment of fillers on the mechanical, electrical properties, and tracking performance of silicone rubber insulators have been investigated. For base polymer, $\alpha,\;\omega$) vinyl poly(dimethyl-methylphenyl) siloxane(VPMPS) containing dimethyl siloxane and methylphenyl siloxane was prepared by the equilibrium polymerization. High voltage silicone rubber composites(HVSRC) were prepared from VPMPS, nano-silica, and alumina trihydrate (ATH) modified by various coupling agents. Bound rubber of uncured silicone rubber, cross-linking density of the vulcanizate as well as the mechanical, electrical properties, and tracking performance were measured.

Synthesis of Conjugated Copolymers with phenothiazine and Azomethine Units and their Electro-Optic Properties

  • Seo, Hyeon-Jin;Jang, Byeung-Jo;Chang, Jin-Gyu;Park, Lee-Soon
    • Journal of Information Display
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    • v.2 no.4
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    • pp.8-14
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    • 2001
  • Three types of conjugated polymers, poly(PZ-Pi), poly(PZ-BPI) and poly(PZ-NPI) were synthesized by Schiff-base reaction. These new conjugated polymers exhibited improved solubility in common organic solvents due to the presence of alkyl side chains as well as azomethine groups, Double layer LEDs made with the synthesized polymers as emitting layer and $Alq_3$, as electron transporting layer exhibited enhanced EL emission and efficiency compared to those of single layer LEDs. Double layer LEDs exhibited gradual shift in the emission peak th the single layer LED, made of only $Alq_3$ as the emitting layer as the thickness of $Alq_3$ layer increased.

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Geometric interpretation of time-temperature superposition

  • Cho, Kwang-Soo
    • Korea-Australia Rheology Journal
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    • v.21 no.1
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    • pp.13-16
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    • 2009
  • We investigate time-temperature superposition from the viewpoint of geometry. The arc length of viscoelastic plots provides powerful resolution for check of the validity of time-temperature superposition. We also suggest a new algorithm for determination of shift factor which is base on the minimization of the total arc length and does not assume any functional form of viscoelastic function.

Study on synthesis of Schiff base and its basic characteristics (Schiff base의 합성과 그의 기초적 물성에 관한 연구)

  • Shin, Dong-Gyu;Kwon, Oh-Kwan;Lim, Sung-Taek;Kim, Young-Kwan;Nam, Ki-Dae;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.4
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    • pp.57-62
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    • 1998
  • In this study, a new conducting materials, namely, a Schiff base (polymeric azomethine) was synthesized from 2,6-diamino-N-docosyl pyridinium bromide and terephthalaldehyde to obtain a soluble and fusible conducting polymer. The synthesized Schiff base structure was analyzed by using UV/vis absorption spectrophotometer, FT-IR spectrometer and $^1H$-NMR spectrometer. It was found that the Schiff base was successfully synthesized and soluble in carbon tetrachloride$(CC^{14})$, its Langmuir-Blodgett film was easily fabricated, and its surface pressure was determined to be 30mN/m for solid state by measuring ${\pi}$-A isotherm.