• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.838-841
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• 2006

Orientational alignment patterns proved that they are very useful for realizing diverse properties of liquid crystals. Here we tried to produce the patterns combining interfered laser light and double irradiations. A photo-isomerizable polymer doped with azo dye, which induce uniform liquid crystal alignment to the uniform laser irradiation, was used as the alignment layer. Double irradiations into two orthogonal directions brought the orientation patterns similar to the checkerboard. It indicates the possibility of bistability on those patterns.

• 한국막학회:학술대회논문집
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• 한국막학회 2005년도 추계 총회 및 학술발표회
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• pp.281-284
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• 2005

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2011년도 제44차 학술발표회
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• pp.68-68
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• 2011

A new chemosensor based on rhodamine B (1) for $Hg^{2+}$ and $Cu^{2+}$ was synthesized by one-step condensation reaction of rhodamine B hydrazide and Azo dye. Studying for its fluorogenic and colorimetric behaviors towards various metal ions, extreme sensitivity and selectivity were achieved by the detection of $Hg^{2+}$ and $Cu^{2+}$ over other commonly coexistent metal ions, which were accompanied by ring opening of a rhodamine spirocycle framework. In acetonitrile, the presence of $Hg^{2+}$ and $Cu^{2+}$ induces the formation of a Dye 1-ion complex, which was deduced by spectroscopy.

• 한국의류학회지
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• 제13권4호
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• pp.380-387
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• 1989

The Purpose of this study was to investigate the color changes of acid dyed wool fabrics after imparting permanent pleats with si-ro-set finish. Monoethanolamine sulfite was used as a reducing agent. Color changes were determined by measuring CIELAB values after treating the dyed fabrics with various setting temperatures, times and concentrations of MEAS. Setting temperature affected the color changes: in the order of $150^{\circ}C>130^{\circ}C>170^{\circ}C$ Setting time had a tendency to increase the color change. As the concentration of MEAS increased, $\delta$ E was increased. Azo dye was more affected than anthraquinone dye by MEAS treatment. Color changes were mainly due to $\delta$ L.

• 한국염색가공학회지
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• 제26권3호
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• pp.165-172
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• 2014

Novel super hydrophobic orange dyes having maximum absorption band at 450-500nm were synthesized to dye polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers, using 4-alkylanilines and ${\beta}$-naphthol. Their absorption spectra at visible range showed almost the same, which meant that the alkyl substituents introduced to chromophore did not affect on color appearance of the dyes. Considering both color strength and wash fastness, the decyl-substituted dye was determined as the optimum one practically. From the dyeing results at various conditions, the optimum dyeing was $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing 4-5 for both fibers. Light fastness was also acceptable giving rating 3-4 for polypropylene fibers and rating 3 for ultra high molecular weight polyethylene fibers.

• 한국염색가공학회지
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• 제13권4호
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• pp.234-240
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• 2001

In order to improve the washing fastness of dyed polyester artificial suede fabric, it was dyed by using auto and anthraguinone type disperse dyes and treated with 3 different reduction clearing methods. The reduction clearing methods used in this study were normal alkaline reduction clearing, $N_2$ gas replacement method, and ultrasonic treatment during normal reduction clearing. The results were as followings ; The washing fastness property of dyed polyester artificial suede fabric was slightly improved by reduction clearing with $N_2$ gas replacement or with ultrasonic treatment comparing with normal alkaline reduction clearing. It was found that the use of $N_2$ gas replacement or ultrasonic treatment during reduction clearing eave effective removal of unfixed dyes on the fiber surface. We also obtained that the azo type disperse dye on polyester artificial fabric suede fabric showed higher wash fastness than anthraquinone type disperse dye.

• Advances in environmental research
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• 제5권3호
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• pp.189-200
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• 2016

This study aimed at advanced oxidation of hetero tri-functional reactive dye Acid orange 7 using photo-Fenton conditions in a lab-scale experiment. Decolourisation of Acid Orange 7 dye by Fenton's process was dependent on concentration of Hydrogen peroxide, Ferrous sulphate, pH, and contact time. A $2^3$ factorial design was used to evaluate the effects of these key factors: pH, Fe(II), and $H_2O_2$ concentration, for a dye concentration of 50 mg/L with COD of 340 mg/L at pH 3.0. The response function was removal of colour under optimised conditions; pH 3.0, [Fe(II)] 40.83 mg/L, [$H_2O_2$] 4.97 mmol/L; 13.6 min. of treatment resulting in 100% colour removal. The final COD of treated wastewater was nil suggesting that AOP is a potentially useful process of color removal and dye degradation/mineralisation of effluent having AO7. Minimum contact time for complete decolourisation was at 5 mmol/l $H_2O_2$ concentration. Increase in $FeSO_4$ (mg/l) concentration resulted in decrease of time for complete decolourisation. Box-Behnken Design was used to optimize the process variables. Maximum and minimum levels of pH (3-5), $H_2O_2$ (4-6 mmol/l), $FeSO_4$ (30-46 mg/l) and contact time (5-15 minutes) were used. The statistical analysis revealed a value of 0.88 for coefficient of regression ($R^2$) indicating a good fit of model. Calculated F-value was found higher than the tabulated value confirming to significance of the model. Based on student's t-test, Ferrous sulphate, pH, and contact time have a positive effect on the percent decolourisation of Acid Orange 7.

