• 멤브레인
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• 제1권1호
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• pp.78-95
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• 1991

미국 캘리포니아주 Orange County에 위치한 Water Factory 21(WF-21)은 생물학적 처리공정을 거친 도시하수를 재생하여, 이 재생수를 지하수지층으로 유입되는 해수의 침투를 막기 위한 Reinjection System에 이용하고 있다. 장치 구성 공정은 Lime처리, Air Stripping, 사여과, 활성탄처리, 역삼투막 및 염소처리 등으로 이루어지며, 이에 대한 각 처리공정의 효율성에 대하여 실험을 실시하였다. 3년간의 장기간에 걸친 실험결과로부터, 도시하수에 대한 RO Membrane 처리수는 음료 수질 기준에 적합한 고수질의 물을 생성할 수 있음을 입증했다. Pilot Plant 실험에선 Lime Clarifier만으로 전처리를 실시하여 성공적인 결과를 얻었으며, 또한 저압 (250 psi)이 적용된 새로운 Membrane을 사용하여 에너지 절약을 통한 비용 절감 효과에 대한 실험도 상당한 가능성을 보여주었다.

• Membrane and Water Treatment
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• 제6권5호
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• pp.393-409
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• 2015

Zinc and lead pollution are public environmental issues that have attracted lots of attention for a long time. Landfill leachate contains heavy metals, such as Zn(II) and Pb(II), which are usually related to the pollution of groundwater, especially in developing countries. Bentonite has been proven to be effective in enhancing the membrane property of clay, by which landfill liners can have better barrier performance towards the migration of contaminants. In this study, 5% sodium bentonite amended with locally available Fukakusa clay was utilized to evaluate the membrane behavior towards the heavy metals zinc and lead. The chemico-osmotic efficiency coefficient, ${\omega}$, was obtained through Zn(II) and Pb(II) solutions with different concentrations of 0.5, 1, 5, 10, and 50 mM. According to the results, ${\omega}$ continually decreased as the Zn(II) and Pb(II) concentrations increased, which is consistent with the Gouy-Chapman theory. Compared to normal inorganic ions, the membrane behavior towards heavy metal ions was lower. The migration of heavy metal ions was not observed based on experimental results, which can be attributed to the adsorption or ion exchange reaction. The mechanisms of the membrane performance change were discussed with the assistance of XRD patterns, free swelling results, XRF results, and SEM images.

• 에너지공학
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• 제21권4호
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• pp.339-345
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• 2012

최근 안정성 및 경제성 측면에서 완전방호식 LNG 저장탱크(full-containment LNG storage tank)의 대안으로 검토되고 있는 멤브레인 LNG 저장탱크(membrane LNG storage tank)에 대해서 정량적 위험성 평가 방법(QRA; Quantitative Risk Analysis)과 유한요소해석법(FEM; Finite Element Method)을 통하여 안전성 평가를 수행하였다. 본 논문에서는 유한요소해석법(FEM)을 통한 구조안전성 평가에서 140,000 $m^3$ 저장용량을 갖는 LNG 저장탱크의 두 가지 모델은 저장탱크 시스템에 대한 강도 안전성과 누출 안전성 측면에서 해석한 결과에 의하면 모두 안전한 것으로 평가되었다. 또한, 고장수목분석(FTA; Fault Tree Analysis)을 통하여 멤브레인 LNG 저장탱크에 안전성을 강화하기 위해 설계 초기모델에 안전장치로서 멤브레인 바닥부의 충격흡수장치(impact absorber structure), 1차 멤브레인 저장 파손 시 콘크리트 외부탱크(outer tank) 코너부(corner part)의 열충격(thermal stress)을 감소시킬 수 있는 열보호장지(secondary barrier) 및 펌프 낙하 시 안전장치로서 펌프캐쳐(pump catcher)를 보완하고 평가하였다. 결론적으로 개선된 멤브레인 LNG 저장탱크는 안전성 측면에서 완전방호식 LNG 저장탱크와 대등하다는 결론을 도출할 수 있었다.

