• 한국정보디스플레이학회:학술대회논문집
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• 2007.08a
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• pp.553-555
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• 2007

Six azomethine polymers containing bent-core mesogen were synthesized with variation of a bent structure of central core (1,2-dioxyphenylene or 2,3-dioxynaphthylene), and a lateral halogen substituent (X = H, F or Cl ). The properties of the polymers were characterized by FT-IR, NMR spectroscopy, DSC, polarizing optical microscopy, and X-ray diffractometry.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.171-174
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• 2006

In this work, we report the synthesis and characterization of azomethine-ester polymers that consist of banana-shaped mesogen in their backbone. Two parts of the key structure of five-ring bent-core mesogen were modified by connecting different angle of central unit (Ar), and introducing lateral substituent into the outer ring (X). The synthetic details includes (1) placing the dioxydodecamethylene unit as a flexible spacer, (2) possessing 2,3- or 2,7-naphthylene, or 1,2-phenylene connection on the central unit, and (3) introducing fluorine or chlorine substituent (X = F or Cl) into the outer phenylene unit.