• 대한화학회지
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• 제28권6호
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• pp.425-432
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• 1984

難染性纖維인 폴리프로필렌用 反應性染料를 開發하기 위하여 反應部位로서 카르벤을 染料에 生成케하여 폴리프로필렌의 C-H結合에 揷入反應을 시켜 堅固한 染着物을 얻을 수 있었다. 反應性카르벤染料의 前驅體로서 알데히드係, 메틸케톤係 및 페닐케톤係 反應性染料를 合成하고 카보닐基에 토실히드라진 및 부틸리튬을 各各 作用하여 各種染料의 토실히드라존리튬鹽을 만들어 폴리프로필렌상에서 加熱分解시킴으로써 染料分子에 生成된 카르벤이 폴리프로필렌에 共有結合을 하여 染着하였다. 여기에서 合成한 各種 카르벤染料들은 카르벤이 生成되는 隣接位에 있는 置換基의 種類와 位置에 따라 反應性에 差異點을 나타내었다. 특히 페닐케톤係 反應性染料가 反應性이 優秀하였으며 이들 페닐케톤係 反應性染料의 前驅體中에서도 클로로基를 가지는 클로로아미노벤조페논으로부터 合成한 染料가 他에 비해 反應性이 良好하였다.

• 대한화학회지
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• 제32권5호
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• pp.443-451
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• 1988

Monobenzo-15-crown-5와 Dibenzo-18-crown-6을 모체로 아조(-N=N-)기가 치환된 두가지 새로운 crown ether dye-Ⅰ과 dye-Ⅱ를 합성하여 스펙트럼을 조사한바 ${\lambda}_{max}$는 377nm 와 383nm에서 나타났고. 이 crown ether dye 화합물과 알칼리 금속(Na, K, Cs)과의 착물 스펙트럼에서 ${\lambda}_{max}$는 390~400nm의 띠 이동과 세기가 증가함을 보였다. 또한 추출상수값(Kex)은 음이온을 고정한 뒤 추출상수의 크기는 Crown ether dye-Ⅰ에서는$K^+$ < $Cs^+$ < $Na^+$의 순위를 얻었으며 crown ether dye-Ⅱ에서는 $Cs^+$ < $Na^+$ < $K^+$의 순서를 얻었다. 이러한 결과는 알칼리 금속의 이온반지름과 crown ether dye의 동공의 크기 관계와 알칼리 금속 이온의 전하밀도로 설명될 수 있고 도한 음이온의 변화에 따른 추출 상수의 크기는 두가지 crown ether dye에서 똑같이 $Cl^-$ < $Br^-$ < $I^-$ < picrate의 순위를 얻었다. 이는 음이온의 용매화효과 순서와 일치함을 보여주고 있다. 그리고 각각 합성된 crown ether dye화합물의 추출계수 비를 구하여 비교 고찰하였고, 알칼리 금속 이온들의 회수율은 약 90%의 양호한 실험값을 얻었다.

• 약학회지
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• 제40권2호
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• pp.135-140
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• 1996

Ion-selective poly(vinyl chloride)(PVC) membrane electrodes for the determination of the calcium antagonist verapamil and its pharmaceutical preparations were described. Verapam il-superchrome garnet Y(SGY), lumogallion(LG), acid red 97(AR97), Dragendorff(DD) and Meyer reagent ion pairs were inverstigated as an electroactive compound for membrane electrode. Stable potentiometric response was obtained with azo dye at pH 6.5-4.0 and with DD, and Meyer reagent at pH 6.5-3.0. The best plasticizer was 49w/w% 2-nitrophenyl octyl ether for azo dye, and 65.3w/w% tri(n-butyl) citrate for DD and Meyer reagent. Potentiometric response slopes of optimized membrane electrodes based on SGY, LG, AR97, DD, and Meyer complex for verapamil were 52.49, 54.88, 50.81, 54.13 and 49.31 mV/dec., respectively. Lower limits of linear range were $1.0{\times}10^6M$ for SGY, LG, and AR97, while those for DD and Meyer reagent were $4{\times}10^{-6}M$. Detection limits for all these electrodes were $1{\times}10^{-5}M,\;4{\times}10^{-6}M,\;1.8{\times}10^{-6}M,\;8{\times}10^{-7}M,\;and\;1{\times}10^{-6}M$ with relative standard deviation of 2.56, 3.6, 3.96, 2.56, 3.20%, respectively.