• 대한조선학회논문집
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• 제57권3호
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• pp.168-174
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• 2020

Recently, the size of Liquified Natural Gas (LNG) carriers has been increasing, in turn increasing the load generated during operation. To handle this load, the thickness of LNG Cargo Containment Systems (CCSs) should be increased. Despite increasing the thickness of LNG CCSs, a secondary barrier is still used in conventional thickness. Therefore, the mechanical performance of the existing secondary barrier should be verified. In this study, tensile test of the secondary barrier was performed to evaluate mechanical properties under several low- and cryogenic-temperature conditions considering LNG environment, and in each fiber direction considering that the secondary barrier is composed of anisotropic composite materials depending on the glass fibers. Additionally, the coefficient of thermal expansion was measured by considering the degradation of the mechanical properties of the secondary barrier caused by the generated thermal stress during periodical unloading. As a result, the mechanical performance of secondary barrier in the Machine Direction (MD) was generally found to be superior than that in the Transverse Direction (TD) owing to the warp interlock structure of the glass fibers.

• 한국응용과학기술학회지
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• 제30권2호
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• pp.215-224
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• 2013

Recently, many cosmetic researchers have been focused on the development of high functional cosmetics including anti-wrinkle and whitening. In these studies, they couldn't afford to pay a deep attention to stable encapsulations for unstable materials and efficient drug deliveries for them. Particularly, in order to show a degree of instant effects as cosmetics, they can't also ignore moisturizing effect enough to satisfy customers just after applying and its maintenance by improving the function of skin barrier as well as above two effects. Therefore, skin analogue systems have attracted considerable attention in the view of structural and compositional similarity to intercellular membrane in stratum corneum. And, some models for skin analogue composition were developed to improve the function of skin barrier, stably encapsulate unstable materials such as retinol, vitamin B, C, E, etc., and control their skin penetration in order to show good effects as cosmetics. In this study, we suggest the new skin analogue model having the compositional similarity as well as conventional structural ones. Our skin analogue membrane(SAM) is mainly composed of ceramide/ cholesterol/phosphatidylcholin/fatty acids and its structural defects are compensated by including cholesterol amphiphile and controlling the ratio of ceramide/cholesterol. It was possible to confirm the formation of skin analogue membrane having highly-densed multilamella structure and compare them according to the change of each ratio with a polarized microscope, X-ray diffraction. More detaily, we observed their structures with a electron microscope(TEM). Finally, we dispersed them in excess of continuous water phase, observed the formation of maltese-cross liquid crystalline and measured the efficiency of drug deliveries and moisturizing effects.

• Journal of Periodontal and Implant Science
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• 제27권1호
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• pp.19-43
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• 1997

The barrier membranes for GTR procedure could be affected bY bacterial contamination after exposure to oral environment. This study was done to evaluate whether the tetracycline impregnated barrier membranes could inhibit bacterial attachment and penetration into membranes. The resorbable membrane(polylactic and polyglycolide copolymer, $Resolute^{(R)}$, W.L Gore and Associates, Inc..USA) and the non-resorbable membrane(e-PTFE; Gore-TexTM, W.L. Gore & Associates, Inc.,USA) were cut into 4mm discs and trated with 5% tridodecylmethylammonium chloride solution in ethanol and dried in air. The membranes were immersed in tetracycline(TC) solution (100mg/ml, pH 8.0) and dried. To the maxillary canine-premolar region in six periodontally healthy volunteers, removable acrylic devices were inserted, on which 8 cylindrical chambers were glued with TC impregnated and non-impregnated discs, the membrane discs were examined for bacterial attachment and penetration, and structural changes under SEM and LM. From the 1st day to the 7th day, membranes showed bacterial plaque formation composed of cocci and rods. Thereafter, filamentous bacteria appeared and the plaque thickness increased. The TC impregnated e-PTFE membranes showed less bacterial attachment and delayed in bacterial plaque maturation than non-treated membranes. As for bacterial penetration, the TC impregnated e-PTFE membranes showed superficial invasion and infrequent presence of bacteria in unexposed inner surface at the 4th week. while the non-treated e-PTFE membranes showed deep bacterial invasion at the 2nd week and frequent presence of internal bacteria at the 4th week. The resorbable membranes started to be resorbed at the 2nd week and were perforated at the 4th week, regardless of TC treatment. In conclusion, bacterial plaque formation and penetration was efficiently delayed in TC impregnated e-PTFE membranes, whereas resorbable membranes were similar in bacterial invasion due to membrane degradation and perforation, regardless of TC treatment.

