• Title/Summary/Keyword: average fragmentation

Search Result 44, Processing Time 0.023 seconds

Analysis of Polymer Characteristics Using Matrix-assisted Laser Desorption/Ionization Time-of-flight Mass Spectrometry (말디토프 질량분석을 이용한 고분자의 특성분석)

  • Kang, Min-Jung;Seong, Yunseo;Kim, Moon-Ju;Kim, Myung Soo;Pyun, Jae-Chul
    • Applied Chemistry for Engineering
    • /
    • v.28 no.3
    • /
    • pp.263-271
    • /
    • 2017
  • The application of mass spectrometry to polymer science has rapidly increased since the development of MALDI-TOF MS. This review summarizes current polymer analysis methods using MALDI-TOF MS, which has been extensively applied to analyze the average molecular weight of biopolymers and synthetic polymers. Polymer sequences have also been analyzed to reveal the structures and composition of monomers. In addition, the analysis of unknown end-groups and the determination of polymer concentrations are very important applications. Hyphenated techniques using MALDI-tandem MS have been used for the analysis of fragmentation patterns and end-groups, and also the combination of SEC and MALDI-TOF MS techniques is recommended for the analysis of complex polymers. Moreover, MALDI-TOF MS has been utilized for the observation of polymer degradation. Ion mobility MS, TOF-SIMS, and MALDI-TOF-imaging are also emerging technologies for polymer characterization because of their ability to automatically fractionate and localize polymer samples. The determination of polymer characteristics and their relation to the material properties is one of the most important demands for polymer scientists; the development of software and instrument for higher molecular mass range (> 100 kD) will increase the applications of MALDI-TOF MS for polymer scientists.

Genetic diversity and geographic differentiation in the endangered Primula farinosa subsp. modesta, a subalpine endemic to Korea (한반도 아고산대 특산·희귀식물 설앵초의 유전적 다양성과 지리적 분화)

  • Chung, Jae-Min;Son, Sung-Won;Kim, Sang-Yong;Park, Gwang-Woo;Kim, Sung-Shik
    • Korean Journal of Plant Taxonomy
    • /
    • v.43 no.3
    • /
    • pp.236-243
    • /
    • 2013
  • Many plant species in subalpine regions are under threat of extinction as a result of climate change. In this study, the genetic diversity and geographic differentiation of three regions and six populations of Primula farinosa subsp. modesta (Bisset & Moore) Pax in Korea were assessed using the ISSR (Inter Simple Sequence Repeat) marker. The average genetic diversity (P = 60.62, SI = 0.299, h = 0.190) was relatively lower than that of other long-lived perennials, even though it is a self-incompatible species. AMOVA analysis showed that 50% of the total genetic diversity was partitioned among regions and Bayesian cluster analysis showed some remarkable geographic trends that were structured into 2 or 3 regions, suggesting limited gene flow among regions. Considering the population fragmentation, low level genetic diversity, and high genetic differentiation, it is essential to establish in situ and ex situ conservation strategies for P. farinosa subsp. modesta.

Geochemical Characteristics of Scirpus planiculmis Habitats in Nakdong Estuary, Korea (낙동강 하구 새섬매자기 군락지 지화학 연구)

  • Kim, Yunji;Kang, Jeongwon;Choi, Jae Ung;Park, Chan Mi;Woo, Han Jun
    • Journal of Wetlands Research
    • /
    • v.21 no.2
    • /
    • pp.125-131
    • /
    • 2019
  • The Nakdong Estuary has experienced hydraulic and topographic changes over the last century, which have had negative effects of habitat loss and fragmentation. The population of Scirpus planiculmis, a major food plant for wintering birds in Nakdong Estuary, has decreased over the last decade. To identify factors that influence S. planiculmis population, 6 short core samples (about 30cm) were collected in June and August, 2018. The sand percentage was over 80% in every samples and the average sediment salinity in June and August were $17.8{\pm}1.12psu$ and $18.4{\pm}1.83psu$, respectively. ${\delta}^{13}C$ of sediment cores varied from -25.4‰ to -22.6‰ which fall within the estuarine particulate organic matters. In cores collected in Eulsuk area, the highest ${\delta}^{13}C$ values were observed at the surface (0~1cm) indicating inputs of marine POM (particulate organic matter) to the Nakdong Estuary. No significant difference between vegetation and non-vegetation stations was observed in every items we investigated which might indicate that the physicochemical environment of vegetation area is almost same as that of non-vegetation area. Therefore, the high sand percentage and sediment salinity of Nakdong Estuary might affect the reduction in S. planiculmis population.

Evaluation of InVEST habitat quality model using aquatic ecosystem health data (수생태계 건강성 자료를 이용한 InVEST habitat quality 모델 적용성 평가)

  • Lee, Jiwan;Woo, Soyoung;Kim, Yongwon;Park, Jongyoon;Kim, Seongjoon
    • Journal of Korea Water Resources Association
    • /
    • v.54 no.9
    • /
    • pp.657-666
    • /
    • 2021
  • Ecosystem biodiversity is rapidly being lost due to changes in habitat, fragmentation of habitat, climate change, and land use changes by human activities. Recently, attempts have been made to approach the watershed management level to secure the health of the watershed, but studies on how to approach biodiversity and habitat management are still in lack. The purpose of this study is to evaluate the habitat quality of Geum river basin using Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) habitat quality model. The results of habitat quality was verified to eco-natural map and ecological watershed health evaluation results. The habitat quality of watershed was evaluated from 0 to 0.86 and the results showed that habitat quality was higher in upstream than downstream. Compared the habitat quality value in each eco-natural grade, the average habitat quality of 1st, 2nd and 3rd grades were 0.80, 0.76 and 0.71 respectively. The results of the correlation analysis with ecological watershed health data, the coefficient of determination (R2) was 0.58, and the person coefficient was 0.76. The results of this study may be used as foundation data to support habitat protection and implementation of long-term biodiversity-related policies.