• 한국임상수의학회지
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• 제30권2호
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• pp.127-130
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• 2013

13년령의 4.2 kg 암컷 푸들이 하악의 병적 골절 후 지역병원에서 받은 양측성 하악 수술의 실패로 내원하였다. 수술은 2.0-mm miniplates/screws, 돼지해면질골 및 흡수성 막을 사용해 시행되었다. 수술 후 1일, 1, 4, 8, 12주에 예후를 평가하였다; 치아 부정교합, 골절 불유합, 또는 연부조직 감염의 징후는 보이지 않았다. 그러나 1년 후 장기간 검진에서 콜라겐 막을 사용하지 않았던 왼쪽 하악골절부위에 불유합이 관찰되었다. 따라서 노령견에서 하악골 불유합의 치유에 돼지해면골과 흡수성 막을 함께 사용하는 것은 효과적이라 생각된다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.278-281
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• 2009

Proton exchange membrane is the key material for proton exchange membrane fuel cells (PEMFC). Currently widely-used perfluorosulfonic acid membranes have some disadvantages, such as low thermal stability, easy swelling, excessive crossover of methanol and high price etc. Other membranes, including sulfonated polymer, radiation grafted membranes, organic-inorganic hybrids and acid-base blends, do not satisfy the criteria for PEMFC, which set a barrier to the development and commercialization of PEMFC. Pore-filling type proton exchange membrane is a new proton exchange membrane, which is formed by filling porous substrate with electrolytes. Compared with traditional perfluorosulfonic acid membranes, pore-filling type proton exchange membranes have many advantages, such as non- swelling, low methanol permeation, high proton conductivity, low cost and a wide range of materials to choose. In this research, preparation methodology of pore-filling membranes by particularly using all hydrocarbon polymers and fuel cell performances with the membranes are evaluated.

• 멤브레인
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• 제26권2호
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• pp.152-158
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• 2016

클로알칼리(CA) 멤브레인 셀은 대표적인 염수전해 시스템으로서 가성소다와 염소를 생산하는 염수전기분해 프로세스이다. CA 멤브레인 프로세스는 타 공정에 비해 낮은 에너지 소모량을 가져 CA산업에서 가장 선호되는 공정이다. CA프로세스에 사용되는 과불소계 술폰화 이오노머막은 CA프로세스의 핵심구성 요소이며, 양이온을 선택적으로 이동시키는 역할 및 배리어적인 역할을 제공한다. 하지만, CA 구동을 위해 충족되어야 하는 요소들에 대한 정보가 제한적이기 때문에 알맞은 CA분리막 적용을 위한 제품 간의 연구가 필요하다. 본 연구에서는 실제 셀 구동을 바탕으로 하여 상용 고불소계 분리막의 이온전도경향 및 전기화학적 성능 등을 평가하였다.

• Maxillofacial Plastic and Reconstructive Surgery
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• 제42권
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• pp.34.1-34.7
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• 2020

Purpose: The purpose of this study was to evaluate the influence of biodegradable polycaprolactone membrane on new bone formation and the biodegradation of biphasic alloplastic bone substitutes using animal models. Materials and methods: In this study, bony defect was formed at the canine mandible of 8 mm in diameter, and the defects were filled with Osteon II. The experimental groups were covered with Osteoguide as barrier membrane, and the control groups were closed without membrane coverage. The proportion of new bone and residual bone graft material was measured histologically and histomorphometrically at postoperative 4 and 8 weeks. Results: At 4 weeks, the new bone proportion was similar between the groups. The proportion of remaining graft volume was 27.58 ± 6.26 and 20.01 ± 4.68% on control and experimental groups, respectively (P < 0.05). There was no significant difference between the two groups in new bone formation and the amount of residual bone graft material at 8 weeks. Conclusion: The biopolymer membrane contributes to early biodegradation of biphasic bone substitutes in the jaw defect but it does not affect the bone formation capacity of the bone graft.